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161.
Hai Zhao Dexiang Zhang Fangfang Wang Tingting Wu Jinsheng Gao 《Process Safety and Environmental Protection》2008,86(6):448-454
Fe–Mn oxide and Ce-doped Fe–Mn oxide sorbents were studied on the structural and desulfurization behavior in COS removal from syngas. The effects of cerium oxide on the Fe–Mn oxides have been investigated by XRD, BET, TPR, XPS and TEM methods. Analysis data show that the Ce-doped sorbent has larger specific surface area and better particles’ dispersion compared with non-modified Fe–Mn sorbent. The addition of Ce improves the reduction performance of Fe–Mn species. The desulfurization experiments show that the desulfurization activity of sorbent can be increased because of the promotion of the structural and redox properties by ceria doped. The Ce-doped sorbent can reduce COS from 15,000 ppmv to less than 0.1 ppmv at 325 °C and a space velocity of 1000 h−1. 相似文献
162.
羧甲基-β-环糊精对土壤中萘的洗脱去除作用 总被引:5,自引:0,他引:5
研究了不同浓度的羧甲基-β-环糊精溶液对不同组分土壤中萘的洗脱去除作用,同非离子表面活性剂脂肪醇聚氧乙烯醚的洗脱去除作用比较,讨论了其对洗脱效果的影响因素.结果表明:羧甲基-β-环糊精溶液对土壤中的萘有较好的洗脱去除效果,20g·1-1的羧甲基-β-环糊精溶液的洗脱率可达90%以上;洗脱液浓度和土壤质地是影响洗脱去除率的主要因素;适当地增加洗脱液浓度对洗脱去除率有显著提高;与脂肪醇聚氧乙烯醚相比,以羧甲基-β-环糊精溶液作为增溶试剂,对土壤中的弱极性有机污染物进行洗脱处理具有更好的效果 相似文献
163.
为了认识岩溶区石灰土含水介质中化学氧化联合生物降解去除燃油苯系物的效果,以汽油中的苯、甲苯、乙苯和二甲苯(BTEX)作为污染物,通过批实验研究过硫酸盐(PS)联合硝酸盐去除汽油BTEX的效果,并认识不同浓度乙醇(EtOH)存在时带来的影响及化学氧化与反硝化联合修复的可能性.结果表明,在35 d内各组的BTEX去除率均达到91.00%以上,PS化学氧化能有效地去除BTEX.在不含EtOH及含EtOH初始浓度为500和5000 mg·L-1的情况下,BTEX浓度在第65 d时分别为未检出、0.226 mg·L-1、0.243 mg·L-1,去除率分别为99.98%、99.00%、98.70%,其中,苯的去除率分别为99.98%、97.01%、93.32%.随着EtOH浓度的增加,苯的去除受到抑制,EtOH对BTEX的化学氧化具有阻碍作用.石灰土介质中高铁含量对PS具有活化能力,高含量有机质能促进PS分解,并导致pH值回升,出现反硝化作用和硫酸盐还原作用,有利于生物降解作用的恢复. 相似文献
164.
Yunpeng Yu Fanghong Nie Anthony Hay Hongying Lin Yi Ma Xianghong Ju Dongliang Gong Jinjun Chen Ravi Gooneratne 《Environmental monitoring and assessment》2017,189(6):289
Dioxin-like polychlorinated biphenyls (DLPCBs) are ubiquitous persistent pollutants that cause adverse effects in many environmental organisms. DLPCBs in marine sediments can be absorbed by benthic organisms, bioaccumulate, and biomagnify through the food chain and threaten animal and human health. There are no reports of DLPCBs concentrations in the Zhanjiang Gulf seabed. This study was designed to investigate the concentration of DLPCBs in the Zhanjiang coastal sediment and histopathological changes in zebrafish (Diano rerio) embryos exposed to environmentally relevant concentrations of DLPCBs. Of the five sites selected, two sites TS and JSW contained DLPCBs at concentrations of 0.08 and 22.54 ng/g dry sediment, respectively. Two groups of zebrafish embryos were used. One group was exposed to 3.75, 7.5, 15, 30, and 60 mg/ml of DLPCBs extracted from the sediments sampled from the TS site and the second group to 4.375, 8.75, 17.5, 35, and 70 mg/ml of DLPCBs from JSW site from 0.75 h post-fertilization (hpf) to 96 hpf. The zebrafish exposed to 60 and 70 mg/ml of DLPCBs at 96 hpf displayed gross histopathological changes with cardiac lesions including pericardial edema being the most deleterious. Other changes observed were hydropic degeneration of gill filaments and hepatocytes, loss of intestinal folds, and uninflated swim bladder. It appears that only a few sites of the Zhanjiang gulf are contaminated with DLPCBs. This is the first report of histopathological changes in the gills, hepatocytes, intestines, heart, and the swim bladder in zebrafish embryos exposed to DLPCBs from a coastal sediment. Further studies with sampling at different stages of development are required to identify which organ/tissue is most sensitive to DLPCBs. 相似文献
165.
