全文获取类型
收费全文 | 601篇 |
免费 | 4篇 |
专业分类
安全科学 | 11篇 |
废物处理 | 17篇 |
环保管理 | 47篇 |
综合类 | 283篇 |
基础理论 | 93篇 |
污染及防治 | 107篇 |
评价与监测 | 24篇 |
社会与环境 | 19篇 |
灾害及防治 | 4篇 |
出版年
2019年 | 7篇 |
2018年 | 12篇 |
2017年 | 11篇 |
2016年 | 8篇 |
2015年 | 14篇 |
2014年 | 22篇 |
2013年 | 17篇 |
2012年 | 12篇 |
2011年 | 16篇 |
2010年 | 20篇 |
2009年 | 19篇 |
2008年 | 16篇 |
2007年 | 16篇 |
2006年 | 15篇 |
2005年 | 11篇 |
2004年 | 8篇 |
2003年 | 14篇 |
2002年 | 12篇 |
1998年 | 12篇 |
1997年 | 6篇 |
1996年 | 12篇 |
1995年 | 6篇 |
1994年 | 13篇 |
1993年 | 13篇 |
1991年 | 7篇 |
1990年 | 8篇 |
1989年 | 6篇 |
1985年 | 6篇 |
1978年 | 6篇 |
1976年 | 5篇 |
1974年 | 5篇 |
1972年 | 5篇 |
1971年 | 5篇 |
1970年 | 8篇 |
1969年 | 5篇 |
1965年 | 7篇 |
1964年 | 7篇 |
1963年 | 10篇 |
1962年 | 8篇 |
1961年 | 7篇 |
1960年 | 7篇 |
1959年 | 10篇 |
1958年 | 6篇 |
1957年 | 10篇 |
1956年 | 14篇 |
1955年 | 16篇 |
1954年 | 6篇 |
1952年 | 5篇 |
1934年 | 7篇 |
1933年 | 4篇 |
排序方式: 共有605条查询结果,搜索用时 312 毫秒
31.
Conservation of the Toromiro Tree: Case Study in the Management of a Plant Extinct in the Wild 总被引:1,自引:0,他引:1
Mike Maunder Alastair Culham † Bjorn Alden ‡ Georg Zizka § Cathérine Orliac Wolfram Lobin †† Alberto Bordeu ‡‡ Jose M. Ramirez §§ and Sabine Glissmann-Gough 《Conservation biology》2000,14(5):1341-1350
Abstract: We reviewed the history and conservation of Sophora toromiro , a species that has been extinct in the wild since 1960 but has survived as scattered individuals in botanic gardens and private collections. The short-term conservation of S. toromiro is dependent on the management of surviving ex situ stocks. This is being achieved through international collaboration by a working group established to coordinate the conservation management of the species. Molecular evidence indicates that the species retains greater genetic variability than expected. The greatest amount of genetic variability was located in specimens outside botanic garden collections. No unmodified natural habitat survives on Rapa Nui ( Easter Island); so opportunities to establish a viable wild population are limited. Evidence from past reintroductions indicates that the best short-term opportunity for the species is through conventional horticultural management in botanic gardens and traditional farm plots on Rapa Nui. Some extinct-in-the-wild taxa (sensu World Conservation Union 1994), such as the Toromiro, retain genetic variability, and appropriate reintroduction sites exist. These taxa represent valid priorities for conservation management. 相似文献
32.
Impact of temperature on the dynamics of organic matter and on the soil-to-plant transfer of Cd,Zn and Pb in a contaminated agricultural soil 总被引:1,自引:0,他引:1
Jean-Yves Cornu L. Denaix J. Lacoste V. Sappin-Didier C. Nguyen A. Schneider 《Environmental science and pollution research international》2016,23(4):2997-3007
Predicting the soil-to-plant transfer of metals in the context of global warming has become a major issue for food safety. It requires a better understanding of how the temperature alters the bioavailability of metals in cultivated soils. This study focuses on one agricultural soil contaminated by Cd, Zn and Pb. DGT measurements were performed at 10, 20 and 30 °C to assess how the bioavailability of metals was affected by a rise in soil temperature. A lettuce crop was cultivated in the same conditions to determine if the soil-to-plant transfer of metals increased with a rise in soil temperature. A gradual decline in Cd and Zn bioavailability was observed from 10 to 30 °C, which was attributed to more intense complexation of metals in the pore water at higher temperatures. Together with its aromaticity, the affinity of dissolved organic matter (DOM) for metals was indeed suspected to increase with soil temperature. One main output of the present work is a model which satisfactorily explains the thermal-induced changes in the characteristics of DOM reported in Cornu et al. (Geoderma 162:65–70, 2011) by assuming that the mineralization of initial aliphatic compounds followed a first-order reaction, increased with soil temperature according to the Arrhenius law, and due to a priming effect, led to the appearance of aromatic molecules. The soil-to-plant transfer of Cd and Zn was promoted at higher soil temperatures despite a parallel decrease in Cd and Zn bioavailability. This suggests that plant processes affect the soil-to-plant transfer of Cd and Zn the most when the soil temperature rises. 相似文献
33.
