全文获取类型
收费全文 | 2548篇 |
免费 | 84篇 |
国内免费 | 875篇 |
专业分类
安全科学 | 191篇 |
废物处理 | 148篇 |
环保管理 | 210篇 |
综合类 | 1267篇 |
基础理论 | 444篇 |
污染及防治 | 903篇 |
评价与监测 | 125篇 |
社会与环境 | 94篇 |
灾害及防治 | 125篇 |
出版年
2024年 | 1篇 |
2023年 | 44篇 |
2022年 | 120篇 |
2021年 | 95篇 |
2020年 | 79篇 |
2019年 | 92篇 |
2018年 | 77篇 |
2017年 | 107篇 |
2016年 | 109篇 |
2015年 | 145篇 |
2014年 | 222篇 |
2013年 | 267篇 |
2012年 | 197篇 |
2011年 | 212篇 |
2010年 | 193篇 |
2009年 | 171篇 |
2008年 | 169篇 |
2007年 | 128篇 |
2006年 | 150篇 |
2005年 | 102篇 |
2004年 | 89篇 |
2003年 | 80篇 |
2002年 | 86篇 |
2001年 | 114篇 |
2000年 | 74篇 |
1999年 | 70篇 |
1998年 | 72篇 |
1997年 | 52篇 |
1996年 | 40篇 |
1995年 | 37篇 |
1994年 | 30篇 |
1993年 | 21篇 |
1992年 | 18篇 |
1991年 | 7篇 |
1990年 | 14篇 |
1989年 | 3篇 |
1988年 | 5篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 1篇 |
排序方式: 共有3507条查询结果,搜索用时 171 毫秒
471.
Treatment of oilfield produced water was investigated using an anaerobic process coupled with micro-electrolysis (ME), focusing
on changes in chemical oxygen demand (COD) and biodegradability. Results showed that COD exhibited an abnormal change in
the single anaerobic system in which it increased within the first 168 hr, but then decreased to 222 mg/L after 360 hr. The biological
oxygen demand (five-day) (BOD5)/COD ratio of the water increased from 0.05 to 0.15. Hydrocarbons in the wastewater, such as pectin,
degraded to small molecules during the hydrolytic acidification process. Comparatively, the e ect of ME was also investigated. The
COD underwent a slight decrease and the BOD5/COD ratio of the water improved from 0.05 to 0.17 after ME. Removal of COD was
38.3% under the idealized ME conditions (pH 6.0), using iron and active carbon (80 and 40 g/L, respectively). Coupling the anaerobic
process with ME accelerated the COD removal ratio (average removal was 53.3%). Gas chromatography/mass spectrometry was used
to analyze organic species conversion. This integrated system appeared to be a useful option for the treatment of water produced in
oilfields. 相似文献
472.
Heavy metal (Pb,Zn) uptake and chemical changes in rhizosphere soils of four wetland plants with different radial oxygen loss 总被引:4,自引:0,他引:4
Lead and Zn uptake and chemical changes in rhizosphere soils of four emergent-rooted wetland plants; Aneilema bracteatum,
Cyperus alternifolius, Ludwigia hyssopifolia and Veronica serpyllifolia were investigated by two experiments: (1) rhizobag filled with
“clean” or metal-contaminated soil for analysis of Pb and Zn in plants and rhizosphere soils; and (2) applied deoxygenated solution for
analyzing their rates of radial oxygen loss (ROL). The results showed that the wetland plants with di erent ROL rates had significant
e ects on the mobility and chemical forms of Pb and Zn in rhizosphere under flooded conditions. These e ects were varied with
di erent metal elements and metal concentrations in the soils. Lead mobility in rhizosphere of the four plants both in the “clean”
and contaminated soils was decreased, while Zn mobility was increased in the rhizosphere of the “clean” soil, but decreased in the
contaminated soil. Among the four plants, V. serpyllifolia, with the highest ROL, formed the highest degree of Fe plaque on the root
surface, immobilized more Zn in Fe plaque, and has the highest e ects on the changes of Zn form (EXC-Zn) in rhizosphere under both
“clean” and contaminated soil conditions. These results suggested that ROL of wetland plants could play an important role in Fe plaque
formation and mobility and chemical changes of metals in rhizosphere soil under flood conditions. 相似文献
473.
