NiB2O4 (B = Mn or Co) catalysts for NH3-SCR of NOx at low-temperature in microwave field

● Microwave-assisted catalytic NH₃-SCR reaction over spinel oxides is carried out. ● SCR reaction temperature is tremendously lowered in microwave field. ● NO conversion of NiMn₂O₄ is highly up to 90.6% at 70°C under microwave heating. Microwave-assisted selective catalytic reduction of nitrogen oxides (NO_x) was investigated over Ni-based metal oxides. The NiMn₂O₄ and NiCo₂O₄ catalysts were synthesized by the co-precipitation method and their activities were evaluated as potential candidate catalysts for low-temperature NH₃-SCR in a microwave field. The physicochemical properties and structures of the catalysts were characterized by X-ray diffraction (XRD), Scanning electron microscope (SEM), N₂-physisorption, NO adsorption-desorption in the microwave field, H₂-temperature programmed reduction (H₂-TPR) and NH₃-temperature programmed desorption (NH₃-TPD). The results verified that microwave radiation reduced the reaction temperature required for NH₃-SCR compared to conventional heating, which needed less energy. For the NiMn₂O₄ catalyst, the catalytic efficiency exceeded 90% at 70 °C and reached 96.8% at 110 °C in the microwave field. Meanwhile, the NiMn₂O₄ also exhibited excellent low-temperature NH₃-SCR reaction performance under conventional heating conditions, which is due to the high BET specific surface area, more suitable redox property, good NO adsorption-desorption in the microwave field and rich acidic sites.     

巴基斯坦恰希玛核电站安全壳整体密封性试验

介绍了巴基斯坦恰希玛核电站安全壳整体密封性试验的理论方法和试验系统及第一次换料停堆期间进行的整体密封性试验,并对结果进行试验分析。     

大型溞对水环境中抗生素抗性菌与抗性基因的摄食与去除

原后生动物是污水生物处理系统中的常见生物,了解它们是否能够摄食与去除抗生素抗性菌(ARB)和抗生素抗性基因(ARGs),对于建立藉捕食作用的ARB和ARGs去除技术具有重要意义.本研究以大型溞作为代表生物,探究了其对ARB和ARGs的摄食、去除效果与机制.使用荧光抗性菌直接观察其摄食过程,证实大型溞对ARB的摄食与富集...     

生物膜法A/O系统处理腈纶废水工业试验

本工业试验规模为１４００—１６００ｔ／ｄ,装置Ａ／Ｏ容积比１：３,当平均停留时间２２．６ｈ,回流比３．２,水温约３５℃左右时,平均去除率ＣＯＤｃｒ达８８．３６％、ＢＯＤ５９７．４９％、ＴＮ７７．６７％、ＡＮ９９．４１％。出水各项指标平均值为ＣＯＤＣｒ５３．５７ｍｇ／Ｌ、ＢＯＤ５５．６ｍｇ／Ｌ、ＴＮ１４．９４ｍｇ／Ｌ、ＮＨ３－Ｎ６．９２ｍｇ／Ｌ、ＡＮ１．０２ｍｇ／Ｌ、ＮａＳＣＮ２．６７ｍｇ／Ｌ,ＳＳ仅２０ｍｇ／Ｌ,因此不设二沉池。     

动床条件下泥石流运动参数变化特征实验研究∗

泥石流运动参数变化特征与泥石流流量、沟床纵坡和沟床物源物质组成等紧密相关,准确确定泥石流运动参数变化特征对于进行流域风险评估和防治工程规划设计具有重要意义。通过室内水槽实验探索了不同来流流量、 沟床纵坡和物源细粒含量条件下,沟槽观测点处泥石流流深、流速和容重的变化情况。结果表明：来流流量和沟床纵坡越大,物源细粒含量越小时,泥石流冲刷能力越强;相同实验条件下,流体流深与来流流量间呈正相关关系,与细粒含量间呈负相关关系,且流深受来流流量的影响大于细粒含量;流体流速与来流流量和沟床纵坡间呈正相关关系,与细粒含量间呈负相关关系,且流速受沟床纵坡的影响最大,受细粒含量的影响最小;流体容重与来流流量和细粒含量间呈负相关关系,与沟床纵坡间呈正相关关系,且容重受沟床纵坡和细粒含量的影响大于来流流量。 通过水槽实验数据对泥石流流量进行拟合,采用流量拟合式对锅圈岩沟 2013 年“7·26”泥石流峰值流量进行计算, 与野外实测值对比精度高于 80%。     

Selection and characterization of eight freshwater green algae strains for synchronous water purification and lipid production

