Regeneration of spent organoclays after the sorption of organic pollutants: A review

Clay minerals modified with organic ions, also known as organoclays, have found applications in a wide range of organic pollution control fields because of their excellent sorption capacity towards organic pollutants. Regeneration of the spent organoclays after the sorption of organic pollutants is of great importance during their application in pollution control. In this review, the reported methods for the regeneration of the spent organoclays are summarized, including biological degradation, photo-assisted oxidation, chemical extraction/desorption, supercritical extraction, thermal desorption, et al. The characteristics and applications of these methods are briefly described. It shows that most of these methods have been developed for regenerating spent organoclays from wastewater treatment. The biological regeneration method, as an in situ, low cost and easy-operating method, is applicable for regenerating spent organoclays not only from wastewater treatment, but also from soil and groundwater remediation.     

20世纪80年代以来洪湖流域营养物质输移模拟研究

选择位于长江中游的洪湖流域作为研究对象，应用流域分布式水文模型SWAT，探讨现代农业条件下流域面源营养盐输移的规律。模拟时段选择为1983～2002年。模拟的边界条件设置为自然地形、土壤、现代农业生产及土地利用方式，其中土壤资料包括营养盐（N和P）、有机质含量、粒径等理化参数。径流量与营养盐输出模拟结果与实测值有较好的吻合程度，可以通过置信度95％的显著性检验。模拟结果显示，现代农业条件下流域营养盐输出，TN和TP浓度变化有明显的季节特征，体现了区域耕作方式、径流对营养盐输出浓度的影响。模拟时段内营养盐输出浓度呈明显增长趋势，体现了农药化肥的施用对流域营养盐输移的影响。     

Biomarkers responses of the earthworm Eisenia fetida to acetochlor exposure in OECD soil

To examine the potential of a suite of biomarkers as early warning indicators of environmental pollution, sperm count, neutral red retention time (NRRT) and DNA damage were measured in earthworm Eisenia fetida exposed to increasing concentrations of acetochlor in OECD soil. The neutral red retention time of earthworms coelomocytes was sensitive to acetochlor pollution, and decreased significantly when the concentration was more than 10mgkg(-1) after 30 and 60 days of exposure (P<0.05). The reduced neutral red retention time correlated with the soil acetochlor residual. Sperm count decreased significantly at the concentrations of 40 and 80mgkg(-1) after 15 days of exposure (P<0.05). The DNA damage of earthworms coelomocytes increased significantly after 30 days of exposure at the highest concentration (80mgkg(-1); P<0.05). Earthworms were under physiological stress at field dose of acetochlor (10mgkg(-1)). Higher concentrations of acetochlor caused sperm count decrease and DNA damage of earthworms. Such a suite of biomarkers could serve as indicators of the health of the soil environment and to evaluate the toxicity of acetochlor on earthworms or as a means of monitoring soil acetochlor pollution.     

基于格局-过程理论的非点源污染实证研究:以黄土丘陵沟壑区水土流失为例

非点源污染是影响地表环境的主要污染方式之一.针对黄土高原丘陵沟壑区水土流失这一典型的非点源污染问题,应用非点源污染的空间识别方法———景观空间负荷对比指数和景观坡度指数,对黄土高原泾河流域12个子流域进行了实证研究.结果表明,耕地、低覆盖度草地和各种林地的景观坡度指数和景观空间负荷对比指数对流域土壤侵蚀模数有显著的响应关系,对径流深度存在着一定的响应关系,而对径流变异系数和侵蚀变异系数没有明显的响应.说明景观空间负荷对比指数和景观坡度指数对流域水土流失具有一定的指示作用,可作为水土流失等非点源污染空间风险评价的1个有用方法.     

Mining development,income growth and poverty alleviation: A multiplier decomposition technique applied to China

Mining has grown rapidly and is expected to continue to develop solidly in the future with the economic development in China. Based on this trend, how an increase in the outputs of mining sectors affects household income and poverty alleviation is an issue worthy of study. A multiplier decomposition method within a social accounting matrix (SAM) framework shows the linkages through which a mining sector's output contributes to household income growth and poverty alleviation. The decomposition applied to China reveals that mining development has more significantly positive impacts on the high and middle income household than low income household. Moreover, the decomposition incorporated with the Foster, Greer and Thoerbecke (FGT) poverty measure shows that the ‘coal’ sector contributes most to poverty alleviation and the low income household group, which has the biggest poverty rate, is the smallest beneficiary from the mining development. Thus, the policy implication is proposed that the government should give appropriate adjustment on the distribution of income between rich and poor households and help the unskilled human capital from the household group at a low income level to handle advanced technology of mining through education and training to reduce poverty more effectively.     

