UBAF与IBAC结合工艺应用于化工污水回用的试验研究

在工业废水处理中,化工废水是一种比较难处理的废水。文章介绍了利用UBAF与IBAC结合工艺对化工污水进行 深度处理,使其达到回用的要求,并具有良好的效果。该工艺具有占地面积小,投资省,运行成本底,管理方便等特点。结果 表明:UBAF与IBAC结合的处理工艺对化工污水进行深度处理能够取得良好的效果,处理后的污水完全可以达到循环冷却用 水的水质标准。     

Agricultural Adaptation to Drought for Different Cropping Systems in Southern China under Climate Change

This study investigates agricultural adaptation to drought for different cropping systems in southern China. The study area was divided into three regions: South China (SC), South of the Yangtze River (SYR), and Southwest China (SWC). An index of agricultural adaptation to drought (D) was established. Our findings indicated that the average total crop water demand varied greatly among the regions from 1961 to 2010 in southern China. The maximum value was found in the SC region, followed by the SYR and SWC regions. The effects of droughts on different crops were noticeable. Frequent droughts were recorded in late rice than in early rice in the SC and SYR regions. Droughts in the SWC region mainly affected winter wheat. Moreover, the effects of droughts on crops varied during different growth stages. More frequent and serious droughts occurred during the crop critical flowering stage. Particularly, the frequency of moderate and severe droughts for late rice in the SYR region was 62% during the critical flowering stage. For the SC and SYR regions, the D values of early rice (0.29 and 0.29) were lower than that of late rice (0.31 and 0.33), respectively. For the SWC region, the D values of winter wheat and rice were both low, with averages of 0.16 and 0.29, respectively. Our study provides interesting insights for improving the drought defense abilities for different cropping systems by changing crop planting proportion on a regional scale in China.     

涧河新安县城段河道内生态环境需水量研究

以涧河新安县城区段为例,在统计分析1959年-2010年新安水文站水文资料的基础上,采用水文学中的Tennant法和水力学中的R2CROSS法分析计算了河道内基本生态需水量,另外还计算了河道水质净化需水、河道蒸发渗漏需水、河道最小输沙需水.按照不重复计算的原则,在几个方面需水量中取最大值,得出涧河城区段河道内生态环境需水量为3 010.0 m3/s,此水量是该河段恢复河流生态结构与功能健康的最佳需水量,这一结果对河道的水资源可持续利用和维持河流生态系统平衡都有着重要的参考作用.     

船舶压载水处理技术的应用与研究进展

船舶压载水在船舶航行的安全保障和稳定性提升方面起着至关重要的作用,然而压载水直接排放也造成了海洋污染和外来生物入侵等负面影响.通过研究各国压载水的水质特点及处理现状,总结了当前常用于压载水处理的物理、化学和生物等方法及其原理和特点,介绍了几种现阶段中国自主开发的压载水处理技术和装置以及对各装置的性能及特点进行分析,并提出了各压载水处理设备在使用中应注意的问题.通过总结近年压载水处理所产生的问题对未来压载水处理领域提出一些建议.     

Predicting heavy metals' adsorption edges and adsorption isotherms on MnO2 with the parameters determined from Langmuir kinetics

Although surface complexation models have been widely used to describe the adsorption of heavy metals, few studies have verified the feasibility of modeling the adsorption kinetics, edge, and isotherm data with one pH-independent parameter. A close inspection of the derivation process of Langmuir isothermrevealed that the equilibriumconstant derived from the Langmuir kinetic model, K_S-kinetic, is theoretically equivalent to the adsorption constant in Langmuir isotherm, K_S-Langmuir. The modified Langmuir kinetic model (MLK model) and modified Langmuir isothermmodel (MLImodel) incorporating pH factor were developed. The MLKmodel was employed to simulate the adsorption kinetics of Cu(II), Co(II), Cd(II), Zn(II) and Ni(II) on MnO₂ at pH 3.2 or 3.3 to get the values of K_S-kinetic. The adsorption edges of heavy metals could be modeled with the modified metal partitioning model (MMP model), and the values of K_S-Langmuirwere obtained. The values of K_S-kinetic and K_S-Langmuir are very close to each other, validating that the constants obtained by these two methods are basically the same. The MMP model with K_S-kinetic constants could predict the adsorption edges of heavy metals on MnO₂ very well at different adsorbent/adsorbate concentrations. Moreover, the adsorption isotherms of heavy metals on MnO₂ at various pH levels could be predicted reasonably well by the MLI model with the K_S-kinetic constants.     

