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51.
Abstract Dissolved iodine in sea water, about 60 μg L?1, usually exists in equal proportions as iodate and iodide ions. For their determination several techniques have been proposed (Riley, 1975); among them the volumetric one which depends upon the release of elementary iodine by the addition of acid and iodide ions to the iodate present in the sample. The liberated iodine is titrated with thiosulphate the equivalence point being detected photometrically (Matthews and Riley, 1970; Wong and Brewer, 1974) or it can also be reduced with an excess of thiosulphate and the residual thiosulphate back-titrated with iodate amperometrically (Barkley and Thompson, 1960; Truesdale and Spencer, 1974; Tsonkova and Kulev, 1981). To titrate total iodine in the sample the iodide must be previously oxidized to iodate with bromine (Barkley and Thompson, 1960; Tsonkova and Kulev, 1981) or permanganate (Schnepfe, 1972). In the amperometric procedure Truesdale and Spencer (1974) observed that platinum electrodes often do not respond reliably. 相似文献
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Needles of two conifer species, Picea abies and Pinus nigra, were used as passive samplers for monitoring air contamination by sampling at increasing distances from a suspected point source of DDT. Needle concentrations declined with increasing distance downwind of the point source allowing to identify spatial and temporal trends of accumulation. This suggested that conifer needles are effective biomonitors of contamination levels in areas characterized by the presence of semi-volatile substances. Differences in uptake were apparent between the species. Needle morphology and structure were studied with scanning electron microscope (SEM) as were dimensional parameters (surface area, volume). The results suggest that the concentrations depend on a mechanism involving the inner structure of the needles, specifically the number and accessibility of resin channels rather than their surface area. Pine needles have more channels with greater accessibility than spruce. The results suggest that spruce is more suitable for short term measurement while pine for determining long term cumulative exposure. 相似文献
54.
Giuseppe Gambolati Giorgio Galeati 《Journal of the American Water Resources Association》1990,26(4):677-685
ABSTRACT: The analysis of the sea depth in the vicinity of a thermal power plant is important in view of the heat dispersion and transport of the cooling water discharged from the energy production processes. The bathymetry of the Tyrrhenian Sea in the area facing the thermoelectric plant being built at Montalto di Castro, Italy, is reconstructed with the aid of the kriging technique. The large number of measurements (2038) precludes the use of a global interpolation model. At the same time, the steepness of the variogram suggests that the stochastic process is likely non-stationary. The latter problem is managed by detrending the observed records with a fourth-order polynomial drift determined with the least squares method. The global approach is replaced with local models with an influence radius of 70 m and a minimal number of interpolation records equal to 10. The detrended residuals appear to be second-order stationary having an isotropic vaniogram that is fitted equally well by a linear or a spherical function. The average size of the local interpolation models is 28, which ensures a high cemputational efficiency. The bathymetry of the sea area of interest is then reconstructed over a regular grid with a total of 3570 nodes. The estimation standard deviation maps show that the accuracy of the prediction is even greater than the prescribed tolerance (= 0.2 m) and indicate that future data collection campaigns require a less dense and, therefore, less expensive recording network. The redundant measurement profiles are identified. Their elimination still allows for bathymetry estimates affected by interpolation errors that fall within the project specifications. 相似文献
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56.
POEMS: A Case Study of an Italian Wine-Producing Firm 总被引:1,自引:1,他引:0
Over the last decade, researchers paid much attention to concepts such as Design for Environment, Extended Producer Responsibility,
Responsible Chain Management, and Eco-design. Many management tools and standards (such as EMAS, ISO 14001, LCA, EPD, Ecolabel)
have been developed to support companies in the evaluation and management of their environmental performance and to pursue
continual environmental improvement. The more recent development of the aforesaid fields looks at interorganizational environmental
management. Such an approach can complement the more traditional intraorganizational corporate environmental management approaches
and tools. A typical example of this new trend is the Product Oriented Environmental Management System (POEMS), which represents
the natural evolution of the above-mentioned tools, combining the features of EMS, EPD and Ecolabel. Although the structure
of the POEMS is still not standardized, many experimental applications have yet been carried out in Europe. In developing
a POEMS, a company needs to determine all of the environmental impacts caused at all life-cycle stages of the product and,
ideally, to reduce all of them through a continual commitment. The aim of the present study was to perform a survey of the
developed POEMS models and to analyze their peculiarities and drawbacks in the application to Small and Medium Enterprises.
A case study regarding an Italian winery company is presented. The study analyzes the structure and the activities of the
examined firm, in order to estimate direct and indirect environmental impacts following a life-cycle approach. The chosen
functional unit is a 0.75-L bottle of red wine. The article also suggests some solutions to improve the environmental performances
of the firm’s products. 相似文献
57.
In recent years, a significant part of the studies on air pollutants has been devoted to improve statistical techniques for forecasting the values of their concentrations in the atmosphere. Reliable predictions of pollutant trends are essential not only for setting up preventive measures able to avoid risks for human health but also for helping stakeholders to take decision about traffic limitations. In this paper, we present an operating procedure, including both pollutant concentration measurements (CO, SO2, NO2, O3, PM10) and meteorological parameters (hourly data of atmospheric pressure, relative humidity, wind speed), which improves the simple use of neural network for the prediction of pollutant concentration trends by means of the integration of multivariate statistical analysis. In particular, we used principal component analysis in order to define an unconstrained mix of variables able to improve the performance of the model. The developed procedure is particularly suitable for characterizing the investigated phenomena at a local scale. 相似文献
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59.
Isabella Scroccaro Marco Ostoich Georg Umgiesser Francesca De Pascalis Luigi Colugnati Giorgio Mattassi Marina Vazzoler Marco Cuomo 《Environmental science and pollution research international》2010,17(4):844-855
Background, aim and scope
Opposite interests must coexist in coastal areas: the presence of significant cities and urban centres, of touristic and recreational areas, and of extensive shellfish farming. To avoid local pollution caused by treated wastewaters along the Northern Adriatic coast (Friuli Venezia-Giulia and Veneto regions), marine outfall systems have been constructed. In this study, the application of a numerical dispersion model is used to support the traditional monitoring methods in order to link information concerning the hydrodynamic circulation and the microbiological features, to evaluate possible health risks associated with recreational and coastal shellfish farming activities. The study is a preliminary analysis of the environmental impact of wastewater treatment plants (WWTPs) with submarine discharge outfalls. It also could be useful for the water profile definition according to the Directive 2006/7/EC on the quality of bathing water and for the integrated areal analysis (Ostoich et al. 2006), to define the area of influence of each submarine discharge point. 相似文献60.
Alessandro Fumagalli Bruno Faggion Matteo Ronchini Giorgio Terzaghi Marco Lanfranchi Nicola Chirico Laura Cherchi 《Environmental science and pollution research international》2010,17(3):665-673