全文获取类型
收费全文 | 2709篇 |
免费 | 17篇 |
国内免费 | 34篇 |
专业分类
安全科学 | 79篇 |
废物处理 | 141篇 |
环保管理 | 263篇 |
综合类 | 483篇 |
基础理论 | 550篇 |
环境理论 | 2篇 |
污染及防治 | 801篇 |
评价与监测 | 242篇 |
社会与环境 | 179篇 |
灾害及防治 | 20篇 |
出版年
2023年 | 30篇 |
2022年 | 87篇 |
2021年 | 103篇 |
2020年 | 53篇 |
2019年 | 41篇 |
2018年 | 98篇 |
2017年 | 102篇 |
2016年 | 122篇 |
2015年 | 72篇 |
2014年 | 112篇 |
2013年 | 166篇 |
2012年 | 127篇 |
2011年 | 164篇 |
2010年 | 115篇 |
2009年 | 105篇 |
2008年 | 119篇 |
2007年 | 112篇 |
2006年 | 74篇 |
2005年 | 118篇 |
2004年 | 159篇 |
2003年 | 150篇 |
2002年 | 96篇 |
2001年 | 74篇 |
2000年 | 35篇 |
1999年 | 33篇 |
1998年 | 14篇 |
1997年 | 26篇 |
1996年 | 17篇 |
1995年 | 22篇 |
1994年 | 18篇 |
1993年 | 8篇 |
1992年 | 11篇 |
1991年 | 16篇 |
1990年 | 9篇 |
1989年 | 11篇 |
1988年 | 5篇 |
1987年 | 11篇 |
1986年 | 8篇 |
1985年 | 11篇 |
1984年 | 11篇 |
1983年 | 11篇 |
1982年 | 5篇 |
1981年 | 7篇 |
1979年 | 8篇 |
1977年 | 3篇 |
1975年 | 3篇 |
1970年 | 3篇 |
1966年 | 3篇 |
1964年 | 4篇 |
1961年 | 3篇 |
排序方式: 共有2760条查询结果,搜索用时 0 毫秒
111.
Diogenes Meneses José Guimarães F. Júnior Paulo Cesar Costa de Oliveira 《Environmental monitoring and assessment》2018,190(10):617
This work proposes the quantification of Cr (VI) ions in natural waters in trace level, using activated alumina (Al2O3) as preconcentration support, controlled in-line dissolution of the solidified chromophore diphenylcarbazide after heat treatment and spectrophotometric detection. The manifold ensures high sensitivity of analytical response, good repeatability, and stability. In this work, optimization of experimental conditions of a flow injection system was chosen as the parameters for greater sensitivity and better selectivity. The selected optimized conditions were 0.30 mol L?1 for H2SO4 concentration, system flow rate as 0.40 mL min?1, sample injection volume of 192.50 μL, 2 min for preconcentration time, and 0.10 mol L?1 for eluent concentration. The analytical curves obtained for real sample analysis show linear range from 0.192 to 0.961 μM, linear correlation coefficient R?=?0.9997 and LOD?=?0.024 μM. The preconcentration factor of about four times was obtained through the passage of 800 μL of a standard solution containing 0.961 μM of Cr (VI) through mini-column of preconcentration followed by elution at 192.5 μL of NH4OH 0.1 mol L?1 solution. The solid chromogenic reagent presented high durability (weeks in daily use with mass of 0.0993 g) and good reproducibility in analytical signal. The reactivation of the mini-column of alumina should be executed after ten injections of eluent, using 800 μL of HCl 0.02 mol L?1 solution in flow through the same. Each cycle of injection and elution of the sample takes about 5 min on the proposed terms. Despite the length of each cycle still be high, low concentrations can be detected using a technique of relatively low cost. This is due in part, the association dissolution of the chromogenic reagent directly in the line and the preconcentration step. Another important factor is the economy of reagent chromogenic, low generation of reject contributing to better quality of the environment, and the high potential for applications to work in field. 相似文献
112.
José Carlos de Moura Xavier Irany de Andrade Azevedo Wilson Cabral de Sousa Junior Augusto Nishikawa 《Environmental monitoring and assessment》2013,185(2):1463-1471
Atmospheric pollutant monitoring constitutes a primordial activity in public policies concerning air quality. In São Paulo State, Brazil, the São Paulo State Environment Company (CETESB) maintains an automatic network which continuously monitors CO, SO2, NO x , O3, and particulate matter concentrations in the air. The monitoring process accuracy is a fundamental condition for the actions to be taken by CETESB. As one of the support systems, a preventive maintenance program for the different analyzers used is part of the data quality strategy. Knowledge of the behavior of analyzer failure times could help optimize the program. To achieve this goal, the failure times of an ozone analyzer—considered a repairable system—were modeled by means of the nonhomogeneous Poisson process. The rate of occurrence of failures (ROCOF) was estimated for the intervals 0–70,800 h and 0–88,320 h, in which six and seven failures were observed, respectively. The results showed that the ROCOF estimate is influenced by the choice of the observation period, t 0?=?70,800 h and t 7?=?88,320 h in the cases analyzed. Identification of preventive maintenance actions, mainly when parts replacement occurs in the last interval of observation, is highlighted, justifying the alteration in the behavior of the inter-arrival times. The performance of a follow-up on each analyzer is recommended in order to record the impact of the performed preventive maintenance program on the enhancement of its useful life. 相似文献
113.