Effects of silica nanoparticles on growth and photosynthetic pigment contents
of Scenedesmus obliquus 总被引:1,自引:0,他引:1
To assess the aquatic ecosystem safety for silica (SiO2) nanoparticles (NPs), the growth inhibition and photosynthetic pigment contents of Scenedesmus obliquus in logarithm growth phase exposed to SiO2 NPs and SiO2 bulk particles (BPs) suspensions were measured. SiO2 NPs with 10-20 nm diameters were found to be toxic. The 20% effective concentration (EC20) values for 72 and 96 hr were 388.1 and 216.5 mg/L, respectively. The contents of chlorophyll decreased significantly under moderate and high concentratio... 相似文献
474.
Low-cost, easy-maintenance and high-e ciency decentralized wastewater treatment technologies are urgently needed in rural areas
of China. Processes with high potential for phosphorus removal are of great interest. However, commonly used treatment methods often
do not meet the strict criteria for removing phosphorus from rural wastewater. In order to search an economic and simple technology
for phosphorus removal from the common bio-technologies e uent, seven soil types collected from di erent rural areas in China were
investigated for their ability to remove phosphorus. X-ray di raction (XRD) was used to analyse the mineral structure, and inductively
coupled plasma optical emission spectrometer (ICP-OES) was used to analyse the geochemical composition of the soil samples. Three
primary minerals – quartz, albite and montmorillonite – were clearly detected. The samples were divided into two soil types, acidic
soils and alkaline soils, based on their pH values. The geochemical composition study indicated that a higher percentage of Ca and Mg
occurred in alkaline soils (pH > 8) than in acidic soils (pH < 6.5). Adsorption isotherms from batch experiments fitted the Langmuir
and Freundlich models well, the maximum P adsorption capacities ranged from 0.256 to 1.598 mg P/g, indicating a high phosphorus
removal potential for all of these soils. The P fractions extracted revealed that the sum of NaOH-extracted inorganic P (NaOH-Pi) was
the major P component in the acidic soils, and CaCO3-bound phosphorus (Ca-P) in the alkaline soils. Dynamic adsorption simulation
showed that these soils have the ability to remove phosphorus from wastewater. 相似文献
475.
Regional crop yield, water consumption and water use efficiency and their responses to climate change in the North China Plain 总被引:9,自引:0,他引:9
Xingguo Mo Suxia Liu Zhonghui Lin Ruiping Guo 《Agriculture, ecosystems & environment》2009,134(1-2):67-78
The North China Plain (NCP) is one of the most important regions for food production in China, with its agricultural system being significantly affected by the undergoing climate change and vulnerable with water stress. In this study, the Vegetation Interface Processes (VIP) model is used to evaluate crop yield, water consumption (ET), and water use efficiency (WUE) of a winter wheat (Triticum aestivum L.)–summer maize (Zea mays L.) double cropping system in the NCP from 1951 to 2006. Their responses to future climate scenarios of 21st century projected by the GCM (HadCM3) with Intergovernmental Panel on Climate Change Special Report on Emission Scenario (IPCC SRES) A2 and B1 emissions are investigated. The results show a rapid enhancement of crop yield in the past 56 years, accompanying with slight increment of ET and noticeable improvement of WUE. There exist spatial patterns of crop yield stemmed mainly from soil quality and irrigation facilities. For climate change impacts, it is found that winter wheat yield will significantly increase with the maximum increment in A2 occurring in 2070s with a value of 19%, whereas the maximum in B1 being 13% in 2060s. Its ET is slightly intensified, which is less than 6%, under both A2 and B1 scenarios, giving rise to the improvement of WUE by 10% and 7% under A2 and B1 scenarios, respectively. Comparatively, summer maize yield will gently decline by 15% for A2 and 12% for B1 scenario, respectively. Its ET is obviously increasing since 2050s with over 10% relative change, leading to a lower WUE with more than 25% relative change under both scenarios in 2090s. Therefore, possible adaptation countermeasures should be developed to mitigate the negative effects of climate change for the sustainable development of agro-ecosystems in the NCP. 相似文献
476.
