菱镁矿尾矿制备高活性MgO的性能表征

菱镁矿尾矿经预处理后,在一定条件下制备高活性MgO。使用热重-差热分析仪,分析菱镁矿尾矿的分解温度,应用X射线衍射、SEM分析不同煅烧温度、保温时间对MgO晶体结构的影响,并根据Scherrer公式计算MgO晶粒的尺寸。通过电导率仪测定MgO水化电导率,分析不同条件下的MgO活性,探讨煅烧温度、保温时间、颗粒细度与MgO活性之间的关系。结果发现:煅烧温度在1 050℃,保温时间60 min时,菱镁尾矿完全分解,MgO活性最佳;煅烧温度越高,保温时间越长,MgO的活性越差;MgO颗粒细度越小,活性越高。     

林可霉素菌(Streptomyces lincolnensis)利用吡唑酮废水的研究

采用被吡唑酮废液驯化、分离、筛选后的林可霉素菌,并对其在摇瓶上利用吡唑酮废液中的硫酸铵发酵(7 d)生产林可霉素进行了研究。实验结果表明,废液加入培养基体积比都为1∶10,实验1中菌丝代谢和对照比正常,其中还原糖利用最快,在发酵后期为0.24 mg/L,林可霉素起步效价最低为2 100 IU/mL,与对照相比最后发酵效价降低了70 IU/mL;实验2发酵过程pH值偏低,全程为5.86～6.50,氨基氮代谢缓慢为40 mg/100 mL,最后林可霉素效价最低为4 480 IU/mL;实验3中废液在发酵进入48 h中后期的时候补入能促进菌丝体分泌,最后林可霉素为5 180 IU/mL,比对照发酵水平高出8.82%。可见实验3的实验设计有利于林可霉素菌利用吡唑酮废液生产林可霉素,为废物循环利用、变废为宝的可行性作了有意义尝试。     

用含固定化微生物的曝气生物滤池处理炼油厂高浓度废水

采用含固定化微生物的曝气生物滤池(G-BAF)处理炼油厂高浓度废水。当G-BAF池进水COD为298～11 278 mg/L时,出水COD为33.0～94.3 mg/L,COD平均去除率为97%;当G-BAF池进水ρ(NH_3-N)为12.1～188.0 mg/L时,出水ρ(NH_3-N)为0.9～49.4 mg/L,NH_3-N平均去除率为83%。经G-BAF处理后出水水质完全达到GB8978—1996《污水综合排放标准》第二类污染物的二级排放标准。     

Lateral movement of soil fumigants 1,3-dichloropropene and chloropicrin from treated agricultural fields

The soil fumigants 1,3-dichloropropene (1,3-D) and chloropicrin (CP) are often used for controlling soil-borne plant pathogens and parasitic nematodes before reestablishing new vineyards and orchards. To evaluate crop safety and environmental risks with the replant fumigation, four field experiments were performed over 2 yr to examine 1,3-D and CP lateral movement away from the treated fields. Shank injection with or without a virtually impermeable film (V1F) was used in two vineyard fumigation experiments, and spot drip application without tarp cover was used in two orchard experiments. Results showed that 1,3-D and CP gases moved laterally to 6 m from the treated fields when the fumigants were applied by shank injection. The maximum 1,3-D or CP soil gas concentration at 6 m was approximately 10 ng cm(-3) when the fumigated plot was not cover with a tarp. With VIF, the measured maximum concentration increased to approximately 100 ng cm(-3). In the spot drip application, maximum 1,3-D and CP gas concentrations reached approximately 100 ng cm(-3) but at 1.5 m radial distance from the point of fumigant injection.     

Mobility of radium and trace metals in sediments of the Winterbeek: Application of sequential extraction and DGT techniques

For several decades, phosphate ores containing ²²⁶Ra as well as several trace metals have been processed in Belgium to produce calcium phosphate for use in cattle food. The waste water is discharged in two small rivers, the Laak and the Winterbeek.In this study, the levels of ²²⁶Ra and trace metals in surface water and sediments of the Winterbeek were investigated and the mobility of these compounds was assessed using DGT (Diffusive Gradient in Thin Films) and sequential extraction techniques.The concentrations of ²²⁶Ra and trace metals in water and sediment indicate a decreasing trend in inputs to the Winterbeek.The mobility of ²²⁶Ra, assessed by DGT, is related to the reductive mobilization of Fe. The sequential extraction technique shows that at some stations an important fraction of ²²⁶Ra is found to labile sediment phases.Diffusive ²²⁶Ra sediment fluxes, are however, relatively small and have only a minor contribution to the water column concentration of ²²⁶Ra.     