PM_(2.5)和甲醛联合暴露致小鼠肺损伤及其分子机制的研究

我国城市当前普遍存在室外大气PM_(2.5)与室内甲醛(FA)联合污染状况,二者均被报道在单独暴露下可以导致肺损伤并诱导和诱发哮喘的急性发作,但其联合污染的具体效应,以及分子机制目前尚不清楚。为探究PM_(2.5)和/或甲醛暴露对小鼠的肺损伤及其可能的机制,分别将雄性Balb/c小鼠分为以下6组:对照组,AZD8055组,PM_(2.5)组,FA组,PM_(2.5)+FA组,PM_(2.5)+FA+AZD8055组。染毒结束后,观察肺组织病理学变化;检测肺组织氧化损伤,活性氧(reactive oxygen species,ROS),还原型谷胱甘肽(glutathione,GSH)和丙二醛(malondialdehyde,MDA)的含量,DNA损伤,DNA-蛋白质交联(DNA-protein crosslink,DPC)系数和8羟基脱氧鸟苷(8-OH-d G)的含量,以及细胞凋亡、半胱氨酸天冬氨酸蛋白酶-3(Caspase-3)的含量。结果表明,当吸入气态甲醛浓度为3 mg·m-3,气道滴注PM_(2.5)浓度为2.5 mg·m L-1时,肺组织出现不同程度的支气管重塑和炎症细胞浸润。ROS显著上升,GSH显著下降,DPC、8-OH-d G以及Caspase-3都显著上升。添加AZD8055后,肺组织损伤效应更加显著。PM_(2.5)复合甲醛的暴露导致小鼠肺损伤具有协同作用,氧化应激及其下游的DNA损伤可能是甲醛联合PM_(2.5)致小鼠肺损伤的一种重要机制。     

松嫩高平原土地利用格局变化时间尺度特征研究

土地利用格局变化的时间尺度是其尺度依赖性和敏感性表达的重要基础。论文以松嫩高平原典型区域巴彦县为研究区,运用GIS、RS技术,结合Matlab编程,采用K-L变换将多波段的遥感影像提取为单波段图像作为原始信号数据,在研究区土地利用格局最优空间尺度下,应用快速傅里叶变换对小波分析模型进行改进,探寻研究区土地利用格局变化研究的适宜时间尺度,进而明确适宜时空尺度下土地利用格局变化的波动性特征,并采用土地利用转移矩阵对其时间尺度的划分结果进行检验。结果表明：1）研究区土地利用格局变化在10~20、30~40和40~50 a均有明显的波动性特征,表明10~20、30~40和40~50 a是研究区土地利用格局变化的3个重要时间尺度。2）1979—2015年研究区土地利用格局变化研究的最优时间分析尺度为36 a,土地利用格局在12.33 a左右具有明显的波动性变化特征,可将研究区时间域划分为3个发展阶段：发展初期1979—1991年、发展中期1991—2003年、发展近期2003—2015年。3）在空间上,研究区土地利用格局变化的全局化时间尺度和土地利用格局变化的局部化时间尺度具有较高水平的一致性。4）论文建立的基于小波分析的土地利用格局变化时间尺度识别方法可行并具有准确性,研究区旱地、林地和建设用地等主要土地利用类型在1979、1991、2003和2015年4个重要时间节点上的变化发生了明显的趋势性转换。     

Distribution of Organo-Chlorine Pesticides (DDT and HCH) Between Plant and Soil System

This paper reports a study of the distribution of organo-chlorine pesticides (DDT and HCH) between rice plants and the soil system by spraying before the heading stage at four different dosage levels – control, normal dosage (15 kg ha^–1 of 6% HCH and 7.5 kg ha^–1 of 25% DDT), double dosage and four times dosage. Soil and plant samples were taken respectively at the 1st h, 3rd, 10th, 20th, and 40th day after spraying and at the harvest time. The results indicate that less than 5% of HCH and 15% of DDT were absorbed by the surface of rice leaves for normal dosage. Most of both pesticides moved into the soil in solution after spraying. Compared with DDT, HCH was degraded and run off more easily. HCH residues in the surface soil layer (1–3 cm) were already below 6.4 g kg^–1 at the mature stage, lower than Chinese Environmental Quality Standard for Agricultural Soils: HCH <0.05 mg kg^–1. However DDT residues in the surface soil layer remained 172 g kg^–1, higher than the national standard: DDT <0.05 mg kg^–1. According to the test f OCP residues in rice seeds, it can be concluded that the OCP sprayed onto the surface of rice leaves can move into rice plants and accumulate in the seeds at the mature stage. HCH residues in rice seeds of the double and four times dosage treatments, and DDT residues in all treatments, exceeded the Chinese National Food Standard (HCH <0.10 mg kg^–1, DDT <0.20 mg kg^–1).     

面向防洪救灾的人口空间分布模拟——以大安市为例

人是最重要的受灾体，准确的人口空间模拟是衡量洪涝灾情和实施防灾救灾的重要依据。利用遥感数据模拟人口空间分布需解决两大难题：（1）居民地类型、面积、位置的精确获取；（2）居民地类型、面积与人口数量的关系。基于地理意义和数学意义，对经典的城市人口一面积异速生长模型进行了扩展，导出了城乡人口一面积统一模型；并以大安市为例，建立了居民地分类体系，以1：5万地形图为辅助数据，利用ETM影像提取居民地信息，在上述模型的基础上建立了人口分布的反演模型，模拟人口的空间分布。通过精度评价，进一步证明了基于遥感数据的人口统计数据空间化的研究思路是切实可行的。     

中国中老年男性全血比粘度参考值与海拔高度的曲线模型分析

目的：为制定中国中老年男性全血比粘度参考值的统一标准提供科学依据,方法：收集了中国３１２个单位用毛细管法测定的２１２７７例健康中老年男性全血比粘度参考值,用曲线回归分析的方法研究了其与海拨高度之间的关系。结果：发现随着海拨高度的逐渐增大,中老年男性全血比粘度参考值按指数律也在逐渐的增大,相关性很显著（Ｒ＝０．７８４）;推导出了一个曲线回归模型＾Ｙ＝４３５×１０００１２９ｘ±０９３。结论：如果知道了中国某地的海拨高度,就可以用回归模型估算这个地区的中老年男性全血比粘度参考值,依据中老年男性全血比粘度参考值与地理因素的依赖关系把中国分为青藏区,中部区,东部区等三个区