城市合流污水A2/O处理系统中TTC ETS活性监测研究 总被引:2,自引:1,他引:1
研究了温度和F/M的变化对A2/O系统TTCETS活性的影响,分析了TTCETS活性与COD降解的相关关系;通过低C/N冲击下TTCETS活性和理化指标的比较,讨论了以TTCETS活性表征系统运行状况的优劣.结果表明,一定范围内,温度与F/M均与TTCETS活性成正相关,TTCETS活性(TF/TSS·t)变化范围约13.2~48.3 mg/(g·h),最大值约为60 mg/(g·h);TTCETS活性与COD去除率相关性显著,并且TTCETS活性可预警系统的异常状态,当TTCETS活性为41.0 mg/(g·h)时,COD去除效率最高. 相似文献
477.
西部管道工程HSE一体化绩效管理应用研究 总被引:1,自引:0,他引:1
分析了我国管道工程项目HSE绩效管理存在问题,运用绩效管理理论,结合“PMT(业主)+PMC(监理)+EPC(施工总承包方)”一体化模式及西部管道工程,阐述了HSE一体化绩效管理体系的建立及应用情况。 相似文献
478.
采用H_2O_2溶液对兰炭末进行改性,并将改性后的兰炭末用于硝基苯生产废水(COD为560 mg/L)的吸附处理。对改性前后的兰炭末进行了表征,考察了吸附效果的影响因素,并对吸附前后改性兰炭末的燃烧热进行了测定。表征结果显示,兰炭末经改性后比表面积和孔径均增大。实验结果表明:在改性兰炭末投加量为0.2 g/m L、吸附时间为180 min、吸附温度为30℃的条件下,废水的COD去除率为93.4%,处理出水达到GB 8978—1996《污水综合排放标准》中规定的排放标准;改性兰炭末对废水中COD的吸附过程符合准二级动力学方程和Freundlich等温吸附模型;吸附后的改性兰炭末燃烧热值增大。 相似文献
479.
Ye Sun Yuan Meng Xiaoyan Guo Tianle Zhu Hongju Liu Wenpei Li 《Journal of Material Cycles and Waste Management》2016,18(4):618-624
Experiments were conducted using a bubbling reactor to investigate nitrogen oxide absorption in the calcium sulfite slurry. The effects of CaSO3 concentration, NO2/NO mole ratio and O2 concentrations on NO2 and SO2 absorption efficiencies were investigated. Five types of additives, including MgSO4, Na2SO4, FeSO4, MgSO4/Na2SO4 and FeSO4/Na2SO4, had been evaluated for enhancing NO2 absorption in CaSO3 slurry. Results showed that CaSO3 concentration had significant impact on NO2 and SO2 absorption efficiencies, and the highest absorption efficiencies of SO2 and NO2 could reach about 99.5 and 75.0 %, respectively. Furthermore, the NO2 absorption was closely related to the NO2/NO mole ratio, and the existence of NO2 in flue gas may promote NO absorption. The presence of O2 in simulated flue gas was disadvantage for NO x removal because it can oxidize sulfite to sulfate. It was worth pointing out that FeSO4/Na2SO4 was the best additive among those investigated additives, as the NO2 removal efficiency was significantly increased from 74.8 to 95.0 %. IC and in situ FTIR results suggest that the main products were NO3 ? and NO2 ? in liquid phase and N2O, N2O5 and HNO3 in gas phase during the CaSO3 absorption process. 相似文献
480.
一维纳米结构是最吸引人的功能材料而被广泛关注.一维形态可以很容易地提高纳米结构的独特性能,使它们适合各种各样的应用程序,包括气体传感器、电致变色的设备、发光二极管、场发射器、超级电容器和纳米发电机.因此,目前已合成多种一维纳米结构形式的纳米棒、纳米线、纳米管、纳米带等.本文主要介绍了一维碳纳米管与金属氧化物的性质与研究现状,探讨两种材料的优缺点以期进行互补修饰合成新型复合材料. 相似文献