Dynamics of the lakes in the middle and lower reaches of the Yangtze River basin, China, since late nineteenth century 总被引:1,自引:0,他引:1
Lijuan Cui Changjun Gao Xinsheng Zhao Qiongfang Ma Manyin Zhang Wei Li Hongtao Song Yifei Wang Shengnan Li Yan Zhang 《Environmental monitoring and assessment》2013,185(5):4005-4018
The middle and lower reaches of the Yangtze River basin have the most representative and largest concentration of freshwater lakes in China. However, the size and number of these lakes have changed considerably over the past century due to the natural and anthropogenic impact. The lakes, larger than 10 km2 in size, were chosen from relief maps and remotely sensed images in 1875, 1950, 1970, 1990, 2000, and 2008 to study the dynamics of lakes in the middle and lower reaches of the Yangtze River basin and to examine the causes and consequences of these changes. Results indicated that there was a dramatic reduction in lake areas, which decreased by 7,841.2 km2 (42.64 %) during the study period (1875–2008), and the number of lakes in this region changed moderately. Meanwhile, a large number of lakes in the middle and lower reaches of the Yangtze River basin were directly converted into paddy fields, ponds, building lands, or other land-use types over the study period. Therefore, all kinds of lake reclamation should be identified as the major driving factors for the loss of lake in this region. Furthermore, flooding, soil erosion, and sedimentation were also the main factors which triggered lake changes in different periods. Some wetland conservation and restoration projects have been implemented since the 1970s, but they have not reversed the lake degradation. These findings were of great importance to managers involved in making policy for the conservation of lake ecosystems and the utilization of lake resources. 相似文献
166.
Occurrence of organotins in the Yangtze River and the Jialing River in the urban section of Chongqing, China 总被引:2,自引:0,他引:2
Jun-Min Gao Ying Zhang Jin-Song Guo Fen Jin Ke Zhang 《Environmental monitoring and assessment》2013,185(5):3831-3837
The occurrence of organotins in the Yangtze River and the Jialing River in the urban section of Chongqing, China and their impact on drinking water waterworks are reported in this study. Water samples were extracted by solid-phase microextraction and measured using a gas chromatograph with mass spectrometer. The results showed that the rivers studied were polluted by both butyltins and phenyltins and that the butyltin species was the dominant pollutant. Butyltins, especially monobutyltin, were detected in all 18 sampling stations, and phenyltins were detected only in 11 sampling stations. Majority of the organotins were MBTs with concentrations varying from 27.3 to 1,145.8 ng Sn L?1. Diphenyltin and dibutyltin were the second most common with the highest levels of 113.7 and 202.5 ng Sn L?1, respectively. Monophenyltin, tributyltin, and triphenyltin had the lowest detection rates with concentration levels of 9.7, 161.8, and 37.2 ng Sn L?1, respectively. Some of the organotins were also detected in drinking water waterworks, which posed a threat to the water quality of Chongqing. 相似文献
167.
Landscape ecological security assessment based on projection pursuit in Pearl River Delta 总被引:2,自引:0,他引:2
Gao Y Wu Z Lou Q Huang H Cheng J Chen Z 《Environmental monitoring and assessment》2012,184(4):2307-2319
Regional landscape ecological security is an important issue for ecological security, and has a great influence on national
security and social sustainable development. The Pearl River Delta (PRD) in southern China has experienced rapid economic
development and intensive human activities in recent years. This study, based on landscape analysis, provides a method to
discover the alteration of character among different landscape types and to understand the landscape ecological security status.
Based on remotely sensed products of the Landsat 5 TM images in 1990 and the Landsat 7 ETM+ images in 2005, landscape classification
maps of nine cities in the PRD were compiled by implementing Remote Sensing and Geographic Information System technology.
Several indices, including aggregation, crush index, landscape shape index, Shannon’s diversity index, landscape fragile index,
and landscape security adjacent index, were applied to analyze spatial–temporal characteristics of landscape patterns in the
PRD. A landscape ecological security index based on these outcomes was calculated by projection pursuit using genetic algorithm.
The landscape ecological security of nine cities in the PRD was thus evaluated. The main results of this research are listed
as follows: (1) from 1990 to 2005, the aggregation index, crush index, landscape shape index, and Shannon’s diversity index
of nine cities changed little in the PRD, while the landscape fragile index and landscape security adjacent index changed
obviously. The landscape fragile index of nine cities showed a decreasing trend; however, the landscape security adjacent
index has been increasing; (2) from 1990 to 2005, landscape ecology of the cities of Zhuhai and Huizhou maintained a good
security situation. However, there was a relatively low value of ecological security in the cities of Dongguan and Foshan.
Except for Foshan and Guangzhou, whose landscape ecological security situation were slightly improved, the cities had reduced
values in landscape ecological security, with the most decreased number 0.52 in Zhaoqing. Results of this study offer important
information for regional eco-construction and natural resource exploitation. 相似文献
168.