The objective of this study is to select and characterize the candidate for synchronous water purification and lipid production from eight freshwater microalgae strains (Chlorella sp. HQ, C. emersonii, C. pyrenoidosa, C. vulgaris, Scenedesmus dimorphus, S. quadricauda, S. obiquus, Scenedesmus sp. LX1). The strains Chlorella sp. HQ, C. pyrenoidesa, and S. obliquus showed superiority in biomass accumulation, while the top biomass producers did not correspond to the top lipid producers. S. quadricauda achieved higher lipid content (66.1%), and Chlorella sp. HQ and S. dimorphus ranked down in sequence, with lipid content above 30%. Considering nutrient removal ability (total nitrogen (TN): 52.97%; total phosphorus (TP): 84.81%), the newly isolated microalga Chlorella sp. HQ was the possible candidate for water purification coupled with lipid production. To further investigate the lipid producing and nutrient removal mechanism of candidate microalga, the ultra structural changes especially the lipid droplets under different water qualities (different TN and TP concentrations) were characterized. The results elucidate the nutrient-deficiency (TN: 3.0 mg·L^–1; TP: 0.3 mg·L^–1) condition was in favor of forming lipid bodies in Chlorella sp. HQ at the subcellular level, while the biomass production was inhibited due to the decrease in chloroplast number which could further suppress the nutrient removal effect. Finally, a twophase cultivation process (a nutrient replete phase to produce biomass followed by a nutrient deplete phase to enhance lipid content) was conducted in a photo-bioreactor for Chlorella sp. HQ to serve for algae-based synchronous biodiesel production and wastewater purification.     

Effective degradation of tetracycline by mesoporous Bi<Subscript>2</Subscript>WO<Subscript>6</Subscript> under visible light irradiation

Bi₂WO₆ was synthesized with a hydrothermal method at different pHs and used for the degradation of tetracycline (TC) in water. The mesoporous Bi₂WO₆ prepared at pH 1 (BWO-1) displayed the highest adsorption and degradation capacity to TC due to its large surface area and more efficient capacity to separate photogenerated electrons and holes. 97% of TC at 20 mg·L^?1 was removed by BWO-1 at 0.5 g·L^?1 after 120 min irradiation under simulated solar light. Only 31% of the total organic carbon (TOC) was removed after 360 min irradiation although the TC removal reached 100%, suggesting that TC was mainly transformed to intermediate products rather than completely mineralized. The intermediates were identified by high-performance liquid chromatography-time of flight-mass spectrometry (HPLC-TOF-MS) and possible photodegradation pathways were proposed.     

长江上游地区土壤可蚀性空间分异特征

研究土壤可蚀性K值有助于宏观判断和定量分析长江上游地区土壤侵蚀的空间分布特征。利用第二次土壤普查资料建立了长江上游土壤的理化性质数据库,通过三次样条插值对土壤质地进行转换,采用EPIC模型计算出各土种的可蚀性K值,采用面积加权的方法,求得各亚类的可蚀性K值,将其链接至长江上游土壤图的属性表,得到土壤可蚀性空间分布图,进而探讨土壤可蚀性的分布特征。结果表明：长江上游土壤可蚀性以较低可蚀性、中等可蚀性和较高可蚀性为主,横断山区、云贵高原和三峡库区区域土壤可蚀性明显高于四川盆地地区;高可蚀性土壤主要分布在嘉陵江上游和横断山区的低海拔谷地;平均K值为0239 0,最大值041,最小值007土壤可蚀性高低与土壤侵蚀强度、海拔高度和坡度在空间分布上具有一定的规律性     

经验正交函数方法和TRMM数据对长江流域降水模式与极端水文过程的研究

气候变化加剧了极端天气和水文事件的发生,降水是区域干旱与洪水事件最直接驱动因素。以TRMM/PR月累积降水反演遥感数据为基础,利用经验正交函数EOF（Empirical Orthogonal Function）方法对长江流域降水时空变化模式进行提取,并对比分析了主要模式振幅强弱与极端水文事件的对应关系。结果表明在流域尺度上EOF方法及TRMM/PR数据可以较好地识别降水主要模式,通过时空尺度变换成功揭示主要降水模式强弱与流域极端水文事件的对应关系。鉴于日益丰富的巨量水文气象时空数据,EOF方法在模式提取、水文模拟、极端事件预估及灾害适应性研究等方面具有应用潜力     

An analytical solution to contaminant diffusion in semi-infinite clayey soils with piecewise linear adsorption

The adsorption of contaminants onto soil particles typically is nonlinear if the contaminant concentration is sufficiently high. A simplified piecewise linear adsorption isotherm consistent with experimental results is proposed as an approximation for nonlinear adsorption behavior. This approximation allows for the use of analytical solution to model solute diffusion of contaminants that exhibit nonlinear adsorption. A moving boundary is introduced to represent significant changes in the retardation factor of clay with an increase in solute concentration. The proposed analytical solutions were validated using experimental data presented in the literature. There is negligible difference between the results obtained by the proposed analytical solution and those obtained by the linear model when C_m/C₀ reached 0.5. The results also show that the model based on linear adsorption using the initial secant of the Freundlich isotherm leads to significantly lower estimated breakthrough time for the contaminant of interest than that obtained using the proposed model. The earlier breakthrough is due to an under-estimation of the amount of adsorption. The proposed method is relatively simple to apply and can be used for evaluating experimental results and verifying more complex numerical models.