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511.
The results of the chemical analysis of soil samples from WWI munition plants showed that the most important compounds are dinitrobenzenes, trinitrotoluene and metabolites, and dinitronaphthalenes. The presence of 1,2-dinitrobenzene and 1,3-dinitrobenzene in soil samples shows that, during the production of dinitrobenzenes, in WWI, the raw dinitrobenzene was not washed with sulphite. The results show that the parameter list must be different from the parameter list for the analysis of soil samples from munition plants of WW II. 相似文献
512.
Robert E. Lee Jr. Darryl J. von Lehmden 《Journal of the Air & Waste Management Association (1995)》2013,63(10):853-857
Trace metals introduced to the environment from fuel combustion, incineration, and industrial emission sources are causing increasing concern to air pollution researchers. Several metals in urban air, including lead and vanadium, are associated with particles in the predominantly submicrometer diameter range thereby presenting an inhalation threat. There is also growing evidence that some metals emitted from stationary sources are concentrated in submicrometer sized particles which may pass through emission control devices. This report summarizes the concentration and size of trace metals in urban air, the concentration ranges found in selected fuels and emission sources, and describes the areas where further studies are needed. 相似文献
513.
Kateřina Kolaříková Wolf von Tümpling Peter Bartels 《Environmental monitoring and assessment》2013,185(5):4333-4346
Sediments of the Elbe River have been extremely polluted by contaminants originating from previous large-scale hexachlorocyclohexane (HCH) production and the application of γ-HCH (lindane) in its catchment in the second half of the twentieth century. In order to gain knowledge on bioaccumulation processes at lower trophic levels, field investigations of HCHs in macroinvertebrates were carried out along the longitudinal profile of the Elbe and tributary. Among the sites studied, concentrations in macroinvertebrates ranged within five orders of magnitude (0.01–100 μg/kg). In general, lower values of HCH isomers were observed at all Czech sites (mostly <1 μg/kg) compared with those in Germany. At the most contaminated site, Spittelwasser brook (a tributary of the Mulde), extremely high concentrations were measured (up to 234 μg/kg α-HCH and 587 μg/kg β-HCH in Hydropsychidae). In contrast, the Ob?íství site, though also influenced by HCH production facilities, showed only negligibly elevated values (mostly <1 μg/kg). Results showed that fairly high levels of α-HCH and β-HCH compared to γ-HCH can still be detected in aquatic environments of the Elbe catchment, and these concentrations are decreasing over time to a lesser extent than γ-HCH. Higher HCH concentrations in sediments in the springtime are considered to be the result of erosion and transport processes during and after spring floods, and lower concentrations at sites downstream are thought to be caused by the time lapse involved in the transportation of contaminated particles from upstream. In addition, comparison with fish (bream) data from the literature revealed no increase in tissue concentrations between invertebrates and fish. 相似文献
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Thomas Hari Roland von Arx Hans Ulrich Ammon Georg Karlaganis 《Environmental science and pollution research international》1996,3(1):32-38
The primary aim of this study was to evaluate the “clearance concept” as a tool for describing the behavior of xenobiotic movement into and through soils. As an example, degradation of 2-chloro-4-ethylamino-6-isopropylamino-s-triazine (atrazine) with the formation of metabolites 2-chloro-6-isopropylamino-s-triazine (desethylatrazine) and 2-chloro-4-ethylamino-s-triazine (desisopropylatrazine) was investigated. Atrazine was sprayed post-emergently in doses of 0.125 or 0.5 g active ingredient/m2 each on four test plots. Soil type was a sandy-loam, on which corn (Zea mays L.) was cultivated. Soil samples were taken as cores of 0.2 m depth 0, 1, 2, 4, 8, 12, 16 and 20 weeks after application of atrazine, and analyzed by HPLC. Soil concentrations of atrazine were highly correlated (r=0.993, p< 0.001) between the two applications of 0.125 g/m2 and 0.5 g/m2. Up to 50% of the atrazine was measured as metabolites during the whole vegetation period. Clearance of atrazine from soil was calculated as the total load of atrazine divided by the area under the soil atrazine concentration time curve. Soil atrazine clearance was calculated as 5.13 +/? SD 1.10 and 5.17 +/? SD 1.02 liter of soil per day for doses of 0.125 g/m2 and 0.5 g/m2, respectively (from a “soil unit” of 1 × 1 × 0.2 meter). The clearance concept might be a tool for risk assessment of xenobiotics. 相似文献
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517.
