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941.
George Kriek Nelson Lazear Verne Rhodes Joe Barnes John Bollmeier Jane Chen Chuang 《Journal of the Air & Waste Management Association (1995)》2013,63(7):1001-1008
ABSTRACT Emission factors for selected volatile organic compounds (VOCs) and particulate material were developed during processing of commercial grades of polyamide 6, polyamide 66, and polyamide 66/6 resins. A small commercial-type extruder was used, and melt temperatures ranged from 475 to 550 °F. An emission factor was calculated for each substance measured and is reported as pounds released to the atmosphere per million pounds of polymer resin processed. Scaled to production volumes, these emission factors can be used by processors to estimate emission quantities from similar polyamide extrusion operations. 相似文献
942.
George M. Hidy Bruce R. Appel Robert J. Charlson William E. Clark Sheldon K. Friedlander Dale H. Hutchison 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1106-1114
This report gives a brief summary of the experimental plan and the early results of field observations from the California Aerosol Characterization Experiment (ACHEX). The objectives of the program center on questions of the sources and evolution of aerosols in urban air, as they are superimposed on a natural background, particularly as they relate to visibilitydegradation. The project initially nvolved the use of an elaborately instrumented mobile laboratory combined with a fixed station in San Jose, in Pasadena, and in Riverside, and later incorporated several satellite monitoring stations in the Los Angeles Basin. Intensive field observationswere taken from July 1972 to November 1972 in several urban and nonurban locations between the San Francisco Bay area and the South Coast Basin, covering the Los Angeles area. In a second phase of the ACHEX, aerosols accompanying photochemical smog were studied intensively in the Los Angeles Basin during the period between July and October of 1973. The observations cover a wide variety of parameters including physical and chemical properties of aerosols, pollutant gas concentrations, and meteorological variables. The initial results show the great importance of sulfate, nitrate, noncarbonate carbon, and liquid water to the mass concentration of airborne particles and their relation to reduction in visibility. The anthropogenic contribution to atmospheric aerosols is consistently found to be allocated primarily to the submicron or fine particle size range. 相似文献
943.
In many temperate estuarine areas, ongoing climatic changes are expected to lead to higher seawater temperatures, to increased inflow of freshwater and nutrients (due to increased rainfall) and to altered light conditions. During the last two decades, several winters have been unusually mild in southern Finland, and the subsequent springs have been early. This may have consequences for the seasonality of many species, including the bladder-wrack, Fucus vesiculosus, whose reproductive cycle may be especially sensitive. In the present study, F. vesiculosus receptacles from the field were weighed regularly during three warm (early) springs and compared with receptacles from three cold (late) springs. On average, the first sign of receptacle growth in the field occurred 5–6?weeks earlier and receptacles probably matured 2–3?weeks earlier during the warm springs than during the cold springs. This may be due to differences in seawater temperatures among years, but significantly heavier receptacles at 0.8?m compared to at 3.1?m further suggests the importance of light for receptacle growth as a measure of maturation, since there were no depth-related differences in seawater temperatures. Also, when plotting receptacle wet weights against seawater temperatures, the importance of light can be seen as different regression relationships (slopes and intercepts). In an outdoor aquarium experiment, the effects of temperature and light on receptacle growth were also tested, and there were significant differences between shallow and deep specimens, but temperature and light had no effects, except on initial receptacle growth. Since oogonian development, and thereby the time for zygote release, followed the receptacle growth curve, this could mean a mismatch between the timing of F. vesiculosus zygote settlement and the cover of competing filamentous algae, but such species interactions require further investigations in order to better understand their possible consequences. 相似文献
944.
