Preliminary assessment of surface soil lead concentrations in Melbourne,Australia

Urban soils in many cities have been found to be contaminated with lead from past usage of leaded petrol, deteriorating lead-based exterior paints and industrial sources. Currently, the spatial distribution of soil lead concentrations in the Melbourne metropolitan area is unknown. The objective of this study was to perform a preliminary assessment of the spatial distributions of the surface soil lead (Pb) concentrations in the Melbourne metropolitan area, Australia. Fifty-eight surface soil samples were collected at a depth of 0–2 cm along three linear transects oriented across the Melbourne metropolitan area. Surface soil samples were also collected at a higher density in five Melbourne suburbs. Soil cores (0–50 cm) were collected in four locations, soil transects were collected at intervals with distance away from the roadway (0–50 m) in two inner city parks, and one control soil sample was collected in a rural setting. The median soil Pb concentration of the soil transect samples was 173 mg/kg (range 32–710 mg/kg), and the median soil Pb concentration of the five suburbs was 69 mg/kg (range 9–1750 mg/kg). The suburb of Footscray had the highest soil Pb concentration with a median soil Pb concentration of 192 mg/kg (range 40–1750 mg/kg). Soil Pb concentrations were generally higher nearest the centre of the Melbourne metropolitan area and in the west of Melbourne and lower in the outer suburbs to the east and north of the city centre. Soil Pb concentrations decreased with distance from roadways in the two transects taken from urban parks, and soil lead decreased with depth in the four soil cores. The soil Pb concentrations in the Melbourne metropolitan area appear to be lower than soil lead concentrations observed in inner city areas of Sydney New South Wales (NSW) and Newcastle NSW. The spatial extent of the soil Pb hazard remains undefined in portions of the Melbourne metropolitan area.     

Using the paired comparison methodology to assess environmental values in the coastal zone of Ghana

Like many developing countries, Ghana is grappling with environmental issues, such as the degradation of coastal natural resources. In an attempt to ameliorate the current state of affairs, broad institutional arrangements and policy interventions have been put in place. However coastal natural resources are still being overexploited and the effects of this are felt more strongly by certain groups (such as women and the rural poor) than others. This has led to the argument pointing to an urgent need to include local resource users as active participants in environmental decision making and to incorporate their environmental values in the management of coastal natural resources. Using empirical data from women in two Ghanaian coastal communities, this paper highlights the importance of exploring how the environmental attitudes and values of women might be considered in the management of local coastal natural resources. It assesses effectiveness of the paired comparison methodology in this respects and how this method can be also used to prioritise their environmental concerns. The results show that in both areas respondents place the greatest importance on the coastal natural resources as sources of wealth creation and of food, values which are often described as being “anthropocentric”. The paper thus argues that having discovered that the ecological value placed on natural resources is low, initiatives that could win the support of people would be those that link the livelihood and wellbeing to coastal NRM. It emphasizes the fact that conservation cannot exist outside of people and social systems; nor will it succeed unless they are linked to the welfare of resource users.     

Discussion: “Meadow Restoration Increases Baseflow and Groundwater Storage in the Sierra Nevada Mountains of California” by Luke J.H. Hunt,Julie Fair,and Maxwell Odland

We discuss a recent paper which evaluated the hydrologic changes resulting from a pond‐and‐plug meadow restoration project in the Sierra Nevada Mountains of California. In the study, measurements of streamflow into and out of the meadow suggested late‐summer baseflow increased as much as five‐fold when compared with prerestoration conditions. However, the volume of streamflow attributed to the restored meadow (49,000–96,000 m³ over four months) would require that 2.5–4.8 m of saturated meadow soils drain during summer months. The groundwater data from this meadow record only 0.45 m of change over this timeframe, which is less than might be expected from plant use alone (0.75 m), suggesting this restored meadow may be acting as a water sink throughout summer rather than a source.     

The Anthropocene: From Global Change to Planetary Stewardship

Over the past century, the total material wealth of humanity has been enhanced. However, in the twenty-first century, we face scarcity in critical resources, the degradation of ecosystem services, and the erosion of the planet's capability to absorb our wastes. Equity issues remain stubbornly difficult to solve. This situation is novel in its speed, its global scale and its threat to the resilience of the Earth System. The advent of the Anthropence, the time interval in which human activities now rival global geophysical processes, suggests that we need to fundamentally alter our relationship with the planet we inhabit. Many approaches could be adopted, ranging from geoengineering solutions that purposefully manipulate parts of the Earth System to becoming active stewards of our own life support system. The Anthropocene is a reminder that the Holocene, during which complex human societies have developed, has been a stable, accommodating environment and is the only state of the Earth System that we know for sure can support contemporary society. The need to achieve effective planetary stewardship is urgent. As we go further into the Anthropocene, we risk driving the Earth System onto a trajectory toward more hostile states from which we cannot easily return.     

Relationships between dairy slurry total solids, gas emissions, and surface crusts

Livestock slurry storages are sources of methane (CH?), nitrous oxide (NO?), and ammonia (NH?) emissions. Total solids (TS) content is an indicator of substrate availability for CH? and N?O production and NH? emissions and is related to crust formation, which can affect these gas emissions. The effect of TS on these emissions from pilot-scale slurry storages was quantified from 20 May through 16 Nov. 2010 in Nova Scotia, Canada. Emissions from six dairy slurries with TS ranging from 0.3 to 9.5% were continuously measured using flow-through steady-state chambers. Methane emissions modeled using the USEPA methodology were compared with measured data focusing on emissions when empty storages were filled, and retention times were >30 d with undegraded volatile solids (VS) remaining in the system considered available for CH? production (VS carry-over). Surface crusts formed on all the slurries. Only the slurries with TS of 3.2 and 5.8% were covered completely for ～3 mo. Nitrous oxide contributed <5% of total greenhouse gas emissions for all TS levels. Ammonia and CH? emissions increased linearly with TS despite variable crusting, suggesting substrate availability for gas production was more important than crust formation in regulating emissions over long-term storage. Modeled CH? emissions were substantially higher than measured data in the first month, and accounting for this could improve overall model performance. Carried-over VS were a CH? source in months 2 through 6. The results of this study suggest that substrate availability regulates emissions over long-term storage and that modifying the USEPA model to better describe carbon cycling is warranted.     

