全文获取类型
收费全文 | 284篇 |
免费 | 0篇 |
专业分类
安全科学 | 2篇 |
废物处理 | 6篇 |
环保管理 | 8篇 |
综合类 | 125篇 |
基础理论 | 50篇 |
污染及防治 | 68篇 |
评价与监测 | 11篇 |
社会与环境 | 12篇 |
灾害及防治 | 2篇 |
出版年
2021年 | 3篇 |
2018年 | 9篇 |
2017年 | 4篇 |
2015年 | 7篇 |
2014年 | 13篇 |
2013年 | 7篇 |
2012年 | 7篇 |
2011年 | 5篇 |
2010年 | 12篇 |
2009年 | 11篇 |
2008年 | 8篇 |
2007年 | 9篇 |
2006年 | 9篇 |
2005年 | 8篇 |
2004年 | 7篇 |
2003年 | 8篇 |
2002年 | 8篇 |
1998年 | 7篇 |
1996年 | 7篇 |
1995年 | 3篇 |
1993年 | 4篇 |
1979年 | 2篇 |
1971年 | 2篇 |
1969年 | 2篇 |
1966年 | 3篇 |
1965年 | 5篇 |
1964年 | 2篇 |
1963年 | 7篇 |
1962年 | 4篇 |
1961年 | 3篇 |
1960年 | 2篇 |
1959年 | 5篇 |
1958年 | 5篇 |
1957年 | 3篇 |
1956年 | 10篇 |
1955年 | 7篇 |
1954年 | 3篇 |
1953年 | 3篇 |
1952年 | 2篇 |
1950年 | 2篇 |
1949年 | 2篇 |
1947年 | 2篇 |
1942年 | 2篇 |
1940年 | 2篇 |
1939年 | 4篇 |
1934年 | 3篇 |
1933年 | 2篇 |
1929年 | 2篇 |
1925年 | 2篇 |
1918年 | 2篇 |
排序方式: 共有284条查询结果,搜索用时 15 毫秒
1.
Only three decades ago it was thought inconceivable that organic compounds could transport electric charges like metals do. However, recently organic molecules exhibiting high conductivities have been synthesized. Some examples of organic conductors are presented together with the present status of this research which is both interesting to chemists and physicists. Some applications of organic conductors are discussed. 相似文献
2.
3.
4.
5.
6.
7.
Impact of Land Use on Soluble Organic Nitrogen in Soil 总被引:5,自引:0,他引:5
Victoria B. Willett James J. Green Andrew J. Macdonald John A. Baddeley Georg Cadisch Steven M. J. Francis Keith W. T. Goulding Gary Saunders Elizabeth A. Stockdale Christine A. Watson David L. Jones 《Water, Air, & Soil Pollution: Focus》2004,4(6):53-60
Although it has been hypothesized that soluble organic nitrogen (SON) plays a central role in regulating productivity in some terrestrial ecosystems, the factors controlling the size of the SON pool in soil remain poorly understood. Therefore our principal aim in this work was to assess the impact of seven different land use systems (rough and managed grassland, deciduous and coniferous woodland, heathland, wetland and tilled land) on the size of the SON and inorganic N (NO
3
–
, NH
4
+
) pools in the surface soil layer (0–15 cm). After extraction with deionised water, we found that in most cases the size of the water extractable organic N (WEON) pool was similar in size to the inorganic N pool. In contrast, the KCl extractable organic N (KClEON) pool constituted the dominant form of soluble N in soils under all land uses, perhaps indicating that significant amounts were held on the soil exchange phase. In contrast to inorganic N, which varied significantly with land use, the size of the KClEON and WEON pool was similar for all land uses with the exception of KClEON in tilled land, where significantly lower amounts were observed. We conclude that SON constitutes an important soil N pool in a broad range of land uses, and that its role in microbial N assimilation, plant nutrition and ecosystem responses to atmospheric N deposition warrants further attention.
SAFRD, University of Newcastle, Newcastle-upon-Tyne, NE1 7RU, U.K. 相似文献
8.
Boy Jens Strey Simone Schönenberg Regine Strey Robert Weber-Santos Oscarlina Nendel Claas Klingler Michael Schumann Charlotte Hartberger Korbinian Guggenberger Georg 《Regional Environmental Change》2018,18(1):63-75
Regional Environmental Change - Soil carbon stocks of 29 plots along a transect through tropical Brazil showed only minor soil carbon losses after land use shift, although replacement of... 相似文献
9.
In Latin America and the Caribbean, river restoration projects are increasing, but many lack strategic planning and monitoring. We tested the applicability of a rapid visual social–ecological stream assessment method for restoration planning, complemented by a citizen survey on perceptions and uses of blue and green infrastructure. We applied the method at three urban streams in Jarabacoa (Dominican Republic) to identify and prioritize preferred areas for nature-based solutions. The method provides spatially explicit information for strategic river restoration planning, and its efficiency makes it suitable for use in data-poor contexts. It identifies well-preserved, moderately altered, and critically impaired areas regarding their hydromorphological and socio-cultural conditions, as well as demands on green and blue infrastructure. The transferability of the method can be improved by defining reference states for assessing the hydromorphology of tropical rivers, refining socio-cultural parameters to better address river services and widespread urban challenges, and balancing trade-offs between ecological and social restoration goals.Supplementary InformationThe online version contains supplementary material available at 10.1007/s13280-021-01565-3. 相似文献
10.
