氧气瓶内附油脂充氧过程爆炸分析与计算

分析总结了氧气钢瓶物理爆炸和化学爆炸的原因。针对2009年某市发生的一起氧气瓶内含油脂爆炸事故,系统分析了国内曾经发生的几次因油脂导致气瓶爆炸事故。油脂进入到氧气瓶内大都是由于误操作。油脂与高压纯氧接触会发生剧烈的自燃氧化放热,使瓶内的氧气迅速升温升压,超出气瓶承压极限导致爆炸破裂。分析比较发现由油脂导致的气瓶爆炸,其破坏程度不如混入可燃气体导致的气瓶爆炸剧烈,一般不是粉碎性爆炸。在正常的充氧过程中,氧气瓶温度会升高,采用变质量热力学中的方法,计算说明气瓶在充装过程中氧气温度的具体变化。充氧温度计算为充氧工作人员提供参考,如发现异常情况,可以及时地控制和预防。由现场压力表可知氧气瓶在充装至12MPa时发生爆炸,而氧气瓶最小爆炸压力为37.6MPa,油脂燃烧放热,计算可知致使钢瓶爆炸破裂所需要的最小油脂量,为66.4-79.6g。不同的充装压力下发生爆炸,所需要的最小油脂量不同,充装压力越高,爆炸所需要的最小油脂量越少。     

安全生产“十一五”规划实施评估技术研究

对安全生产＂十一五＂规划进行了特征分析,明确了规划评估的工作目标,研究提出了规划评估技术体系,包括评估逻辑设计原则、评估总体框架和评估技术路线。安全生产＂十一五＂规划实施评估应重点从目标实现评估、任务完成评估、政策措施评估三方面入手,评价目标实现一致性程度,评价任务实施情况及其作为目标战略的有效性如何,评价政策措施的制订与贯彻对目标实现与任务完成的支撑程度,在此基础上评价规划实施的总体效果,并对存在的问题进行原因分析,最后提出做好安全生产＂十二五＂规划的对策建议。实例应用表明,国家安全生产＂十一五＂规划实施进展总体比较顺利,取得良好成效,本文提出的评估技术体系对各级政府开展安全生产规划实施评估具有指导意义。     

PTG测定油脂与高压氧气的反应

介绍说明几起氧气瓶内附油脂充氧过程中爆炸事故。介绍高压氧气与油脂的反应,论述了空压机润滑油燃烧基本特性,采用热重天平进行了空压机润滑油在不同压力的气体氛围内的燃烧试验,建立起空压机润滑油的热重和微商热重曲线,得到空压机润滑油在不同压力的氧气氛围内的自燃点。放入加压热重分析仪内的润滑油,接触高压氧气后迅速被氧化,氧气压力越高,氧化程度越深。随着氧气压力的升高,润滑油的着火点降低。这表明氧气瓶中油脂,随着充氧压力的增加,着火点降低,即压力越大,油脂越容易自燃,释放热量,导致爆炸。提出安全措施。     

改造现有工艺回收地面计量天然气

为解决牙哈作业区A区块3口井在见水后含水上升较快、单井产液量增加、现有装置处理能力不足,导致A区块所有生产井不能全部进站的问题,同时为提高最终采收率,需要延长见水时间,见水后控制含水的上升趋势。这就要求掌握含水井的生产动态,而现有装置无法对单井的含水进行计量,塔里木油田公司牙哈作业区A区块建造集中试采装置,文章介绍了改造前后的工艺流程及改造效果。     

环介导等温扩增技术(LAMP)检测人星状病毒方法的建立及其在再生水检测中的应用

为快速高效地检测人星状病毒,建立了一种新的试验方法——环介导等温扩增技术(loop-mediated isothermal amplification technology,LAMP),并对人星状病毒LAMP反应条件进行了优化.结果表明,镁离子终浓度为4 mmol·L-1、甜菜碱终浓度为1mol.L-1的25μL体系下...     

Characterizing wetland change at landscape scale in Jiangsu Province, China

Human activities produced great impacts on wetlands worldwide. Taking Jiangsu Province, China, as a representative wetland region subject to extensive human activities, the aim of this study is to understand the conversion trajectory and spatial differentiation in wetland change from a multi-scale perspective. Based on multi-temporal Landsat images, it was found that the natural wetlands decreased by 11.2% from 1990 to 2006 in Jiangsu Province. Transition matrices showed that the conversion of natural wetlands to human-made wetlands (mostly aquaculture ponds) was the major form of natural wetland reduction, accounting for over 60% of the reduction. Percentage reduction and area reduc tion of natural wetlands were respectively quantified within different wetland cover zones using a moving window analysis. Average percentage reduction showed a decreasing tendency with increasing wetland cover. The high-cover and mid-cover zone presented the largest area reduction at the scales of 1-2 km and 4-8 km, respectively. Local hotspots of natural wetland reduction were mapped using the equal-interval and quantile classification schemes. The hotspots were mostly concentrated in the Lixiahe marshes and the coastal wetland areas. For the area reduction hotspots, the quantile classification presented larger area and more patches than the equal-interval classification; while an opposite result was shown for the percentage reduction hotspots. With respect to the discontinuous distribution of the natural wetlands, area reduction could be more appropriate to represent reduction hotspots than percentage reduction in the study area. These findings could have useful implications to wetland conservation.     