Ana Victoria Marta-Sanchez Sergiane Souza Caldas Antunielle Schneider Sónia Maria Vaz Sanches Cardoso Ednei Gilberto Primel 《Environmental science and pollution research international》2018,25(15):14460-14470
Parabens have been widely used as antimicrobial agents, mainly in food products, pharmaceuticals, and cosmetics. Although they are known as safe preservatives, they also cause some harm to human health, which has been discussed lately. Therefore, the aim of this study was to evaluate the occurrence of nine parabens (including isomers) in mineral and drinking waters, besides in drinking water treatment sludge (DWTS) samples with determination by liquid chromatography tandem mass spectrometry (LC-MS/MS). Both methods solid phase extraction (SPE) and QuEChERS were validated. Calibration curves showed a correlation coefficient of 0.99 for all compounds. LOQ values ranged from 0.04 to 4 μg L?1 in aqueous matrices and from 5 to 500 ng g?1 in DWTS. Recoveries between 70 and 115% were reached with RSD below 20% for all compounds in SPE whereas recoveries between 62 and 119% were found with RSD below 20% for almost all compounds in QuEChERS. Matrix effect had low values (<?20%); it was only above 20% for methylparaben in the SPE and for pentylparaben in the QuEChERS. Using a quick and simple extraction procedures with SPE, QuEChERS, and LC-MS/MS analyses, these methods proved to be selective and sensitive. They were successfully applied to real samples (treated water, mineral water, and sludge), and methylparaben was detected at concentration levels below 0.242 μg L?1 in mineral and treated water samples and 10 ng g?1 in DWTS samples. 相似文献
34.
Xueyuan Wang Xin-Zhong Liang Weimei Jiang Zhining Tao Julian X.L. Wang Hongnian Liu Zhiwei Han Shuyan Liu Yuyan Zhang Georg A. Grell Steven E. Peckham 《Atmospheric environment (Oxford, England : 1994)》2010,44(5):660-669
This study develops fine temporal (seasonal, day-of-week, diurnal) and vertical allocations of anthropogenic emissions for the TRACE-P inventory and evaluates their impacts on the East Asian air quality prediction using WRF-Chem simulations in July 2001 at 30-km grid spacing against available surface measurements from EANET and NEMCC. For NO2 and SO2, the diurnal and vertical redistributions of emissions play essential roles, while the day-of-week variation is less important. When all incorporated, WRF-Chem best simulates observations of surface NO2 and SO2 concentrations, while using the default emissions produces the worst result. The sensitivity is especially large over major cities and industrial areas, where surface NO2 and SO2 concentrations are reduced by respectively 3–7 and 6–12 ppbv when using the scaled emissions. The incorporation of all the three redistributions of emissions simulates surface O3 concentrations higher by 4–8 ppbv at night and 2–4 ppbv in daytime over broad areas of northern, eastern and central China. To this sensitivity, the diurnal redistribution contributes more than the other two. 相似文献
35.
Lukas Hörtnagl Robert Clement Martin Graus Albin Hammerle Armin Hansel Georg Wohlfahrt 《Atmospheric environment (Oxford, England : 1994)》2010,44(16):2024-2032
Using proton transfer reaction mass spectrometry equipped with a quadrupol mass analyser to quantify the biosphere-atmosphere exchange of volatile organic compounds (VOC), concentrations of different VOC are measured sequentially. Depending on how many VOC species are targeted and their respective integration times, each VOC is measured at repeat rates on the order of a few seconds. This represents an order of magnitude longer sample interval compared to the standard eddy covariance (EC) method (5–20 Hz sampling rates). Here we simulate the effect of disjunct sampling on EC flux estimates by decreasing the time resolution of CO2 and H2O concentrations measured at 20 Hz above a temperate mountain grassland in the Austrian Alps. Fluxes for one month are calculated with the standard EC method and compared to fluxes calculated based on the disjunct data (1, 3 and 5 s sampling rates) using the following approaches: i) imputation of missing concentrations based on the nearest neighbouring samples (iDECnn), ii) imputation by linear interpolation (iDECli), and iii) virtual disjunct EC (vDEC), i.e. flux calculation based solely on the disjunct concentrations. It is shown that the two imputation methods result in additional low-pass filtering, longer lag times (as determined with the maximum cross-correlation method) and a flux loss of 3–30% as compared to the standard EC method. A novel procedure, based on a transfer function approach, which specifically corrects for the effect of data treatment, was developed, resulting in improved correspondence (to within 2%). The vDEC method yields fluxes which approximate the true (20 Hz) fluxes to within 3–7% and it is this approach we recommend because it involves no additional empirical corrections. The only drawback of the vDEC method is the noisy nature of the cross-correlations, which poses problems with lag determination – practical approaches to overcome this limitation are discussed. 相似文献
36.