渗滤液的反渗透浓缩液回灌技术应用

以宜昌、宁国、蒙城垃圾填埋场为例,介绍了碟管式反渗透(DTRO)——浓缩液回灌工艺,研究发现:浓缩液回灌方式应根据垃圾填埋场的地理特征和业主的具体要求来确定。山谷型填埋场可以采用石笼回灌法,施工简单,成本较低,另外也可采用两层生物滤化床方式,成本稍高,但效果较好;平原型填埋场宜采用两层生物滤化床方式,而采用石笼回灌法容易出现短流现象。浓缩液回灌对渗滤液电导率无明显影响,不会影响后续反渗透系统的正常运行。     

炼油污水三泥脱水装置调试运行

炼油污水处理装置的三泥脱水实验表明,剩余污泥的脱水性能最好。根据实验结果,将浮渣与剩余污泥按比例混合进行脱水,连续少量掺入油泥,调整转速与混凝剂用量后取得较好的脱水效果。在离心机处理量13～15m3/h,离转速3000r/min,差转速5～7r/min,混凝剂量5kg/h的工况下,离心机所产泥饼含水率<85%、滤液ρ(COD)<800mg/L。脱水处理直接成本19.6元/m3。     

地方政府投融资平台信息披露问题研究

地方政府投融资平台在促进地方经济发展，推动城市化进程，应对国际金融危机等方面发挥了重要作用。但由于缺乏统一的管理，各地方政府投融资平台财务状况披露不公开、不透明，债务风险急剧扩大，引起了有关部门和专家学者的高度关注。各地方政府应将融资平台的各种信息，特别是债务情况，定期向主管部门报告，建立地方投融资平台信用评价方法，使得投融资平台朝着健康、良性的方向发展。     

Estimation of explosion energy based on fragment characteristics

Explosions of vessels containing high pressure gases or superheated liquids are a common accident in the chemical industry. Fragments are the most information-rich physical evidence in accident analysis. A method is presented to calculate the total explosion energy based on the characteristics of fragments from the scene of an accident, such as mass, horizontal displacement, etc. The implicit expressions of the initial velocity can be obtained through analysing the trajectory equations of the fragments and the data obtained from the scene of the accident. The total energy is calculated from the relationship between the total explosion energy and the kinetic energy of the fragment. During the calculation there are some uncertain parameters, e.g., the energy factor and the initial angle. To solve the parameter uncertainties, a Monte-Carlo simulation is introduced. Analysis of an industrial accident shows that it is feasible to estimate the total explosion energy using the maximum probability density interval with the proposed methodology.     

Experimental evidence of colloids and nanoparticles presence from 25 waste leachates

The potential colloids release from a large panel of 25 solid industrial and municipal waste leachates, contaminated soil, contaminated sediments and landfill leachates was studied. Standardized leaching, cascade filtrations and measurement of element concentrations in the microfiltrate (MF) and ultrafiltrate (UF) fraction were used to easily detect colloids potentially released by waste. Precautions against CO₂ capture by alkaline leachates, or bacterial re-growth in leachates from wastes containing organic matter should be taken. Most of the colloidal particles were visible by transmission electron microscopy with energy dispersion spectrometry (TEM–EDS) if their elemental MF concentration is greater than 200 μg l^?1. If the samples are dried during the preparation for microscopy, neoformation of particles can occur from the soluble part of the element. Size distribution analysis measured by photon correlation spectroscopy (PCS) were frequently unvalid, particularly due to polydispersity and/or too low concentrations in the leachates. A low sensitivity device is required, and further improvement is desirable in that field. For some waste leachates, particles had a zeta potential strong enough to remain in suspension. Mn, As, Co, Pb, Sn, Zn had always a colloidal form (MF concentration/UF concentration > 1.5) and total organic carbon (TOC), Fe, P, Ba, Cr, Cu, Ni are partly colloidal for more than half of the samples). Nearly all the micro-pollutants (As, Ba, Co, Cr, Cu, Mo, Ni, Pb, Sb, Sn, V and Zn) were found at least once in colloidal form greater than 100 μg l^?1. In particular, the colloidal forms of Zn were always by far more concentrated than its dissolved form. The TEM–EDS method showed various particles, including manufactured nanoparticles (organic polymer, TiO₂, particles with Sr, La, Ce, Nd). All the waste had at least one element detected as colloidal. The solid waste leachates contained significant amount of colloids different in elemental composition from natural ones. The majority of the elements were in colloidal form for wastes of packaging (3), a steel slag, a sludge from hydrometallurgy, composts (2), a dredged sediment (#18), an As contaminated soil and two active landfill leachates.These results showed that cascade filtration and ICP elemental analysis seems valid methods in this field, and that electronic microscopy with elemental detection allows to identify particles. Particles can be formed from dissolved elements during TEM sample preparation and cross-checking with MF and UF composition by ICP is useful. The colloidal fraction of leachate of waste seems to be a significant source term, and should be taken into account in studies of emission and transfer of contaminants in the environment. Standardized cross-filtration method could be amended for the presence of colloids in waste leachates.