全文获取类型
收费全文 | 129篇 |
免费 | 1篇 |
国内免费 | 3篇 |
专业分类
安全科学 | 5篇 |
废物处理 | 2篇 |
环保管理 | 17篇 |
综合类 | 18篇 |
基础理论 | 23篇 |
污染及防治 | 48篇 |
评价与监测 | 10篇 |
社会与环境 | 8篇 |
灾害及防治 | 2篇 |
出版年
2023年 | 1篇 |
2022年 | 2篇 |
2021年 | 1篇 |
2020年 | 2篇 |
2019年 | 2篇 |
2018年 | 2篇 |
2017年 | 2篇 |
2016年 | 9篇 |
2015年 | 8篇 |
2014年 | 3篇 |
2013年 | 6篇 |
2012年 | 7篇 |
2011年 | 10篇 |
2010年 | 6篇 |
2009年 | 8篇 |
2008年 | 13篇 |
2007年 | 12篇 |
2006年 | 6篇 |
2005年 | 4篇 |
2004年 | 3篇 |
2003年 | 7篇 |
2002年 | 6篇 |
2001年 | 2篇 |
1999年 | 2篇 |
1995年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 3篇 |
排序方式: 共有133条查询结果,搜索用时 15 毫秒
131.
The sorption of Cd and Pb by extracellular polymeric substances (EPS) extracted from activated sludges originated from wastewater treatment plants (WWTPs) or Lab-scale bioreactors was investigated as a function of pH. The study was carried out using a polarographic method in the SMDE (stripping mercury dropping electrode) mode which is suited to determine labile metals in solution containing soluble ligands such as EPS. The results obtained provide evidence of the presence of a pH-sorption/desorption edge for Cd and Pb by EPS. The use of Kurbatov’s model gives information on the mechanisms involved through the determination of “relative complexation constants” (operationally defined) and the number of protons exchanged. The use of this model demonstrates that proton exchange with metals is not the only mechanism involved in metal biosorption by EPS. Other mechanisms such as cation exchange with Ca or Mg, global electric field surrounding the ligand or micro-precipitation of metals could be involved in metal sorption by EPS. The position of the pH-sorption edge curves and the “relative complexation constants” show that Pb displays a greater affinity for EPS than Cd. The studied EPS have large differences regarding binding strength of Cd and Pb. These differences are not correlated with the organic parameters measured to characterize the EPS, however the mineral fraction of the EPS could be involved to a large extent in the sorption of metal. 相似文献
132.
Metal speciation in landfill leachates with a focus on the influence of organic matter 总被引:2,自引:0,他引:2
Claret F Tournassat C Crouzet C Gaucher EC Schäfer T Braibant G Guyonnet D 《Waste management (New York, N.Y.)》2011,31(9-10):2036-2045
This study characterises the heavy-metal content in leachates collected from eight landfills in France. In order to identify heavy metal occurrence in the different size fractions of leachates, a cascade filtration protocol was applied directly in the field, under a nitrogen gas atmosphere to avoid metal oxidation. The results of analyses performed on the leachates suggest that most of the metals are concentrated in the <30 kDa fraction, while lead, copper and cadmium show an association with larger particles. Initial speciation calculations, without considering metal association with organic matter, suggest that leachate concentrations in lead, copper, nickel and zinc are super-saturated with respect to sulphur phases. Speciation calculations that account for metal complexation with organic matter, considered as fulvic acids based on C1(s) NEXAFS spectroscopy, show that this mechanism is not sufficient to explain such deviation from equilibrium conditions. It is therefore hypothesized that the deviation results also from the influence of biological activity on the kinetics of mineral phase precipitation and dissolution, thus providing a dynamic system. The results of chemical analyses of sampled fluids are compared with speciation calculations and some implications for the assessment of metal mobility and natural attenuation in a context of landfill risk assessment are discussed. 相似文献
133.
Factors affecting trace element content in periurban market garden subsoil in Yunnan Province, China 总被引:1,自引:0,他引:1
Field investigations were conducted to measure subsoil trace element content and factors influencing content in an intensive periurban market garden in Chenggong County,Yunnan Province,South-West China.The area was divided into three different geomorphological units:specifically,mountain (M),transition (T) and lacustrine (L).Mean trace element content in subsoil were determined for Pb (58.2 mg/kg),Cd (0.89 mg/kg),Cu (129.2 mg/kg),and Zn (97.0 mg/kg).Strong significant relationships between trace element con... 相似文献