Y. Schneider M. Beier K.-H. Rosenwinkel 《Environmental science and pollution research international》2014,21(20):12099-12108
Nitrous oxide (N2O), a strong greenhouse gas, can be produced by ammonium-oxidizing bacteria (AOB) as a by-product of ammonium oxidation and can potentially be formed in all types of nitrification processes. However, partial nitritation has been reported to cause significantly higher N2O emissions than complete nitrification. In the study presented here, the mechanisms and factors that drive N2O formation by AOB were investigated with respect to different operational strategies to achieve nitrite accumulation base on combined evaluation of oxygen uptake rate (OUR) and N2O formation rate. On the one hand, N2O formation during partial nitritation and nitrification in a continuously stirred tank reactor (CSTR) with continuous aerobic conditions was observed. On the other hand, the effect of intermittent aeration on N2O formation during nitrification was investigated. The presence of nitrite, the extend of sludge-specific ammonium loading, low oxygen concentration, and transition from aerobic to anoxic conditions significantly increased N2O formation in this reactor independently from each other, indicating that different formation pathways, supposedly via nitrite or hydroxylamine, were active. 相似文献
37.
Irrigated agriculture is a main user of groundwater. Achieving a sustainable use of groundwater will often require agricultural
land-use changes such as shifting to entirely different kinds of crops and/or technologies. Enhanced understanding of land-use
change is hence required for developing policies for a sustainable water future. We use an agent-based model to investigate
the history of irrigated agriculture in the Upper Guadiana Basin, Spain, in order to learn about the influence of farmers’
characteristics on land-use change and associated groundwater over-use. A shift from vineyards and cereals to horticultural
crops would provide a possibility for higher income with less water use. Such a shift cannot be observed historically. The
model results suggest that risk aversion and path dependency are insufficient to explain this observation, and the organisational
set-up of farms limiting the maximum labour force needs to be considered as additional explanatory factor. Furthermore, it
is shown that different types of farms existing in the UGB can be expected to exhibit distinct responses to drivers of land-use
change such as agricultural policies. It is concluded that a sound understanding of the social system making use of a resource
is required to solve problems of resource over-use. This article demonstrates that agent-based models can be useful tools
to enhance such an understanding even in situations of scarce and uncertain data that are often encountered when dealing with
resource-use problems. 相似文献
38.
Walter John Georg Reischl 《Journal of the Air & Waste Management Association (1995)》2013,63(8):872-876
A cyclone with a 47 mm after-filter has been developed for ambient air size-selective monitoring. It has been extensively evaluated with laboratory-generated aerosol. Variation of the pressure drop and 50% cut point with flow rate show that the cyclone operates in a single flow regime with a vortex in the outlet flow. The particle size cutoff curve is comparable in sharpness to a cascade impactor and is the same for solid or liquid particles. At 21.7 L/min, D 50 is 2.5μm and at 15.4 L/min, D 50 is 3.5 μm. Collection efficiency data for flow rates from 8 to 27 L/min fit a universal curve when plotted vs. the normalized particle diameter, (D-D 50)/D 50 Reentrainment of previously deposited particles is less than 1 % of the loading per day. In field tests the cyclone has proved to be a very satisfactory size-selective sampler. 相似文献
39.
Long-term effects of clear-cutting and selective cutting on soil methane fluxes in a temperate spruce forest in southern Germany 总被引:1,自引:0,他引:1
Wu X Brüggemann N Gasche R Papen H Willibald G Butterbach-Bahl K 《Environmental pollution (Barking, Essex : 1987)》2011,159(10):2467-2475
Based on multi-year measurements of CH4 exchange in sub-daily resolution we show that clear-cutting of a forest in Southern Germany increased soil temperature and moisture and decreased CH4 uptake. CH4 uptake in the first year after clear-cutting (−4.5 ± 0.2 μg C m−2 h−1) was three times lower than during the pre-harvest period (−14.2 ± 1.3 μg C m−2 h−1). In contrast, selective cutting did not significantly reduce CH4 uptake. Annual mean uptake rates were −1.18 kg C ha−1 yr−1 (spruce control), −1.16 kg C ha−1 yr−1 (selective cut site) and −0.44 kg C ha−1 yr−1 (clear-cut site), respectively. Substantial seasonal and inter-annual variations in CH4 fluxes were observed as a result of significant variability of weather conditions, demonstrating the need for long-term measurements. Our findings imply that a stepwise selective cutting instead of clear-cutting may contribute to mitigating global warming by maintaining a high CH4 uptake capacity of the soil. 相似文献
40.
Various studies have been performed to determine nitrous oxide (N2O) emissions from conventional biological nitrogen removal processes in wastewater treatment like nitrification and denitrification in the main stream. However, with respect to the overall emissions of a wastewater treatment plant, part-stream treatment for high-strength wastewater (e.g., sludge liquor) is also expected to hold a significant emission potential because of high concentrations and extreme boundary conditions. This paper presents results from a laboratory-scale study on nitrous oxide production by biomass from a deammonification process (nitritation + anammox) under anoxic conditions. It was discovered that N2O formation results from incomplete endogenous denitrification rather than anammox and is dependent on substrate availability. Based on direct measurements of the dissolved N2O concentrations in a sequencing batch reactor, the dynamic behavior of N2O production is characterized in more detail. The results show that, during anoxic conditions, the N2O emission potential of deammonification is significantly lower than from conventional denitrification. 相似文献