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161.
Governments strive increasingly to reduce the ‘burden of legislation’ by shifting responsibilities to private institutions, thereby making use of ‘the market’ as regulating mechanism, and striving to base the relationship with industries on trust, rather then stringent enforcement. This makes mandatory certification and testing arrangements in occupational safety and health (OSH) an attractive alternative for traditional legislation and enforcement. The functioning of such OSH market arrangements has, however, hardly been investigated so far.The research described in this paper elaborated on the same cases that were used in the twin article (Zwetsloot et al., this issue) on risk control in mandatory occupational safety and health certification and testing regimes. In this research we carried out additional analyses on the functioning of market mechanisms in (mandatory) OSH regimes.Other market interests may prevail over the OSH aspect, and the conditions for good market functioning (a well-functioning supply and demand side, independency of the agents, informedness and transparency of the agents, and the added-value of the certificate expressed in the price), are not always met. The results show that policy makers are often too optimistic in their assumptions about the functioning of the market mechanisms in mandatory certification and testing.This does not imply that mandatory certification cannot be an interesting policy option. However, there seems to be a need for a second generation of mandatory certification arrangements, whereby the limitations of the market regulation are recognised, and the consequences are digested. 相似文献
162.
Bouchet S Tessier E Monperrus M Bridou R Clavier J Thouzeau G Amouroux D 《Journal of environmental monitoring : JEM》2011,13(5):1351-1359
The elemental mercury evasion from non-impacted natural areas is of significant importance in the global Hg cycle due to their large spatial coverage. Intertidal areas represent a dynamic environment promoting the transformations of Hg species and their subsequent redistribution. A major challenge remains in providing reliable data on Hg species variability and fluxes under typical transient tidal conditions found in such environment. Field experiments were thus carried out to allow the assessment and comparison of the magnitude of the gaseous Hg fluxes at the three interfaces, sediment-water, sediment-atmosphere and water-atmosphere of a mesotidal temperate lagoon (Arcachon Bay, Aquitaine, France) over three distinct seasonal conditions. The fluxes between the sediment-water and the sediment-atmosphere interfaces were directly evaluated with field flux chambers, respectively static or dynamic. Water-atmosphere fluxes were evaluated from ambient concentrations using a gas exchange model. The fluxes at the sediment-water interface ranged from -5.0 to 5.1 ng m(-2) h(-1) and appeared mainly controlled by diffusion. The occurrence of macrophytic covers (i.e.Zostera noltii sp.) enhanced the fluxes under light radiations. The first direct measurements of sediment-atmosphere fluxes are reported here. The exchanges were more intense and variable than the two other interfaces, ranging between -78 and 40 ng m(-2) h(-1) and were mostly driven by the overlying atmospheric Hg concentrations and superficial sediment temperature. The exchanges between the water column and the atmosphere, computed as a function of wind speed and gaseous mercury saturation ranged from 0.4 to 14.5 ng m(-2) h(-1). The flux intensities recorded over the intertidal sediments periodically exposed to the atmosphere were roughly 2 to 3 times higher than the fluxes of the other interfaces. The evasion of elemental mercury from emerged intertidal sediments is probably a significant pathway for Hg evasion in such tidal environments exhibiting background contamination level. 相似文献
163.
This issue comprises the fourth IRIOP Annual Review Issue, following the incorporation of the International Review of Industrial and Organizational Psychology (IRIOP) into the Journal of Organizational Behavior (JOB). In this, the final editorial of our 12‐year period of office, we celebrate the achievements of our authors and anonymous peer reviewers, each of whom has played a major role in transforming the highly successful invitation only IRIOP book series into the leading peer reviewed outlet for the publication of critical state‐of‐the‐art overviews and commentary on established knowledge and developments at the forefront of the field that the IRIOP Annual Review Issue has become, exemplified by the six papers appearing in this issue. 相似文献
164.
Sequestration of polycyclic aromatic hydrocarbons (PAHs) results in the slow release of PAHs from sediment to the aqueous environment, thus limiting bioavailability. Three methods to account for the limited bioavailability of native PAHs to the gastropod Hinia reticulata were therefore investigated: (i) infinite-sink extractions that measure desorption; (ii) equilibrium extractions that measure freely dissolved pore water concentrations and (iii) black carbon-inclusive modeling. The rapidly desorbing fraction was estimated based on the amount desorbed by Tenax. Relatively small amounts of PAHs (<9%) were present in F(rapid) and the observed solid-water distribution ratios (K(d,obs)) were approximately 1-2 orders of magnitude higher than literature K(oc) values. Biota to sediment accumulation factors (BSAFs) measured in the gastropod H. reticulata ranged from 0.02 to 0.07, 10-140 times lower than the theoretical value of approximately 1-2. The BSAFs calculated using the rapidly desorbing fraction or freely dissolved aqueous concentrations were also much lower than the theoretical value, and median values differed from the measured BSAFs by only a factor of 1.5-9. Furthermore, the result of using a BC-inclusive BSAF model could explain the deviation from the theoretical BSAF value and account for the low bioavailability of these native PAHs to H. reticulata. Risk assessment strategies of in situ contamination should therefore include a combination of chemical methods accounting for bioavailability, as well as bioaccumulation studies. 相似文献