Nédia de Castilhos Ghisi Marta Margarete Cestari 《Environmental monitoring and assessment》2013,185(4):3201-3207
The glyphosate-based herbicide, Roundup®, is one of the most used pesticides worldwide. In concert with the advent of transgenic crops resistant to glyphosate, the use of this pesticide has led to an increase in agricultural yields. The objective of this study was to evaluate the genotoxic effect that the herbicide Roundup® (at a concentration of 6.67 μg/L, corresponding to 3.20 μg/L glyphosate) can have on the fish Corydoras paleatus. Treatment groups were exposed for 3, 6, and 9 days, and effects were analyzed using the piscine micronucleus test (PMT) and comet assay. A group subjected to filtered water only was used as a negative control. The PMT did not show differences between the control and exposed groups for any of the treatment times. In contrast, the comet assay showed a high rate of DNA damage in group exposed to Roundup® for all treatment times, both for blood and hepatic cells. We conclude that for the low concentration used in this research, the herbicide shows potential genotoxic effects. Future research will be important in evaluating the effects of this substance, whose presence in the environment is ever-increasing. 相似文献
114.
Ponce de León CA DeNicola K Montes Bayón M Caruso JA 《Journal of environmental monitoring : JEM》2003,5(3):435-440
Different techniques have been employed in order to evaluate the most efficient procedure for the extraction of selenium from soil as required for speciation. Selenium contaminated sediments from Stewart Lake Wetland, California were used. A strong acid mineralization of the samples gives quantitative total selenium, which is then used to estimate recoveries for the milder extraction methods. The different extraction methodologies involve the sequential use of water, buffer (phosphate, pH 7) and either acid solution (e.g. HNO3 or HCl) or basic solutions (e.g. ammonium acetate, NaOH or TMAH). Pyrophosphate extraction was also evaluated and showed that selenium was not associated with humic acids. The extractants were subsequently analyzed by size exclusion chromatography (SEC) with UV (254 and 400 nm) and on-line ICP-MS detection; anion exchange chromatography, and ion-pair reversed phase chromatography with ICP-MS detection. For sequential extractions the extraction efficiencies showed that the basic extractions were more efficient than the acidic. The difference between the acidic and the basic extraction efficiency is carried to the sulfite extraction, suggesting that whatever is not extracted by the acid is subsequently extracted by the sulfite. The species identified with the different chromatographies were selenate, selenite, elemental selenium and some organic selenium. 相似文献
115.
Sardine (Sardina pilchardus) spawning seasonality in European waters of the northeast Atlantic 总被引:3,自引:0,他引:3
Yorgos Stratoudakis Stephen Coombs Ana Lago de Lanzós Nicholas Halliday Gersom Costas Bruno Caneco Concha Franco David Conway M. Begoña Santos Alexandra Silva Miguel Bernal 《Marine Biology》2007,152(1):201-212
Egg data from ichthyoplankton monitoring sites in the western English Channel (1988–2003) and northern Spain (1990–2000) and
macroscopic maturity data from biological samples of purse seine landings in western and southern Iberia (1980–2004) are used
to describe the spawning seasonality of sardine (Sardina pilchardus) in European waters of the northeast Atlantic using generalised additive models. The fitted models reveal a double peak in
spawning activity during early summer and autumn in the western Channel, a wider spring peak off northern Spain and a broad
winter season in the western and southern Iberian Peninsula. At all sites, a high probability of spawning activity was observed
over at least 3 months of the year, with the duration of the season increasing with both decreasing latitude and increasing
fish size. Off western and southern Iberia there are indications that the spawning season has been of longer duration in recent
years for all size classes (reaching in some cases 8 months of the year for large fish). These patterns are in general agreement
with existing literature and theoretical expectations of sardine spawning being driven locally by the seasonal cycle of water
temperature, assuming preferences for spawning at 14 –15°C and avoidance for temperatures below 12°C and above 16°C. Regional
quotient plots indicated that spawning tolerance to higher temperatures increases progressively with decreasing latitude.
Despite the weak evidence for geographical differences in temperature tolerance that may have some genetic origin, the degree
of spatio-temporal overlap in sardine-spawning activity within Atlantic European waters is unlikely to promote any reproductive
isolation in that area. 相似文献
116.
de Carvalho Bueno Rafael Bleninger Tobias Yao Huaxia Rusak James A. 《Environmental Fluid Mechanics》2021,21(1):209-237
Environmental Fluid Mechanics - An internal wave is a propagating disturbance within a stable density-stratified fluid. The internal seiche amplitude is often estimated through theories that... 相似文献
117.
The study of Pb(II) binding to the system humic acid/goethite in acidic medium is reported in the present paper. From a macroscopic point of view, we have constructed the experimental sorption isotherms (using atomic absorption spectroscopy) and compared them with the prediction of the additivity rule. It is found that this system presents positive deviations, that is, the amount sorbed is about an order of magnitude higher than predicted. Apart from this, microscopic and structural aspects have also been studied using in situ and ex situ infrared spectroscopy. These results suggest that the presence of Pb(II) increases the amount of humic acid bound to the oxide. It is proposed that proton displacement due to the interaction between humic substances and the oxide, along with the formation of ternary complexes with the Pb(II) cation bridging the oxide and the humic substances (Type A complexes), cause the deviation from additivity. 相似文献
118.
119.
120.
Rachèl V. van Schendel G. C. Page-Christiaens Lean Beulen Catia M. Bilardo Marjon A. de Boer Audrey B. C. Coumans Brigitte H. Faas Irene M. van Langen Klaske D. Lichtenbelt Merel C. van Maarle Merryn V. E. Macville Dick Oepkes Eva Pajkrt Lidewij Henneman for the Dutch NIPT Consortium 《黑龙江环境通报》2016,36(12):1091-1098