The effect of digestion and dewatering on sudden increases and regrowth of indicator bacteria after dewatering

Several investigators have reported higher densities of indicator bacteria after dewatering of anaerobically digested biosolids. The increases appear to occur at two points in the biosolids process: the first, referred to as "sudden increase", occurs immediately after dewatering; the second, "regrowth", occurs during storage over longer periods. The objectives of this study were to examine the effect of digestion and dewatering processes on sudden increase and regrowth of fecal coliform and E. coli. Samples were collected from five thermophilic and five mesophilic digestion processes, with either centrifuge or belt filter press dewatering. Sudden increase typically was observed in the thermophilic processes with centrifuge dewatering and was not observed in the mesophilic processes with either centrifuge or belt filter press dewatering. Regrowth was observed in both thermophilic and mesophilic processes with centrifuge dewatering but not belt filter press dewatering.     

Estimation of Smog Effects in the Hydrocarbon-Nitric Oxide System

Hydrocarbon components (propylene, simulated auto exhaust, or authentic auto exhaust) were irradiated in the presence of nitric oxide in large chambers instrumented for measurements of numerous variables. Eye irritation was measured using a selected panel of human subjects. The various dependent variables are presented as functions of the reactant concentrations by means of contour diagrams derived by computer treatment. The effect of “hydrocarbon” and nitric oxide levels on smog effects are discussed; the observed relationships between end effects and reaction rates are considered. The study simulated the effects of varying degrees of vehicular emissions control over one or both reactants and has a bearing on the establishment of vehicle emission standards in California.     

Sorption and degradation of neonicotinoid insecticides in tropical soils

ABSTRACT

Neonicotinoids are the most widely applied class of insecticides in cocoa farming in Ghana. Despite the intensive application of these insecticides, knowledge of their fate in the Ghanaian and sub-Saharan African environment remains low. This study examined the behavior of neonicotinoids in soils from cocoa plantations in Ghana by estimating their sorption and degradation using established kinetic models and isotherms. Studies of sorption were conducted using the batch equilibrium method on imidacloprid, thiamethoxam, clothianidin, acetamiprid and thiacloprid, while degradation of imidacloprid, thiamethoxam and their respective deuterated counterparts was studied using models proposed by the European forum for coordination of pesticide fate and their use (FOCUS). Analytes were extracted using the quick, easy, cheap, effective, rugged and safe (QuEChERS) procedure and quantified by liquid chromatography-tandem mass spectrometry (LC–MS/MS). Average recoveries were high (≥ 85%) for all analytes. The findings from the study suggest that neonicotinoid insecticides may be persistent in the soils studied based on estimated half-lives > 150 days. The study also revealed generally low-sorption coefficients for neonicotinoids in soils, largely influenced by soil organic carbon.     

A Superiority-Inferiority-Based Inexact Fuzzy Stochastic Programming Approach for Solid Waste Management Under Uncertainty

A superiority–inferiority-based inexact fuzzy stochastic programming (SI-IFSP) model was developed for planning municipal solid waste management systems under uncertainty. The SI-IFSP approach represents a new attempt to tackle multiple uncertainties in objective function coefficients which are beyond the capabilities of existing inexact programming methods. Through introducing the concept of fuzzy random boundary interval, SI-IFSP is capable of reflecting multiple uncertainties (i.e., interval values, fuzzy sets, probability distributions, and their combinations) in both the objective function and constraints, leading to enhanced system robustness. The developed SI-IFSP method was applied to a case study of long-term municipal solid waste management. Useful solutions were generated. A number of decision alternatives could be generated based on projected applicable conditions, reflecting the compromise between system optimality and reliability as well as the tradeoffs between economic and environmental objectives. Moreover, the consequences of system violations could be quantified through introducing a set of economic penalties, reflecting the relationships between system costs and constraint violation risks. The results suggest that the proposed SI-IFSP method can explicitly address complexities in municipal solid waste management systems and is applicable to practical waste management problems.     

Why geodiversity matters in valuing nature's stage

Geodiversity—the variability of Earth's surface materials, forms, and physical processes—is an integral part of nature and crucial for sustaining ecosystems and their services. It provides the substrates, landform mosaics, and dynamic physical processes for habitat development and maintenance. By determining the heterogeneity of the physical environment in conjunction with climate interactions, geodiversity has a crucial influence on biodiversity across a wide range of scales. From a literature review, we identified the diverse values of geodiversity; examined examples of the dependencies of biodiversity on geodiversity at a site‐specific scale (for geosites <1 km² in area); and evaluated various human‐induced threats to geosites and geodiversity. We found that geosites are important to biodiversity because they often support rare or unique biota adapted to distinctive environmental conditions or create a diversity of microenvironments that enhance species richness. Conservation of geodiversity in the face of a range of threats is critical both for effective management of nature's stage and for its own particular values. This requires approaches to nature conservation that integrate climate, biodiversity, and geodiversity at all spatial scales.