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采用巨正则蒙特卡罗方法模拟了CO_2在FAU分子筛上的吸附情况,比较了不同CO_2逸度下,CO_2在分子筛模型上的吸附位、吸附量的变化,拟合了其吸附等温线。结果表明:在吸附饱和状态下,分子筛的孔结构越大,对CO_2的吸附量越大,对于比CO_2分子更小的微孔结构,吸附几乎不发生;在低逸度下,CO_2的吸附主要发生在小孔内,随着逸度的提高,CO_2的吸附量迅速上升;在高逸度下,吸附量的提高主要发生在大孔内;FAU分子筛吸附CO_2的过程符合Ⅰ型Langmuir吸附等温线,在高压下对CO_2的吸附能力远大于低压下的吸附能力。 相似文献
464.
快开门式压力容器是一种广泛应用于建材、纺织、橡胶、医药、食品、玻璃等行业的固定式压力容器,因其结构的特殊性,对安全联锁保护装置和作业人员操作及应急处置能力要求较高,一旦安全联锁装置失效或作业人员应急处置不当,极易发生安全事故。本文针对快开门式压力容器安全管理的法律法规要求、几种典型快开门式压力容器现状及存在问题,从设计、制造、检验、监管等环节提出快开门式压力容器安全管理措施及建议,以确保其安全运行。 相似文献
465.
采用间歇振荡法,研究了钢渣吸附模式、选择性以及等温吸附方程。结果表明,钢渣对阳离子的吸附容量远远大于对阴离子的吸附容量,其吸附模式属于离子交换;其对重金属离子具有一定的吸附选择性,其选择性能与离子的电性、电价、离子半径和水化热等因素有关;钢渣吸附Pb2+是单层吸附,符合Langmuir等温吸附方程。 相似文献
466.
储油罐防腐涂料选用及施工 总被引:1,自引:0,他引:1
储油罐内壁选用导静电涂料,油罐外壁涂料需要较长的防腐年限,所以应选用防锈性好的底漆、面漆.施工过程中应按照规定严格执行涂料施工方法,并经检测达到合格要求,才能保证质量和安全. 相似文献
467.
液化石油气"溢出"的危害及对策 总被引:2,自引:0,他引:2
对液化石油气的性质及危险性进行了论述,分析了溢出后对人员及设备的危害,提出了减轻损失的对策。 相似文献
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Gao J Liu L Liu X Lu J Zhou H Huang S Wang Z Spear PA 《Environment international》2008,34(8):1097-1103
Persistent organochlorine pesticides pollutants (OCPs) have been reported to occur at relatively high concentrations in some Chinese waters. In order to map the distribution of organochlorine pesticides in the surface water throughout China, samples were collected from over 600 sites in seven major river basins and three main internal rivers drainage areas during 2003 and 2004. The surface water samples were analyzed for the representative organochlorine pesticides contaminants including lindane (gamma-HCH), p,p'-DDT and heptachlor epoxide. In general, the most frequently detected compound was lindane, being detected in 83.9% of samples (mean=31.3 ng/l; range <0.17-860 ng/l), and the highest concentration was present in the Yellow River basin. p,p'-DDT was detected in 63.1% of the samples collected (mean=14.6 ng/l; range <0.14-368 ng/l) with the highest concentration present in the Huaihe River basin. Heptachlor epoxide was detected in only 9.3% of water samples (range <0.11-10 ng/l). Measured concentrations for the three compounds were low and rarely exceed the environment quality standard for surface water of China. Lindane was more frequently detected at much higher concentrations in the rivers of northern China compared with those of southern China. The sites with higher concentration of lindane and p,p'-DDT mainly occurred in the Yellow River and Huaihe River basins, so the results of this investigation indicate that the organochlorine pesticide contamination of Yellow River and Huaihe River basins should be of particular concern relative to the other basins. When compared with other regions of the world, it appears that the Chinese surface water is moderately polluted by lindane and p,p'-DDT. 相似文献
470.
Hong Wang Jay Gao Li-Liang Ren Yan Kong He Li Ling Li 《Regional Environmental Change》2013,13(1):115-123
As wildlife habitat is in constant evolution, periodic monitoring is essential to assess its quality. In this study, the change to the red-crowned crane habitat in the Yellow River Delta Nature Reserve was detected from multi-temporal remote sensing data from 1992 to 2008 in a geographic information system. Habitat fragmentation was derived from both physical constraints and human disturbance. The changing habitat quality was assessed against five landscape indices. The results obtained from Landsat TM images indicate that potential habitat shrank 37.9 % during 1992–2001, but recovered 99.4 % by 2008. Suitable habitat shrank by 4,329 ha to a level below that of 1992 despite an increase of 4,747 ha in potential habitat due to an increase of 9,075 ha in fragmented areas. Both landscape indices and the red-crowned crane population reveal that suitable habitat was the most fragmented in 2001, but the least fragmented in 1992. Therefore, it is inadequate to just restore wetland through artificial diversion of channel flow to the Reserve to preserve the crane habitat. Commensurate efforts should also be directed at improving habitat quality by minimizing human activities and spatially juxtaposing water and reed marshes harmoniously inside the Reserve. 相似文献