Blends of Zein and Nylon-6

Blends of zein and nylon-6 (55?k) in formic acid were used to produce solution cast films and electrospun fibers. When the amount of nylon-6 was 8?% or less blends were formed that had improved tensile strength and reduced solubility. The blends were analyzed using physical property measurements, DSC and IR spectra. Using between 2 and 8?% nylon-6 provided a 33?% increase in tensile strength. Young??s modulus increased by over 50?% in this range. In general elongation was lower for all formulations. Surprisingly the cast films having 0.5?C8?% nylon-6 had improved solvent resistance to 90?% ethanol/water. Electrospun fibers were produced from formic acid solutions of zein and nylon-6 where the amount of nylon was 0, 2 and 6. Fibers produced from 27?% spinning solids had average diameters on the order of 0.5???m. Reducing the spinning solids to 21?% provide slightly smaller fibers however, the fibers had more defects.     

Quantifying the conservation gains from shared access to linear infrastructure

The proliferation of linear infrastructure such as roads and railways is a major global driver of cumulative biodiversity loss. One strategy for reducing habitat loss associated with development is to encourage linear infrastructure providers and users to share infrastructure networks. We quantified the reductions in biodiversity impact and capital costs under linear infrastructure sharing of a range of potential mine to port transportation links for 47 mine locations operated by 28 separate companies in the Upper Spencer Gulf Region of South Australia. We mapped transport links based on least‐cost pathways for different levels of linear‐infrastructure sharing and used expert‐elicited impacts of linear infrastructure to estimate the consequences for biodiversity. Capital costs were calculated based on estimates of construction costs, compensation payments, and transaction costs. We evaluated proposed mine‐port links by comparing biodiversity impacts and capital costs across 3 scenarios: an independent scenario, where no infrastructure is shared; a restricted‐access scenario, where the largest mining companies share infrastructure but exclude smaller mining companies from sharing; and a shared scenario where all mining companies share linear infrastructure. Fully shared development of linear infrastructure reduced overall biodiversity impacts by 76% and reduced capital costs by 64% compared with the independent scenario. However, there was considerable variation among companies. Our restricted‐access scenario showed only modest biodiversity benefits relative to the independent scenario, indicating that reductions are likely to be limited if the dominant mining companies restrict access to infrastructure, which often occurs without policies that promote sharing of infrastructure. Our research helps illuminate the circumstances under which infrastructure sharing can minimize the biodiversity impacts of development.     

Characterizing Spatial Uncertainty when Integrating Social Data in Conservation Planning

Recent conservation planning studies have presented approaches for integrating spatially referenced social (SRS) data with a view to improving the feasibility of conservation action. We reviewed the growing conservation literature on SRS data, focusing on elicited or stated preferences derived through social survey methods such as choice experiments and public participation geographic information systems. Elicited SRS data includes the spatial distribution of willingness to sell, willingness to pay, willingness to act, and assessments of social and cultural values. We developed a typology for assessing elicited SRS data uncertainty which describes how social survey uncertainty propagates when projected spatially and the importance of accounting for spatial uncertainty such as scale effects and data quality. These uncertainties will propagate when elicited SRS data is integrated with biophysical data for conservation planning and may have important consequences for assessing the feasibility of conservation actions. To explore this issue further, we conducted a systematic review of the elicited SRS data literature. We found that social survey uncertainty was commonly tested for, but that these uncertainties were ignored when projected spatially. Based on these results we developed a framework which will help researchers and practitioners estimate social survey uncertainty and use these quantitative estimates to systematically address uncertainty within an analysis. This is important when using SRS data in conservation applications because decisions need to be made irrespective of data quality and well characterized uncertainty can be incorporated into decision theoretic approaches.     

The consequences of land use change on nutrient exports: a regional scale assessment in south-west Victoria, Australia

Estimation of nutrient load production based on multi-temporal remotely sensed land use data for the Glenelg-Hopkins region in south-west Victoria, Australia, is discussed. Changes in land use were mapped using archived Landsat data and computerised classification techniques. Land use change has been rapid in recent history with 16% of the region transformed in the last 22 years. Total nitrogen and phosphorus loads were estimated using an export coefficient model. The analysis demonstrates an increase in modelled nitrogen and phosphorus loadings from 1980 to 2002. Whilst such increases were suspected from past anecdotal and ad-hoc evidence, our modelling estimated the magnitude of such increases and thus demonstrated the enormous potential of using remote sensing and GIS for monitoring regional scale environmental processes.     