Robert Kase Peter D. Hansen Birgit Fischer Werner Manz Peter Heininger Georg Reifferscheid 《Environmental science and pollution research international》2009,16(1):54-64
Background, aim, and scope The enzyme-linked receptor assay (ELRA) detects estrogenic and anti-estrogenic effects at the molecular level of receptor
binding and is a useful tool for the integrative assessment of ecotoxicological potentials caused by hormonally active agents
(HAA) and endocrine disrupting compounds (EDC). The main advantage of the ELRA is its high sample throughput and its robustness
against cytotoxicity and microbial contamination. After a methodological adaptation to salinity of the ELRA, according to
the first part of this study, which increased its salinity tolerance and sensitivity for 17-β-estradiol, the optimised ELRA
was used to investigate 13 native sediments characterised by different levels of salinity and chemical contamination. The
applicability of the ELRA for routine analysis in environmental assessment was evaluated. Salinity is often a critical factor
for bioassays in ecotoxicological sediment assessment. Therefore, salinity of the samples was additionally adjusted to different
levels to characterise its influence on elution and binding processes of receptor-binding substances.
Materials and methods The ELRA was carried out with the human estrogen receptor α (ER) in a 96-well microplate format using the experimental setup
known from the competitive immunoassay based on ligand–protein interaction. It is an important improvement that a physiologically
relevant receptor was used as a linking protein instead of an antibody. The microplates were coated with a 17-β-estradiol-BSA
conjugate, and dilution series of estradiol and of native sediment samples were added and incubated with the ER. After a washing
step, a biotinylated mouse anti-ER antibody was added to each well. Receptor binding to estradiol, agonistic and antagonistic
receptor binding, were determined by a streptavidin-POD-biotin complex with subsequent measurement of the peroxidase activity
at the wavelength of 450 nm using a commercial ELISA multiplate reader. The sediment elutriates and pore water samples of
sediments were tested in a dilution series to evaluate at which dilution step the receptor-binding potential ends. In the
elution process (see Section 2.1 to 2.2), a method was developed to adjust the salinity to the levels of the reference testings, which offers an appropriate option
to adjust the salinity in both directions. Statistical evaluation was made with a combination of the Mann–Whitney U test and the pT-method.
Results This part of the study characterised the environmental factor ‘salinity’ for prospective applications of the ELRA. Using reference
substances such as 17-β-estradiol, the ELRA showed sigmoid concentration-effect relations over a broad range from 0.05 μg/l
to 100 μg/l under physiological conditions. After methodological optimisation, both sensitivity and tolerance of the assay
against salinity could be significantly raised, and the ELRA became applicable under salinity conditions up to concentrations
of 20.5‰. The mean relative inter-test error (n = 3) was around 11% with reference substances and below 5% for single sediments elutriates in three replicates each. For
sediment testings, the pore water and different salinity-adjusted elutriates of 13 sediments were used. A clear differentiation
of the receptor-binding potential could be reached by application of the pT-method. Thereby, pT-values from one to six could
be assigned to the sediments, and the deviation caused by the different salinity conditions was one pT-value. The mean standard
deviation in the salinity adaptation procedure of the elutriates was below 5%.
Discussion Although the ELRA has already been used for assessments of wastewater, sludge and soil, its applicability for samples to different
salinity levels has not been investigated so far. Even if the ELRA is not as sensitive as the E-screen or the YES-assay, with
regard to reference substances like 17-β-estradiol, it is a very useful tool for pre-screening, because it is able to integrate
both estrogenic as well as anti-estrogenic receptor-binding effects. According to the results of sediment testing, and given
the integrative power to detect different directions of effects, the ELRA shows sufficient sensitivity and salinity tolerance
to discriminate receptor-binding potentials in environmental samples.
Conclusions The optimised ELRA assay is a fast, cost-effective, reliable and highly reproducible tool that can be used for high-throughput
screening in a microplate format in detecting both estrogenic and anti-estrogenic effects. Additionally, the ELRA is robust
against microbial contaminations, and is not susceptible towards cytotoxic interferences like the common cell-culture methods.
The general applicability and sufficient sensitivity of the ELRA was shown in freshwater environments. Marine and brackish
samples can be measured up to salinity levels of 20.5‰.
Recommendations and perspectives In view of the proven sensitivity, functionality and the fastness of the ELRA, it is recommendable to standardise the test
method. At the moment, no adequate in vitro test procedure exists which is standardised to DIN or ISO levels. The E-screen
and the yeast estrogen/androgen screens (YES/YAS) sometimes underlie strong cytotoxic effects, as reported in the first part
of this study. Further development of an ELRA assay using human androgen receptors appears to be very promising to gain information
about androgenic and anti-androgenic effects, too. This would offer a possibility to use the ELRA as a fast and reliable pre-screening
tool for the detection of endocrine potentials, thus minimising time and cost-expensive animal experiments. 相似文献