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341.
George T. Wolff Alan M. Dunker S. Trivikrama Rao P. Steven Porter Igor G. Zurbenko 《Journal of the Air & Waste Management Association (1995)》2013,63(2):273-282
ABSTRACT Ozone and precursor trends can be used to measure the effectiveness of regulatory programs that have been implemented. In this paper, we review trends in the concentrations of O3, NOx, and HCs over North America that have been reported in the literature. Although most existing trend studies are confounded by meteorological variability, both the raw data trends and the trends adjusted for meteorology collectively indicate a general decreasing trend in O concentrations in most areas of the United States during 1985-1996. In Canada, mean daily maximum 1-hr O3 concentrations at urban sites show mixed trends with a majority of sites showing an increase from 1980 to 1993. Mean daily maximum 1-hr O3 at most regionally representative Canadian sites appears to decrease from 1985 to 1993 or shows no significant change. There are far fewer data and analyses of NOx and HC trends. Available studies covering various ranges of years indicate decreases in ambient NOx and HC concentrations in Los Angeles, CA, decreases in HC concentrations in northeastern U.S. cities, and decreases in NO concentrations in Canadian cities. Two key needs are long-term HC and NOx measurements, particularly at rural sites, and a systematic comparison of trend detection techniques on a reference data set. 相似文献
342.
George M. Hidy Delbert J. Eatough George A. Klouda 《Journal of the Air & Waste Management Association (1995)》2013,63(5):600-613
Abstract An experimental design is described to estimate the fraction of secondary fine particle from the biogenic component of volatile organic compounds (VOCs) in the atmosphere using radiocarbon isotopic abundance ratios. The method distinguishes between “modern” carbon (C), and “old” C of primary and secondary origins based on three components, condensed-phase organic carbon (OC), semi-volatile particulate compounds (SVOCs), and VOCs. The method depends on interpretation of diurnal and seasonal variation in OC, SVOC, and VOC concentrations. Sampling employs a filter-denuder unit, which collects the three C components for isotopic analysis. The samples are collected repetitively for a daily sequence of the same hourly intervals covering diurnal periods with similar meteorological conditions. Collected C is thermally treated to separate OC from black carbon on filters and VOCs or SVOCs from adsorbents, with all four fractions individually oxidized to carbon dioxide to determine the radiocarbon content by accelerator mass spectrometry. Using C isotope abundance, the data are interpreted for fractions of primary modern C and secondary modern C as estimated from averaging diurnal and seasonal variations in the concentration data. As support for interpretation, samples of OC, SVOCs, and VOCs would be analyzed for speciation to identify source indicator species present. 相似文献
343.
Steve E. Lindberg George R. Southworth Mary Anna Bogle T.J. Blasing Jim Owens Kelly Roy 《Journal of the Air & Waste Management Association (1995)》2013,63(7):859-869
Abstract Mercury-bearing material enters municipal landfills from a wide array of sources, including fluorescent lights, batteries, electrical switches, thermometers, and general waste; however, the fate of mercury (Hg) in landfills has not been widely studied. Using automated flux chambers and downwind atmospheric sampling, we quantified the primary pathways of Hg vapor releases to the atmosphere at six municipal landfill operations in Florida. These pathways included landfill gas (LFG) releases from active vent systems, passive emissions from landfill surface covers, and emissions from daily activities at each working face (WF). We spiked the WF at two sites with known Hg sources; these were readily detected downwind, and were used to test our emission modeling approaches. Gaseous elemental mercury (Hg0) was released to the atmosphere at readily detectable rates from all sources measured; rates ranged from ~1–10 ng m?2 hr?1 over aged landfill cover, from ~8–20 mg/hr from LFG flares (LFG included Hg0 at μg/m3 concentrations), and from ~200–400 mg/hr at the WF. These fluxes exceed our earlier published estimates. Attempts to identify specific Hg sources in excavated and sorted waste indicated few readily identifiable sources; because of effective mixing and diffusion of Hg0, the entire waste mass acts as a source. We estimate that atmospheric Hg releases from municipal landfill operations in the state of Florida are on the order of 10–50 kg/yr, substantially larger than our original estimates, but still a small fraction of current overall anthropogenic losses. 相似文献
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George Antonious Regina Hill Kyla Ross Timothy Coolong 《Journal of environmental science and health. Part. B》2013,48(5):369-378
Endosulfan 3 EC, a mixture of α- and β-stereo isomers, was sprayed on field-grown pepper, melon, and sweet potato plants at the recommended rate of 0.44 kg A.I. acre?1. Plant tissue samples (leaves, fruits, or edible roots) were collected 1 h to 30 days following spraying and analyzed for endosulfan isomers (α- and β-isomers). Analysis of samples was accomplished using a gas chromatograph (GC) equipped with a mass detector in total ion mode. The results indicated the formation of endosulfan sulfate as the major metabolite of endosulfan sulfite and the relatively higher persistence of the β-isomers as compared to the α-isomer. The initial total residues (α- and β-isomers plus endosulfan sulfate) were higher on leaves than on fruits. On pepper and melon fruits, the α-isomer, which is the more toxic to mammals, dissipated faster (T1/2 = 1.22 and 0.95 d, respectively) than the less toxic β-isomer (T1/2 = 3.0 and 2.5 d, respectively). These results confirm the greater loss of the α-isomer compared to the β-isomer, which can ultimately impact endosulfan dissipation in the environment. Additionally, the higher initial residues of endosulfan on pepper and sweet potato leaves should be considered of great importance for timing field operations and the safe entry of harvesters due to the high mammalian toxicity of endosulfan. 相似文献
347.