Forecasting environmental equity: air quality responses to road user charging in Leeds, UK

Sustainable development requires that the goals of economic development, environmental protection and social justice are considered collectively when formulating development strategies. In the context of planning sustainable transport systems, trade-offs between the economy and the environment, and between the economy and social justice have received considerable attention. In contrast, much less attention has been paid to environmental equity, the trade-off between environmental and social justice goals, a significant omission given the growing attention to environmental justice by policy makers in the EU and elsewhere. In many countries, considerable effort has been made to develop clean transport systems by using, for example, technical, economic and planning instruments. However, little effort has been made to understand the distributive and environmental justice implications of these measures. This paper investigates the relationship between urban air quality (as NO2) and social deprivation for the city of Leeds, UK. Through application of a series of linked dynamic models of traffic simulation and assignment, vehicle emission, and pollutant dispersion, the environmental equity implications of a series of urban transport strategies, including road user cordon and distance-based charging, road network development, and emission control are assessed. Results indicate a significant degree of environmental inequity exists in Leeds. Analysis of the transport strategies indicates that this inequity will be reduced through natural fleet renewal, and, perhaps contrary to expectations, road user charging is also capable of promoting environmental equity. The environmental equity response is, however, sensitive to road pricing scheme design.     

SEDIMENT TRANSPORT AND CHANNEL MORPHOLOGY OF SMALL,FORESTED STREAMS1

This paper reviews sediment transport and channel morphology in small, forested streams in the Pacific Northwest region of North America to assess current knowledge of channel stability and morphology relevant to riparian management practices around small streams. Small channels are defined as ones in which morphology and hydraulics may be significantly influenced by individual clasts or wood materials in the channel. Such channels are headwater channels in close proximity to sediment sources, so they reflect a mix of hillslope and channel processes. Sediment inputs are derived directly from adjacent hillslopes and from the channel banks. Morphologically significant sediments move mainly as bed load, mainly at low intensity, and there is no standard method for measurement. The larger clastic and woody elements in the channel form persistent structures that trap significant volumes of sediment, reducing sediment transport in the short term and substantially increasing channel stability. The presence of such structures makes modeling of sediment flux in these channels — a potential substitute for measurement — difficult. Channel morphology is discussed, with some emphasis on wood related features. The problem of classifying small channels is reviewed, and it is recognized that useful classifications are purpose oriented. Reach scale and channel unit scale morphologies are categorized. A “disturbance cascade” is introduced to focus attention on sediment transfers through the slope channel system and to identify management practices that affect sediment dynamics and consequent channel morphology. Gaps in knowledge, errors, and uncertainties have been identified for future research.     

The remaining islands with primary rain forest: A global resource

Islands with large tracts of primary rain forest constitute a distinct complex of terrestrial and marine ecosystems with global significance because of high levels of biological richness or, in the case of oceanic islands, the evolutionary distinctiveness of the organisms that they support. The myriad of small habitat units makes these settings particularly prone to fragmentation and thus problematic for the conservation of biological diversity. Most of the remaining examples of islands with primary rain forest are in the Pacific Rim, particularly in Indonesia, and there are threats from intensive timber harvesting, mining, tourism, and dismemberment of traditional convervation systems. Prospects for inventorying, monitoring, and protecting the remaining islands with relatively pristine successional mosaics of humid forest and shallow marine habitats within a framework global monitoring are explored. Recommendations are made for a program of expanded use of the biosphere reserve designation for rain forest islands and adjacent marine areas.     

GEOMETRIC VARIATIONS IN RESERVOIR WATER QUALITY1

ABSTRACT: In developing water quality models for lakes and reservoirs, the assumptions of one-dimensionality (i.e., water quality changes are significant only in one dimension – usually depth), as well as two-dimensionality (considering the length and depth of the water body), have been utilized to predict water quality. In both caws, the assumption of lateral homogeneity is made. A field study was undertaken to determine the change of water quality in the lateral dimension. The main study reservoir was Center Hill Lake in Middle Tennessee. Data were also obtained for Cherokee Lake in East Tennessee. Several water quality parameters (temperature, dissolved oxygen, pH, conductivity, and oxidation reduction potential) were analyzed over the length, breadth, and depth of these reservoirs from pre-stratification through post-stratification. The statistical and theoretical three-dimensional analysis showed the expected variation for each water quality parameter in each direction. The influence of the lateral dimension on water quality management and modeling was found to be negligible.     

Evaluation of management effectiveness of protected areas in the Volta Basin,Ghana: perspectives on the methodology for evaluation,protected area financing and community participation

ABSTRACT

Protected areas are widely recognized as an important strategy for biodiversity conservation. Most of the sites are, however, poorly managed as resource exploitation by fringe communities and low government funding, among other things, threaten their management effectiveness. We used the World Commission on Protected Areas framework for designing management effectiveness evaluation systems, with the Rapid Assessment and Prioritization of Protected Areas Management (RAPPAM) methodology as a tool, to evaluate six components of the management cycle at six sites in Ghana for their management effectiveness. We examined the robustness of RAPPAM as an evaluation tool in the African context. The results showed that most of the sites evaluated are vulnerable and exposed to various degrees of pressure and threats, including poverty in the nearby communities, adjacent land-use and encroachment. On RAPPAM, we noted that apart from inconsistencies in some of the assessment scores due to the biases associated with the self-assessment approach of the methodology, the management effectiveness framework places little emphasis on financing and community participation, though both play major roles in the management process. We proposed a modification of the framework within the African context, to address effectively the underlying courses of pressure and threats facing Ghana’s protected areas.