Spatial and seasonal distribution of nitrogen in marsh soils of a typical floodplain wetland in Northeast China 总被引:3,自引:0,他引:3
Bai J Wang Q Deng W Gao H Tao W Xiao R 《Environmental monitoring and assessment》2012,184(3):1253-1263
Horizontal and profile distributions of nitrogen in marsh soils in different seasons were studied in a typical site within
the Erbaifangzi wetland in Northeast China. Results showed that there was higher spatial heterogeneity for nitrate nitrogen
(NO3--_{3}^{-}-N) and ammonium nitrogen (NH4+_{4}^{+}–N), as well as available nitrogen (AN), in surface soils in July compared to that in September. Relative to July, the mean
nitrogen contents in surface soils were slightly higher in September; however, in November, soils contained significantly
lower NO3--_{3}^{-}-N and NH4+_{4}^{+}–N, higher AN, organic nitrogen (Org-N), and total nitrogen (TN). Except for mineral nitrogen, no significant differences
were observed between Org-N and TN contents in September and November. Nitrogen contents generally declined exponentially
with depth along soil profiles in three sampling dates (July, September, and November), except for a significant accumulation
peak of NO3--_{3}^{-}-N at the 20–30 cm depth in September. However, NH4+_{4}^{+}–N contents showed a vertical alternation of “increasing and decreasing” in both July and September, while nearly kept constant
with depth in November. The depth ranking of nitrogen showed the shallowest distribution for AN, followed by Org-N and TN,
while deeper distributions for NO3--_{3}^{-}-N and NH4+_{4}^{+}–N. TN, Org-N, and AN were significantly correlated with soil organic matter and total phosphorus. Soil pH values were significantly
correlated with TN and AN contents in surface soils. Clay contents showed significant correlations with nitrogen contents
except for NO3--_{3}^{-}-N in surface soils and NH4+_{4}^{+}–N in profile soils. However, soil moisture was not significantly correlated with nitrogen contents among all soil samples. 相似文献
169.
Hongxia Gao Yidian Dong Chunyan Meng Weijun Guan Yingli Liu Guizhi Xing 《Environmental monitoring and assessment》2013,185(3):2475-2482
This work aimed to determine the DNA and oxidative damage on mice by mixtures of organic contaminants in wastewater-irrigated soil, in order to assess their usefulness as markers for this kind of pollution. Wastewater-irrigated soil samples in the vicinity of an industrial area in Tangshan, China were collected, and soil irrigated by underground water satisfying drinking water standards was used as control group. Organic pollutants were extracted from the soil using ultrasonic oscillation, and analyzed by gas chromatography–mass spectrometry (GC-MS). Meanwhile, DNA damage on mice was determined by the Comet assay after oral gavage with the extracts, and changes in total superoxide dismutase (T-SOD) activity, glutathione peroxidase glutathione, GSH peroxidase (GSH-PX) activity and malondialdehyde content in serum of mice were investigated. The number of categories and concentrations of organic compounds in the wastewater-irrigated soil is more than those in groundwater-irrigated soil, as identified by the GC-MS. The toxicity test of mice showed that compared with reagent control group, the activities of T-SOD and GSH-PX decreased; the tailing rate of peripheral blood lymphocyte of mice increased and was more than that of the control group. This shows that mammalian toxicity end points can be used to determine the joint toxicity of organic pollutants in soil. When there is no means to identify each and every pollutant in soil, it is feasible to evaluate the combined effects of various pollutants to determine the extent to which the soil is polluted. 相似文献
170.
Xiyong Hou Mingjie Li Meng Gao Liangju Yu Xiaoli Bi 《Environmental monitoring and assessment》2013,185(1):267-277
Annual normalized difference vegetation index (NDVI) and chlorophyll-a (Chl-a) concentration are the most important large-scale indicators of terrestrial and oceanic ecosystem net primary productivity. In this paper, the Sea-viewing Wide Field-of-view Sensor level 3 standard mapped image annual products from 1998 to 2009 are used to study the spatial–temporal characters of terrestrial NDVI and oceanic Chl-a concentration on two sides of the coastline of China by using the methods of mean value (M), coefficient of variation (CV), the slope of unary linear regression model (Slope), and the Hurst index (H). In detail, we researched and analyzed the spatial–temporal dynamics, the longitudinal zonality and latitudinal zonality, the direction, intensity, and persistency of historical changes. The results showed that: (1) spatial patterns of M and CV between NDVI and Chl-a concentration from 1998 to 2009 were very different. The dynamic variation of terrestrial NDVI was much mild, while the variation of oceanic Chl-a concentration was relatively much larger; (2) distinct longitudinal zonality was found for Chl-a concentration and NDVI due to their hypersensitivity to the distance to shoreline, and strong latitudinal zonality existed for Chl-a concentration while terrestrial NDVI had a very weak latitudinal zonality; (3) overall, the NDVI showed a slight decreasing trend while the Chl-a concentration showed a significant increasing trend in the past 12 years, and both of them exhibit strong self-similarity and long-range dependence which indicates opposite future trends between land and ocean. 相似文献