Fetal echocardiography using transvaginal and transabdominal probes during the first period of pregnancy: A comparative study

The authors compare the diagnostic possibilities of fetal transabdominal echocardiography versus transvaginal echocardiography. A larger diagnostic capacity is verified in different gestation ages with transvaginal probe between the 11th and 14th week of gestation. The results are emphasized by colour Doppler.     

Mapping lightning/human-caused wildfires occurrence under ignition point location uncertainty

Fire managers need to study fire history in terms of occurrence in order to understand and model the spatial distribution of the causes of ignition. Fire atlases are useful open sources of information, recording each single fire event by means of its geographical position. In such cases the fire event is considered as point-based, rather than area-based data, completely losing its surface nature. Thus, an accurate method is needed to estimate continuous density surfaces from ignition points where location is affected by a certain degree of uncertainty. Recently, the fire scientific community has focused its attention on the kernel density interpolation technique in order to convert point-based data into continuous surface or surface-data. The kernel density technique needs a priori setting of smoothing parameters, such as the bandwidth size. Up to now, the bandwidth size was often based on subjective choices still needing expert knowledge, eventually supported by empirical decisions, thus leading to serious uncertainties. Nonetheless, a geostatistical model able to describe the point concentration and consequently the clustering degree is required. This paper tries to solve such issues by implementing the kernel density adaptive mode. Lightning/human-caused fires occurrence was investigated in the region of Aragón's autonomy over 19 years (1983–2001) using 3428 and 4195 ignition points respectively for the two causes of fire origin. An analytical calibration procedure was implemented to select the most reliable density surfaces to reduce under/over-density estimation, overcoming the current drawbacks to define it by visual inspection or personal interpretation. Besides, ignition point location uncertainty was investigated to check the sensitivity of the proposed model. The different concentration degree and the dissimilar spatial pattern of the two datasets, allow testing the proposed calibration methodology under several conditions. After having discovered the slight sensitivity of the model to the exact point position, the obtained density surfaces for the two causes were combined to discover hotspot areas and spatial patterns of the two causes. Evident differences in spatial location of the origin causes were noted and described. The general trend follows the geographical features and the human activity of the study areas. The proposed technique should be promising to support decision-making in wildfire prevention actions, because of the occurrence map can be used as a response variable in fire risk predicting models.     

Geologic emissions of methane to the atmosphere

The atmospheric methane budget is commonly defined assuming that major sources derive from the biosphere (wetlands, rice paddies, animals, termites) and that fossil, radiocarbon-free CH4 emission is due to and mediated by anthropogenic activity (natural gas production and distribution, and coal mining). However, the amount of radiocarbon-free CH4 in the atmosphere, estimated at approximately 20% of atmospheric CH4, is higher than the estimates from statistical data of CH4 emission from fossil fuel related anthropogenic sources. This work documents that significant amounts of "old" methane, produced within the Earth crust, can be released naturally into the atmosphere through gas permeable faults and fractured rocks. Major geologic emissions of methane are related to hydrocarbon production in sedimentary basins (biogenic and thermogenic methane) and, subordinately, to inorganic reactions (Fischer-Tropsch type) in geothermal systems. Geologic CH4 emissions include diffuse fluxes over wide areas, or microseepage, on the order of 10(0)-10(2) mg m(-2) day(-1), and localised flows and gas vents, on the order of 10(2) t y(-1), both on land and on the seafloor. Mud volcanoes producing flows of up to 10(3) t y(-1) represent the largest visible expression of geologic methane emission. Several studies have indicated that methanotrophic consumption in soil may be insufficient to consume all leaking geologic CH4 and positive fluxes into the atmosphere can take place in dry or seasonally cold environments. Unsaturated soils have generally been considered a major sink for atmospheric methane, and never a continuous, intermittent, or localised source to the atmosphere. Although geologic CH4 sources need to be quantified more accurately, a preliminary global estimate indicates that there are likely more than enough sources to provide the amount of methane required to account for the suspected missing source of fossil CH4.     

