硫酸锰废渣浸出毒性及淋溶特性研究

长沙市兴镇13家硫酸锰厂的生产废渣使当地的生态环境造受到了严重破坏。本文在废渣浸出毒性实验、渣柱淋滤实验以及废渣的全分析基础上,全面地研究了废渣的组成、浸出毒性大小以及在当地酸沉降条件下的淋滤特征,为其安全处置提供了理论基础。研究证明,废渣中重金属种类多、含量高,尤其是锰,高达138800mg/kg。渣的浸出毒性虽未达到国家规定的危险废物鉴别标准,但远超过了《污水综合排放标准》,其衰减可用负指数方程来描述。在酸雨淋溶下,渣中的锰离子会在短时期内大量释放后,维持在一相对较低水平长期释放,对环境威胁巨大。     

中孔分子筛Al-MCM-41催化裂解聚烯烃反应研究

采用水热合成法制备了不同硅铝比的中孔分子筛A l-MCM-41,将其应用于高密度聚乙烯(HDPE)和聚丙烯(PP)的催化裂解反应。通过改变硅铝比、反应温度和催化剂用量,对A l-MCM-41催化HDPE和PP裂解反应的规律进行了探讨,研究表明,HDPE裂解反应受硅铝比的影响较大;而对于PP裂解反应,硅铝比在一定范围内对催化剂活性的影响不明显。另外,与热裂解和HZSM-5小孔分子筛的催化裂解结果进行了比较,结果证明A l-MCM-41具有较高的催化活性和较高的液体产物收率,尤其适合于空间位阻较大的PP的催化裂解反应。     

Interaction between β-lactam antibiotic and phosphorus-accumulating organisms

Environmental Science and Pollution Research - β-Lactam antibiotics have been widely used in clinic due to strong antibacterial activity with mild adverse side effects and have been detected...     

Hydrochemical characteristics and identification of pollution ions of the springs in the south of Yanbian City,China

Environmental Geochemistry and Health - Mathematical statistics, correlation analysis, Piper and Gibbs diagrams, and geographic information system- based multi-criteria decision analysis were used...     

安徽省水质自动监测站点位优化方法研究

文章分析了安徽省现有水质自动监测站布设情况和国内外相关研究情况,指出了现有水质自动监测站建设的不足之处,明确了水环境质量预警和水质断面目标考核两个优化布设目标。就水质自动监测站点位优化的筛选方法进行研究与讨论,提出“理论筛选一现场调研一综合打分”三步走策略,在此基础上提出了水质自动监测站布点三级指标体系。并采用德尔斐法确定权重,建立了合理性综合指数评价体系细则,为环境管理提供了参考。     

几种水环境质量评价方法在青海湖入湖河流中的应用

从众多的水环境质量评价方法中,选取代表性的指数评价法、灰色评价法、层次分析法和模糊数学法进行介绍,然后运用这些方法对青海湖入湖河流2010年监测数据进行评价。经过对比分析评价结果发现,本次评价研究中单因子评价法过于悲观,水质综合污染指数法具有不可比性,模糊数学法具有不准确性。四种水环境质量评价方法中,灰色评价法和层次分析法是最适合该流域的评价方法,指数评价法和模糊数学法可以作为其必要的补充。     

Measurement of atmospheric nanoparticles: Bridging the gap between gas-phase molecules and larger particles

Atmospheric nanoparticles are crucial components contributing to fine particulate matter(PM2.5), and therefore have significant effects on visibility, climate, and human health. Due to the unique role of atmospheric nanoparticles during the evolution process from gas-phase molecules to larger particles, a number of sophisticated experimental techniques have been developed and employed for online monitoring and characterization of the physical and chemical properties of atmospheric nanoparticles,...     

双酚类化合物的毒理学效应及微生物降解机制的研究进展

双酚类化合物作为重要的有机化工原料,广泛应用于各行各业。然而双酚类化合物是一类内分泌干扰物,毒性评价结果表明其与许多疾病发病率的升高密切相关。伴随双酚类化合物的大量使用,诸多环境样品中都检测出双酚类化合物。由于双酚类化合物的结构稳定,很难在自然界中被完全降解,会不断累积,对生态安全和人体健康产生危害,亟待有效修复。有机污染物的物理化学修复方法易对环境造成二次污染,微生物降解因其获取容易、无二次污染等特点成为双酚类化合物修复的有效途径。本文总结概述了几种典型双酚类化合物的毒性评价及微生物降解机制。     

Research on ammonia emissions characteristics from light-duty gasoline vehicles

In this study, ammonia emissions characteristics of typical light-duty gasoline vehicles were obtained through laboratory vehicle bench test and combined with New European Driving Cycle (NEDC) condition and Worldwide Harmonized Light Vehicles Test Cycle (WLTC) condition. The influence of ambient temperature on ammonia emissions is mainly concentrated in the cold start stage. The influence of ambient temperature on ammonia emission is shown that the ammonia emissions of light-duty gasoline vehicles under ambient temperature conditions (14 and 23°C) are lower than those under low ambient temperature conditions (?7°C) and high ambient temperature conditions (35 and 40°C). The influence of TWC on ammonia emission is shown that ammonia is a by-product of the catalytic reduction reaction of conventional gas pollutants in the exhaust gas in the TWC. Under NEDC operating conditions and WLTC operating conditions, ammonia emissions after the catalyst are 45 times and 72 times that before the catalyst, respectively. In terms of ammonia emissions control strategy research, Pd/Rh combination can reduce NH₃ formation more effectively than catalyst with a single Pd formula. Precise control of the engine's air-fuel ratio and combination with the optimized matched precious metal ratio TWC can effectively reduce ammonia emissions.