Charles W. Gruber George A. Jutze Norman A. Huey 《Journal of the Air & Waste Management Association (1995)》2013,63(4):327-330
Abstract An airborne lidar was used to study the smoke plume from the burning of a controlled oil spill on the ocean. The ratio of the amount of light (at a wavelength, λ, of 0.532 u.m) backscattered by the smoke to the amount of light extinguished by the smoke was determined by measuring the strength of a laser beam after it had passed through the smoke plume, been reflected from the ocean, and passed through the smoke plume again, and comparing this to the strength of the laser beam reflected directly from the ocean. The optical depth of the smoke (at λ = 0.532 µm) was typically between 0.2 and 0.5. The mass fluxes of smoke particles that passed through four vertical cross sections of the (nonsteady state) smoke plume were estimated from lidar measurements to be 142, 175, 423, and 414 g s-1, compared to an average smoke mass production rate of ~770 g s-1. The spatial distribution of smoke mass along the long axis of the plume was also estimated from the lidar measurements; derived smoke mass concentrations were generally <300 µg m-3, with a few isolated values up to ~800 µg m-3. 相似文献
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George M. Hidy Charles L. Blanchard 《Journal of the Air & Waste Management Association (1995)》2013,63(10):1261-1282
Numerous papers analyze ground-level ozone (O3) trends since the 1980s, but few have linked O3 trends with observed changes in nitrogen oxide (NOx) and volatile organic compound (VOC) emissions and ambient concentrations. This analysis of emissions and ambient measurements examines this linkage across the United States on multiple spatial scales from continental to urban. O3 concentrations follow the general decreases in both NOx and VOC emissions and ambient concentrations of precursors (nitrogen dioxide, NO2; nonmethane organic compounds, NMOCs). Annual fourth-highest daily peak 8-hr average ozone and annual average or 98th percentile daily maximum hourly NO2 concentrations show a statistically significant (p < 0.05) linear fit whose slope is less than 1:1 and intercept is in the 30 to >50 ppbv range. This empirical relationship is consistent with current understanding of O3 photochemistry. The linear O3–NO2 relationships found from our multispatial scale analysis can be used to extrapolate the rate of change of O3 with projected NOx emission reductions, which suggests that future declines in annual fourth-highest daily average 8-hr maximum O3 concentrations are unlikely to reach 65 ppbv or lower everywhere in the next decade. Measurements do not indicate increased annual reduction rates in (high) O3 concentrations beyond the multidecadal precursor proportionality, since aggressive measures for NOx and VOC reduction are in place and have not produced an accelerated O3 reduction rate beyond that prior to the mid-2000s. Empirically estimated changes in O3 with emissions suggest that O3 is less sensitive to precursor reductions than is found by the CAMx (v. 6.1) photochemical model. Options for increasing the rate of O3 change are limited by photochemical factors, including the increase in NOx sensitivity with time (NMOC/NOx ratio increase), increase in O3 production efficiency at lower NOx concentrations (higher O3/NOy ratio), and the presence of natural NOx and NMOC precursors and background O3.Implications:?This analysis demonstrates empirical relations between O3 and precursors based on long term trends in U.S. locations. The results indicate that ground-level O3 concentrations have responded predictably to reductions in VOC and NOx since the 1980s. The analysis reveals linear relations between the highest O3 and NO2 concentrations. Extrapolation of the historic trends to the future with expected continued precursor reductions suggest that achieving the 2014 proposed reduction in the U.S. National Ambient Air Quality Standard to a level between 65 and 70 ppbv is unlikely within the next decade. Comparison of measurements with national results from a regulatory photochemical model, CAMx, v. 6.1, suggests that model predictions are more sensitive to emissions changes than the observations would support. 相似文献