Adsorption of zinc on manganite(γ-MnOOH): particle concentration effect and adsorption reversibility

The adsorption and desorption processes of Zn(Ⅱ) on τ-MnOOH as a function of particle concentrations (Cp) were studied. An obvious Cp effect was observed in this adsorption system. The degree of adsorption hysteresis increased greatly with the increasing of Cp, indicating that the extent of the real metastable-equilibrium states deviating from the ideal equilibrium state was enhanced with the increasing of Cp. The Cp-reversibility relationship confirmed the metastable-equilibrium adsorption (MEA) inequality (Pan, 1998a), which was the core formulation of the MEA theory. Because the MEA inequality was based on the basic hypothesis of MEA theory that adsorption densitιy ι is not a state variable, the Cp-reversibility relationship gave indirect evidence to the basic hypothesis of MEA theory.     

珍贵油料植物诸葛菜的研究

四川大学植物遗传研究室经过几年的调查研究,发现诸葛菜的农艺性状较好,分枝多、角果多,每果子粒多,千粒重较重,含油量较高,特别是油分品质优异,其营养价值高的脂肪酸如油酸和亚油酸的含量较高,分别为20.32％,和53.17％,其营养价值低的脂肪酸如亚麻酸和芥酸的含量较低,分别为4.76％和0.94％,是油菜优质育种的优异新种源,可以作为油菜远缘杂交育种亲本,并可能选育出优质油料新作物。本文对诸葛菜的开花授粉习性作了观察,对核型特点作了分析,可供育种工作的参考,诸葛菜主产中国。四川大学在国内外首先推荐这种有希望的油料新种源。     

Controlled-release fertilizer(CRF):A green fertilizer for controlling non-point contamination in agriculture

Fertilizers contribute greatly to high yields but also result in environmental non-point contamination, including the emission of greenhouse gas(N2O) and eutrophication of water bodies. How to solve this problem has become a serious challenge, especially for China as its high ecological pressure. Controlled-release fertilizer(CRF) has been developed to minimize the contamination while keeping high yield and has become a green fertilizer for agriculture. Several CRFs made with special coating technology were used for testing the fertilizer effects in yield and environment through pot experiment and field trial. The result indicated that the CRFs had higher N use efficiency, thus reducing N loss through leaching and volatilization while keeping higher yields. Comparing with imported standard CRFs,the test on CRFs showed similar fertilizer effect but with much lower cost. CRFs application is becoming a new approach for minimizing non-point contamination in agriculture.     

320米塔上测量的湍流统计特征量的初步分析

应用320米塔上第一次获得的垂直风速脉动量的垂直分布资料,根据湍流扩散统计理论并结合半经验近似,讨论由欧拉参数估算边界层下层扩散参数的主要方法,得到了湍流统计特征量K_(?)、σ_w及ε随高度和稳定度变化的经验关系,为北京地区大气扩散规律研究及污染模式的建立提供实验基础.     

土壤中的铅对三种蔬菜的影响

通过温室栽培萝卜、青菜和莴苣,研究土壤中的铅对蔬菜生长的影响及其在器官中的残留。在低浓度下,铅对蔬菜生长有不同程度的刺激作用。土壤有效态铅浓度与蔬菜各器官含铅浓度存在显著性正相关(P<0.05)。不同蔬菜对铅的敏感性、耐受力不同。     

吉林延吉八道金矿构造控矿模式

八道金矿为延吉中生代火山岩型金矿中较为典型的矿床之一。其矿床成因，除与火山作用有关之外直接受构造的控制，而火山作用本身又与区域深大断裂有关。本文着重讨论了矿区火山岩与朝阳河断裂的关系及构造控矿模式。     

中国黄土元素背景值分异规律研究

报道了中国黄土中40个元素的背景值,并以F、Cr、Mn、Co、Ni、V、Cu、Zn、As、Se、Cd、Pb、Hg等13个元素为例,讨论了其在黄土高原的分布与含量。利用趋势面分析等数理统计方法,揭示了黄土中元素的某些环境地球化学特征及元素背景值的分异规律。结果表明,黄土的元素背景值具有三维的分异特征,黄土的质地及沉积的生物气候环境黄土是影响背景值分异的主要因素。为中国黄土的风成学说提供了佐证。     

Determination of arsenic in grain and soil by hydride nondispersive atomic fluorescence method

Quantity of trace arsenic in grain and soil was determined by hydride nondispersive atomic fluorescence method.Optimum conditions of measurement were selected in the experiment including the pH of the medium, reductive agent, the concentration and flowing velocity of KBH4, rate of carrier gas and atomized temperature. The reference sample of rice C was determined and the linear relationship of the calibration curve was plotted, indicating that the method was highly precise. In the experiment of recovery rate, the method was quite satisfactory.Based on the determination of hundreds of samples, it is proved that atomic fluorescence method is rapid, sensitive and low in interference. It is very efficient on determination of trace arsenic in soils and grains, especially in grains.     

连续化学浸提法测定底泥中不同形态汞的探讨

本文提出用连续化学浸提法将底泥作连续五次抽提,根据不同形态汞的溶解度,将底泥中汞分为水溶性汞、酸溶性汞、碱溶性汞、硝酸溶汞、王水溶汞五个部分。对蓟运河沿岸的天化、茶淀和污水库底泥中汞作上述化学形态分析。用合成样品验证求回收率,认为对底泥中惰性汞的测定较热解法可靠,并发现底泥中腐殖质汞与惰性汞之间有相关关系。     

国产防锈水对威斯塔大鼠致癌性研究

对使用国产防锈水(主要成分为亚硝酸钠和三乙醇胺)的一个工厂进行肿瘤流行病学调查,发现该厂人员恶性肿瘤发病率略有增加。经长期给大白鼠饮用防锈水实验证明,该法可导致大鼠胰腺腺泡增生和不典型增生并能诱发出对照动物所没有的胰腺癌,同时还可引起胃粘膜的增生和胃乳头状瘤。