Development and validation of a method for determination of trace levels of alkylphenols and bisphenol A in atmospheric samples

A method has been developed and validated in order to assess the occurrence of the alkylphenols tert-octylphenol and the isomers of technical nonylphenol as well as bisphenol A in gasphase and aerosol samples of a remote area. Gasphase samples were adsorbed to XAD2 resin, aerosol samples were taken on glass fiber filters. After ultrasonic extraction, clean-up by column chromatography and silylation of the analytes, ten nonylphenol peaks were quantified separately using a GC-MSD-SIM method. The absolute limits of detection and determination are in the range of a few pg per compound, which is a prerequisite for the quantification of the analytes in relatively unpolluted air. The precision of the whole analytical method is in the range of 1-17% and the recoveries range from 57% to 80%. Problems were encountered during method development due to the tendency of the analytes to sorb to glass surfaces. Silanisation of glassware was crucial to achieve acceptable recoveries. The widespread use of the analytes in plastic resins resulted in sample contamination. For this reason a careful choice of sampling material was necessary. Measured concentrations in gasphase samples (lower nanogram per m3 range) and aerosol samples (upper picogram per m3 range) are one to three orders of magnitude below already published concentrations.     

Das Problem der Krebsverbreitung und Krebsbekämpfung

The Science of Nature -     

Implications of uncertainty and scale in carbon emission estimates on locally appropriate designs to reduce emissions from deforestation and degradation (REDD+)

This study combined uncertainty analysis of carbon emissions with local stakeholders' perspectives to develop an effective Reducing Emission from Deforestation and Degradation (REDD+) scheme at the district level. Uncertainty of carbon emission estimates depends on scale while local stakeholders' views on plausible REDD+ schemes influence and limit transaction costs. The uncertainty analysis formed the basis for determining an appropriate scale for monitoring carbon emission estimates as performance measures for REDD+ incentives. Our analysis of stakeholder’ perspectives explored (i) potential location and activities for lower emission development pathways, and (ii) perceived fair allocation of REDD+incentives. Our case study focused on frontier forest in Tanjung Jabung Barat District, Jambi, Indonesia. The uncertainty analysis used Monte Carlo simulation techniques using known inaccuracy of land cover classification and variation in carbon stocks assessment per land cover type. With decreasing spatial resolution of carbon emission maps, uncertainty in carbon estimates decreased. At 1 km² resolution uncertainty dropped below 5 %, retaining most of the coarser spatial variation in the district. Fairness, efficiency and transaction cost issues in the design of REDD+ mechanisms were readily recognized by local stakeholders, who converged on an equal allocation to short-term efficiency (emission reduction activities) and long-term fairness (alternative livelihood development). A striking difference occurred in desirable transaction costs (which include monitoring, reporting and verification), with Non-Governmental Organizations (NGOs) aiming for 8 %, while government and researchers accepted transaction costs of 40 %. Feasible measures for emission reduction in the district, derived from a participatory planning process, are compatible with the 1 km² spatial resolution of performance measures.     

An approach for particle sinking velocity measurements in the 3–400?μm size range and considerations on the effect of temperature on sinking rates

The flux of organic particles below the mixed layer is one major pathway of carbon from the surface into the deep ocean. The magnitude of this export flux depends on two major processes—remineralization rates and sinking velocities. Here, we present an efficient method to measure sinking velocities of particles in the size range from approximately 3–400?μm by means of video microscopy (FlowCAM^?). The method allows rapid measurement and automated analysis of mixed samples and was tested with polystyrene beads, different phytoplankton species, and sediment trap material. Sinking velocities of polystyrene beads were close to theoretical values calculated from Stokes’ Law. Sinking velocities of the investigated phytoplankton species were in reasonable agreement with published literature values and sinking velocities of material collected in sediment trap increased with particle size. Temperature had a strong effect on sinking velocities due to its influence on seawater viscosity and density. An increase in 9?°C led to a measured increase in sinking velocities of ~40?%. According to this temperature effect, an average temperature increase in 2?°C as projected for the sea surface by the end of this century could increase sinking velocities by about 6?% which might have feedbacks on carbon export into the deep ocean.