Robert M. Zink § George F. Barrowclough † Jonathan L. Atwood ‡ and Rachelle C. Blackwell-Rago 《Conservation biology》2000,14(5):1394-1405
Abstract: The California Gnatcatcher ( Polioptila californica ) has become a flagship species in the dispute over development of southern California's unique coastal sage scrub habitat, a fragile, geographically restricted ecosystem with high endemism. One aspect of the controversy concerns the status of the subspecies of this bird in southern California coastal sage scrub that is currently listed as threatened under the U.S. Endangered Species Act. To investigate the recent population history of this species and the genetic distinctiveness of subspecies and to inform conservation planning, we used direct sequencing of mitochondrial DNA (mtDNA) for 64 individuals from 13 samples taken throughout the species' range. We found that coastal sage scrub populations of California Gnatcatchers are not genetically distinct from populations in Baja California, which are dense and continuously distributed throughout the peninsula. Rather, mtDNA sequences from this species contain the signatures of population growth and support a hypothesis of recent expansion of populations from a southern Baja California refugium northward into the southern coastal regions of California. During this expansion, stochastic events led to a reduction in genetic variation in the newly occupied range. Thus, preservation of coastal sage scrub cannot be linked to maintaining the genetic diversity of northern gnatcatcher populations, despite previous recognition of subspecies. Our study suggests that not all currently recognized subspecies are equivalent to evolutionarily significant units and illustrates the danger of focusing conservation efforts for threatened habitats on a single species. 相似文献
945.
Guangxing Wang George Gertner Alan Anderson Heidi Howard 《Environmental management》2009,44(4):810-823
The land management of US Army installations requires information on land conditions and their history for planning future
military training activities and allocation of land repair. There is thus a strong need for methodology development to estimate
the land conditions and cumulative military training impacts for the purpose of repair and restoration. In this study, we
simulated at Fort Riley, USA, spatial patterns and temporal dynamics of military training impacts on land conditions quantified
as percent ground cover using an image-aided spatial conditional co-simulation algorithm. Moreover, we estimated the historical
percent ground cover as a measure of the cumulative impacts, and then calculated the allocation of land repair and restoration
based on both current and historical land conditions. In addition, we developed a loss function method for allocation of land
repair and restoration. The results showed: (1) this co-simulation algorithm reproduced spatial and temporal variability of
percent ground cover and provided estimates of uncertainties with the correlation coefficients and root mean square errors
between the simulated and observed values varying from 0.63 to 0.88 and from 23% to 78%, respectively; (2) with and without
the cumulative impacts, the obtained spatial patterns of the land repair categories were similar, but their land areas differed
by 5% to 40% in some years; (3) the combination of the loss function with the co-simulation made it possible to estimate and
computationally propagate the uncertainties of land conditions into the uncertainties of expected cost loss for misallocation
of land repair and restoration; and (4) the loss function, physical threshold, and probability threshold methods led to similar
spatial patterns and temporal dynamics of the land repair categories, however, the loss function increased the land area by
5% to 30% for intense and moderate repairs and decreased the area by 5% to 30% for no repairs and light repairs for most of
the years. This approach provided the potential to improve and automate the existing land rehabilitation and maintenance (LRAM)
system used for the land management of the U.S. Army installations, and it can be applied to the management of other civil
lands and environments. In conclusion, this study overcame the important gaps that exist in the methodological development
and application for simulating land conditions and cumulative impacts due to human activities, and also in the methods for
the allocation of land for repair and restoration. 相似文献
946.
947.
Metal oxide nanomaterials have exhibited toxicity to a variety of aquatic organisms, especially microbes and invertebrates. To date, few studies have evaluated the toxicity of metal oxide nanomaterials on aquatic vertebrates. Therefore, this study examined effects of ZnO, TiO2, Fe2O3, and CuO nanomaterials (20-100 nm) on amphibians utilizing the Frog Embryo Teratogenesis Assay Xenopus (FETAX) protocol, a 96 h exposure with daily solution exchanges. Nanomaterials were dispersed in reconstituted moderately hard test medium. These exposures did not increase mortality in static renewal exposures containing up to 1000 mg L−1 for TiO2, Fe2O3, CuO, and ZnO, but did induce developmental abnormalities. Gastrointestinal, spinal, and other abnormalities were observed in CuO and ZnO nanomaterial exposures at concentrations as low as 3.16 mg L−1 (ZnO). An EC50 of 10.3 mg L−1 ZnO was observed for total malformations. The minimum concentration to inhibit growth of tadpoles exposed to CuO or ZnO nanomaterials was 10 mg L−1. The results indicate that select nanomaterials can negatively affect amphibians during development. Evaluation of nanomaterial exposure on vertebrate organisms are imperative to responsible production and introduction of nanomaterials in everyday products to ensure human and environmental safety. 相似文献
948.