Wolf von Tümpling Peter Zeilhofer Ulrich Ammer Jürgen Einax Rolf -D. Wilken 《Environmental science and pollution research international》1995,2(4):225-228
As in many other parts of the world, gold is produced in the surface mining region of Poconé, Mato Grosso, Brazil, using mercury.
The goal of this investigation was to estimate the amount of mercury in certain tailings and to determine the area of the
land that has been contaminated by the gold mining operations. Mercury concentrations from 2 to 495 ng/g (dw) were determined
in the tailing materials. It was observed that only isolated sites were acting as central points of contamination. Using digital
Landsat satellite data (The-matic Mapper) and aerial photos, the sites degraded by the mining were classified, and their total
area was estimated to be 12.3 km2 in the region of Poconé. It was estimated, that 4.9 km2 were occupied by the contaminated tailings. The mean height of the pile slags was determined to be 4.5 m. From the experimentally
calculated average density of the material in the tailings, 2.01 g/cm3, the total mercury content in the piles of tailings was estimated to be 1600 ± 350 kg. 相似文献
518.
von Tiedemann A Weigel HJ Jäger HJ 《Environmental pollution (Barking, Essex : 1987)》1991,72(3):205-224
Spring wheat (Triticum aestivum L. cv. Turbo) was exposed in open-top chambers to six different ozone levels (8-h daily means from 12.4 to 122 microg m(-3)), to non-filtered air and to chamberless field conditions for 31 days from seedling stage through ear emergence. Powdery mildew (Erysiphe graminis DC. f.sp. tritici Marchal) which developed during the exposure period was significantly enhanced from 0.3/0.6% (two chamber replicates), 1.2/2.1%, 0.9/2.2% in charcoal-filtered air (CF) to 1.5/1.6%, 3.7/4.3%, 4.4/4.6% at the highest level of ozone, on the flag leaf, second and third leaf position, respectively. Post-exposure inoculation with Septoria nodorum Berk. led to increases of disease severity on the flag leaf from 40.9/43.6% in CF to 66.3/70.6% at the highest ozone concentration and on the ears from 15.7/16.5% to 26.3/26.6%. In the same comparison, severity of spot blotch following inoculation with Bipolaris sorokiniana (Sacc.) Shoem. (syn. Helminthosporium sativum Pamm., King et Bakke) was increased on the flag leaf from 3.6/8.9% to 12.3/23.4%. The three diseases examined correlated significantly with the ozone treatments in fumigated chambers. Disease severity was enhanced even on undamaged plant tissue (flag leaves). Infections of the two facultative pathogens on lower leaf positions started only in part from visible ozone lesions, mildew did not start from such lesions. No significant effects of ozone in the chambers on the saprobial colonization of the phyllosphere were detected, whereas there were marked differences in this respect between plants from the field and the chambers. At the highest ozone treatment, contents of chlorophyll a and carotenoids on the second leaf position declined significantly, which was associated with symptoms of premature senescence. Senescing effects of ozone are therefore assumed to be one major factor in predisposing wheat for necrotrophic leaf pathogens. Surprisingly, injurious and predisposing effects of ozone were completely absent in chambers supplied with non-filtered air containing ambient ozone at doses equivalent to those in CF + ozone chambers. Evidently, biological effects of ozone in pure air and in ambient air may differ markedly. 相似文献
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520.