Polybrominated diphenyl ethers and their methoxylated metabolites in anchovy (<Emphasis Type="Italic">Coilia</Emphasis> sp.) from the Yangtze River Delta,China

Background, aim, and scope  

Polybrominated diphenyl ethers (PBDEs) and their metabolites are toxic to animals, and concentrations of the PBDEs metabolites can exceed those of the parent materials. But no information was available on concentrations of PBDEs metabolites in the lower Yangtze River in the region around Jiangsu Province of China, which is heavily urbanized and industrialized area. The aims of this study were to determine whether PBDEs and their methoxylated PBDEs (MeO-PBDEs) were accumulated in Coilia sp. in this area and to investigate the potential sources for these two kinds of brominated organic pollutants.     

Formation of shaped barium sulfate-dye hybrids: waste dye utilization for eco-friendly treatment of wastewater

Purpose

Owing to the present complexity and difficulty of concentrated dye wastewater treatment, this work aimed to synthesize a reproducible waste-sorbing material for the treatment of wastewater by forming the dye-conjugating complex hybrid.

Methods

The inorganic/organic hybridization was applied to prepare the objective material by immobilizing waster dye-Mordant blue 9 (MB) with barium sulfate (BaSO₄). The composition and pattern of the formed material were determined by spectrometry and characterized by SEM and XRD, and their formation process was clarified. The adsorption of cationic dye-basic blue BO (BB) and copper ion was investigated..

Results

The hybrid of MB alone into growing BaSO₄ formed the pineapple-like particles while that of the MB/BB-conjugating complex was the rhombus material. The adsorption of BB on the MB–BaSO₄ hybrid was probably attributed to ion-pair equilibrium and that of Cu²⁺ may result from the complexation. The treatment of dye and heavy metal wastewaters indicated that the MB hybrid material removed 99.8% BB and 97% Cu²⁺ and the dye-conjugating hybrid with growing BaSO₄ 100% MB, 99.5% BB, and 44% Cu²⁺.

Conclusion

The waste MB–BaSO₄ hybrid material is efficient to treat cationic dye and Cu²⁺ wastewater. The dye-conjugating hybridization method is the first to be advanced for in situ wastewater treatment, and it showed a combined effect for the removal of both organic dyes and heavy metals.     

Turning calcium carbonate into a cost-effective wastewater-sorbing material by occluding waste dye

Background, aim, and scope  

Over the years, organic pollution in the environment has aroused people’s concern worldwide, especially persistent organic pollutants (POPs). Particularly in developing countries, plenty of concentrated organic wastewaters treated noneffectively are discharged into aquatic environments from chemical, textile, paper-making, and other industries to seriously threaten the surface and drinking water. The conventional wastewater treatment techniques are often helpless due to high cost with multilevel processing. Adsorption as an efficient method is often applied to the treatment of wastewater. The aim of this work is to develop an eco-friendly and cost-effective wastewater-sorbing material with weak acidic pink red B (APRB) and calcium carbonate (CaCO₃) by reusing highly concentrated dye wastewater.     

不同模糊评价方法在水环境质量评价中的应用比较

近年来,运用模糊评价方法对水质和水体营养化程度进行评价逐渐受到重视。目前,对模糊评价方法的研究多集中在实测数据标准化、权重的确定和模糊模式识别模型研究几个方面。以滇池历年营养物质数据为实测数据,通过对几种实测数据标准化方法、权重确定方法和模糊模式识别方法的组合应用,获得水环境质量模糊评价最优组合方法。结果表明,在评价方法中,实测数据标准化方法采用线性内插法,权重的确定采用超标倍数法,模糊模式识别模型采用广义海明距离和加权海明距离法,即采用超标倍数法的广义海明距离和加权海明距离法能够更真实反映水环境质量的实际情况。     

膨润土接枝丙烯酸高吸水性树脂的抑尘性能研究

在微波辐射下制备了膨润土接枝丙烯酸高吸水性树脂(SAP)(一种加入聚乙烯醇(PVA),另一种不加入PVA)。结果表明:(1)红外光谱图表明,PVA与聚合网络形成了半互穿网络结构;X射线衍射图表明,膨润土与PVA、丙烯酸形成了具有无定形结构的复合产物。(2)不论是沙土堆还是尘土堆,喷洒膨润土接枝丙烯酸SAP溶液的抑尘效果明显比喷洒自来水好;喷洒膨润土接枝丙烯酸SAP溶液的尘土堆的抑尘效果好于沙土堆。(3)在温度为15℃时,考虑到节约成本的问题,首选不加入PVA的膨润土接枝丙烯酸SAP做抑尘剂;在温度为45℃时,加入PVA的膨润土接枝丙烯酸SAP适合做抑尘剂。(4)膨润土接枝丙烯酸SAP浓度越高,其耐蒸发性越高。