Two aluminum water treatment residuals (Al-WTRs) from water treatment plants in Manatee County, FL and Punta Gorda, FL were evaluated as potential permeable reactive barrier (PRB) media to reduce groundwater phosphorus (P) losses. Short-term (<24 h) P sorption kinetics and long-term P sorption capacity were determined using batch equilibration studies. Phosphorus desorption was characterized following P loadings of 10, 20, 30, 40 and >70 g kg−1. Sorption and desorption studies were conducted on the <2.0 mm material and three size fractions within the <2.0 mm material. The effect of dissolved organic carbon (DOC) on P retention was determined by reacting Al-WTRs with P-spiked groundwater samples of varying initial DOC concentrations. Phosphorus sorption kinetics were rapid for all size fractions of both Al-WTRs (>98% P sorption effectiveness at shaking times ?2 h). The effect of DOC was minimal at <150 mg DOC L−1, but modest reductions (<22%) in P sorption effectiveness occurred at 587 mg DOC L−1. The P sorption capacities of the Manatee and Punta Gorda Al-WTRs (<2.0 mm) are ∼44 g kg−1 and >75 g kg−1, respectively, and the lifespan of an Al-WTR PRB is likely many decades. Desorption was minimal (<2% of the P sorbed) for cumulative P loadings <40 g kg-l, but increased (<9% of the P sorbed) at cumulative P loads >70 g kg−1. The <2.0 mm Manatee and Punta Gorda Al-WTRs are regarded as ideal PRB media for P remediation. 相似文献
949.
George G. Ice George W. Brown John A. Gravelle C. Rhett Jackson Jeffrey T. Light Timothy E. Link Douglas J. Martin Dale J. McGreer Arne E. Skaugset 《Journal of the American Water Resources Association》2010,46(4):838-842
Ice, George G., George W. Brown, John A. Gravelle, C. Rhett Jackson, Jeffrey T. Light, Timothy E. Link, Douglas J. Martin, Dale J. McGreer, and Arne E. Skaugset, 2010. Discussion –“Stream Temperature Relationships to Forest Harvest in Western Washington” by Michael M. Pollock, Timothy J. Beechie, Martin Liermann, and Richard E. Bigley. Journal of the American Water Resources Association (JAWRA) 46(4): 838-842. DOI: 10.1111/j.1752-1688.2010.00441.x 相似文献
950.
Xiao-Huan Liu Yang Zhang Kristen M. Olsen Wen-Xing Wang Bebhinn A. Do George M. Bridgers 《Atmospheric environment (Oxford, England : 1994)》2010,44(20):2443-2456
The prediction of future air quality and its responses to emission control strategies at national and state levels requires a reliable model that can replicate atmospheric observations. In this work, the Mesoscale Model (MM5) and the Community Multiscale Air Quality Modeling (CMAQ) system are applied at a 4-km horizontal grid resolution for four one-month periods, i.e., January, June, July, and August in 2002 to evaluate model performance and compare with that at 12-km. The evaluation shows skills of MM5/CMAQ that are overall consistent with current model performance. The large cold bias in temperature at 1.5 m is likely due to too cold soil initial temperatures and inappropriate snow treatments. The large overprediction in precipitation in July is due likely to too frequent afternoon convective rainfall and/or an overestimation in the rainfall intensity. The normalized mean biases and errors are ?1.6% to 9.1% and 15.3–18.5% in January and ?18.7% to ?5.7% and 13.9–20.6% in July for max 1-h and 8-h O3 mixing ratios, respectively, and those for 24-h average PM2.5 concentrations are 8.3–25.9% and 27.6–38.5% in January and ?57.8% to ?45.4% and 46.1–59.3% in July. The large underprediction in PM2.5 in summer is attributed mainly to overpredicted precipitation, inaccurate emissions, incomplete treatments for secondary organic aerosols, and model difficulties in resolving complex meteorology and geography. While O3 prediction shows relatively less sensitivity to horizontal grid resolutions, PM2.5 and its secondary components, visibility indices, and dry and wet deposition show a moderate to high sensitivity. These results have important implications for the regulatory applications of MM5/CMAQ for future air quality attainment. 相似文献