Performance of a narrow buffer strip in abating agricultural pollutants in the shallow subsurface water flux

The performance of a narrow buffer strip in abating dissolved P, electrical conductivity and herbicides (terbuthylazine, alachlor, nicosulfuron, pendimethalin, linuron) in subsurface water coming from cropland was tested in an experiment carried out on the low plains of the Veneto Region (NE Italy). The experiment lasted from December 1997 to June 1999, monitoring subsurface water quality entering and exiting a buffer composed of a grass strip (5 m wide) and 1 m wide row of trees. Dissolved phosphorus concentrations were reduced by almost 100% passing through the buffer and in most cases exiting water satisfied the limit for avoiding eutrophication. A positive effect was also detected on ECW (reduced by 20%), while pH was not significantly altered. Herbicide concentration abatement varied between 60 and 90%, depending on the chemical and the time elapsed since application.     

Azo-dyes photocatalytic degradation in aqueous suspension of TiO2 under solar irradiation

The photodegradation of two common and very stable azo-dyes, i.e. methyl-orange (C₁₄H₁₄N₃SO₃Na) and orange II (C₁₆H₁₁N₂SO₄Na), is reported. The photocatalytic oxidation was carried out in aqueous suspensions of polycrystalline TiO₂ irradiated by sunlight. Compound parabolic collectors, installed at the “Plataforma Solar de Almería” (PSA, Spain) were used as the photoreactors and two identical reacting systems allowed to perform photoreactivity runs for the two dyes at the same time and under the same irradiation conditions. The disappearance of colour and substrates together with the abatement of total organic carbon content was monitored. The main sulfonate-containing intermediates were found to be in lower number in respect to those obtained under artificial irradiation. In particular there were no more evidence of the presence of hydroxylated transients. The dependence of dye photooxidation rate on: (i) substrate concentration; (ii) catalyst amount; and (iii) initial pH was investigated. The influence of the presence of strong oxidant species (H₂O₂, S₂O₈²⁻) and some ions (Cl⁻, SO₄²⁻) on the process was also studied.     

Community based initiatives to mainstream climate change adaptation into disaster risk reduction: evidence from the Hunter Valley (Australia)

In Australia, local communities often enact Community-Based Initiatives (CBIs) to respond to climate change through Climate Change Adaptation (CCA). CBIs can also be integrated into the Disaster Risk Reduction (DRR) agenda. The paper explores the extent to which CBIs promote the mainstreaming of CCA into DRR. Primary data were obtained from interviews with representatives of CBIs and supporting organisations in three local governments of the Hunter Valley (New South Wales, Australia). Findings show that CBIs recognise the potential contribution of climate change in modifying the local hazard profile. CBIs mainstream CCA into DRR by following four approaches: environmental and social justice; sustainability and transition; ecosystem-based approach; and adaptive planning. Partnerships were identified both among CBIs and between CBIs and City Councils; however, conflicts between CBIs, City Councils and business actors emerged, and a lack of commitment by multi-level governments in responding to climate change was revealed. The findings show that CBIs consider CCA and DRR within a broad everyday context related to vulnerability and local development. But we argue that assigning responsibility for climate change issues to CBIs is not a panacea and should not be the only local climate change response. Instead, CBIs need to be included in a larger and long-term commitment by actors that possess access to resources, such as higher levels of government. The paper provides a local Australian perspective on the effectiveness of mainstreaming CCA into DRR and furthers the conversation for the benefit of other communities facing similar challenges.     

Visible-light driven oxidation of gaseous aliphatic alcohols to the corresponding carbonyls via TiO2 sensitized by a perylene derivative

Sensitized P25 TiO₂ was prepared by wet impregnation with a home-prepared perylene dye, i.e., N,N′-bis(2-(1-piperazino)ethyl)-3,4,9,10-perylene-tetracarboxylic acid diimide dichloride (PZPER). Energy levels of PZPER were found to be compatible with those of TiO₂ allowing fast electron transfer. The obtained catalyst has been characterized and used in the gas-phase partial oxidation of aliphatic primary and secondary alcohols, i.e., methanol, ethanol, and 2-propanol. The reaction was carried out under cut-off (λ?>?400 nm) simulated solar radiation in O₂ atmosphere. The perylene derivative allowed a good absorbance of visible radiation thanks to its low optical energy gap (2.6 eV) which was evaluated by cyclic voltammetry. The optimal organic sensitizing amount was found to be 5.6 % w/w in terms of yield in carbonyl derivatives. Moreover, no change in reactivity/selectivity was observed after 10-h irradiation thus confirming the catalyst stability. Yields into formaldehyde, acetaldehyde, and acetone were 67, 70, and 96 %, respectively. No significant amounts of organic byproducts were detected but for methanol oxidation, whereas a minor amount of the substrate degraded to CO₂.