云南省土壤环境质量分析系统设计与实现

土壤是人类赖以生存的基本要素之一,然而随着我国经济社会的发展,土壤环境污染日益严重,已威胁到各种陆生动植物的生态平衡。为落实环保部《关于加强土壤污染防治工作的意见》要求,2006年云南省土壤污染调查全面启动。系统运用Microsoft Visual Basic作为开发语言,SQL Server作为数据库,Arc GIS作为地图开发工具,来完成数据的导入和校验,统计、评价和对比的分析与查询,以及各类统计图表的自动生成。系统开发解决了庞大数据的管理与分析问题,对数据进行了生动的图表化表示并通过数据自动更新机制,简化了数据的管理工作,提高了《云南省土壤环境质量报告》的编制效率,对各级管理部门的决策工作具有较大的辅助意义。     

危险化工工艺风险辨识方法研究

在安监总局划分的15类危险化工工艺的基础上,参考日本劳动省"六阶段"的定量评价表以及危险度评价法,提出了一种新的危险化工工艺辨识方法.此方法更便于区别化工企业生产工艺是否属于危险化工工艺,从而为政府及企业更好地管理提供便利,进一步实现本质安全化.     

A Bayesian assessment of the effect of highway bypasses in Iowa on crashes and crash rate

Introduction

A common contention is that the construction of highway bypasses negatively impacts the economy of local communities by reducing pass-by traffic for businesses. However, as access to specific business' account records is limited, this impact is difficult to quantify. Another common contention is that bypasses contribute to a reduction in overall crashes in the community and in the surrounding areas. Even though a large number of bypasses have been constructed in the State of Iowa over the past several years, their actual impact in terms of traffic safety has not been quantified.

Objectives

This study seeks answers to the following questions: (a) Are bypasses in Iowa associated with a reduction in crash frequencies and crash rates on the bypassed highway? (b) Do bypasses in Iowa introduce a reduction of overall crash frequencies and rates or do they merely shift crashes from the highways through the communities to the bypasses with no significant overall reduction?

Method

We obtained crash information from the Iowa DOT at 19 sites on which a bypass was constructed sometime during the past 23 years. We also obtained the same information at six sites used as comparison sites on which no bypasses were constructed at least until 2005. We them employed a Bayesian approach to estimating the association between the construction of the bypass and crash rates, while also accounting for other factors.

Results

The construction of bypasses in Iowa is associated with a significant increase in traffic safety both on the main road through town and on the combined main road and bypass roadway.     

Severity models of cross-median and rollover crashes on rural divided highways in Pennsylvania

Introduction

Crossover and rollover crashes in earth-divided, traversable medians on rural divided highways can lead to severe injury outcomes. This study estimated severity models of these two crash types. Vehicle, driver, roadway, and median cross-section design data were factors considered in the models. A unique aspect of the data used to estimate the models were the availability of median cross-slope data, which are not commonly included in roadway inventory data files.

Methods

A binary logit model of cross-median crash severity and a multinomial logit model of rollover crash severity were estimated using five years of data from rural divided highways in Pennsylvania.

Results

The highest probability of a fatal or major injury in cross-median and rollover crashes was found to occur in cases when a driver was not wearing a seatbelt. While flatter cross-slopes and narrower medians were associated with more severe cross-median crash outcomes, steeper cross-slopes and narrower medians significantly increased rollover crash severity outcomes. The presence of horizontal curves was associated with increased probabilities of high-severity outcomes in a median rollover crash.

Impact on Industry

Modeling results in this study confirmed that cross-median and median rollover crash severity outcomes are associated with median cross-section design characteristics. Based on the estimated models, it appears that flatter and narrower medians lead to more severe injury outcomes in cross-median crashes. Steeper median cross-slopes and narrower medians were associated with higher probabilities of more severe outcomes in median rollover crashes. The results presented in this study suggest that there is a trade-off between median cross-section design and cross-median and rollover crashes in earth-divided, traversable medians on rural divided highways. While the severity models can be included in a framework to develop design guidance in relation to this trade-off, models of crash frequency should also be considered.