Cellulose acetate biodegradability upon exposure to simulated aerobic composting and anaerobic bioreactor environments

Cellulose acetate (CA) films with degree of substitution (d.s.) values of 1.7 and 2.5 were exposed to biologically active in-laboratory composting test vessels maintained at approximately 53 °C. The CA 1.7- and 2.5-d.s. films (thickness values of 0.5–1.0 and 2.0 mil, respectively) had completely disappeared by the end of 7- and 18-day exposure time periods in the biologically active bioreactors, respectively. The relatively small CA film weight loss observed in the poisoned control test vessels allows the conclusion that CA film erosion during the composting exposures resulted, at least in part, from biologically mediated processes. Under strictly anaerobic conditions, an active methanogenic inoculum was developed by acclimation of a sewage sludge to a synthetic municipal solid waste (SMSW) mixture at 42°C. The CA 1.7-d.s. film samples (0.5- to 1.0-mil thickness) were exposed in anaerobic serum bottles containing a 25% solids loading of SMSW in which methanogenic activity was rapidly established after introducing of the developed inoculum. For exposures of 30 days only small visually distinguishable fragments of the CA 1.7-d.s. films were recovered. In contrast, exposure of the CA 1.7-d.s. film to a poisoned control test vessel resulted in negligible weight loss. Therefore, degradation of the CA 1.7-d.s. films upon exposure to the anaerobic bioreactors was due, at least in part, to biologically mediated processes.Guest Editor: Dr. Graham Swift, Rohm & Haas.     

一体化平板膜装置回收靛蓝染料的小试研究

文章采用自主研发的一体化平板膜靛蓝回收装置对印染废水进行了小试研究。此工艺采用投加H2O2氧化染液的方式析出靛蓝结晶并采用平板膜处理的方式不断浓缩靛蓝并将浓缩液回用于染色工段,保证了染料回用的效果。对装置中预处理单元,氧化单元,膜过滤单元等主．要参数进行了优化。研究结果表明．该装置氧化单元H2O2最佳投加量为15ml／L,最佳氧化pH=3;最佳过膜条件pH=4,连续曝气,开停比4：3;膜清洗采用水力冲洗后NaC10浸泡2h的方法,通量恢复近100％。在该最佳工况下,装置不仅能够高效回收靛蓝染料,回收效率达到99．5％,同时废水水质得到极大改善,SS平均去除93．9％,浊度下降100％,色度下降98．4％。     

铁岭市城市交通噪声测点优化的研究

通过在48条交通路段进行布点监测,监测数据采用模糊聚类分析的方法,优化出切合实际的铁岭市城市交通噪声的测点.     

粉煤灰基质滤料处理含锰废水的研究

通过静态吸附试验研究了粉煤灰基质滤料对废水中Mn2+的吸附性能,主要探讨了滤料投加量、吸附时间、原水浓度、振荡频率等因素对吸附效果的影响。结果表明:随着投加量增加,Mn2+去除率提高,单位吸附量线性下降;随着吸附时间延长,Mn2+去除率提高,超过80 min后提高幅度变缓,吸附过程符合二级动力学模型;振荡频率的增大对吸附有一定的促进作用,但超过200 r/min后提高不明显。     

试论海南省周边海岛开发利用存在的问题和对策

海南省周边海岛资源丰富,开发前景广阔,但海岛生态系统也极其脆弱,抵抗外来的干扰能力很差,一旦破坏很难恢复。同样海岛开发也面临诸多问题,主要包括海岛管理、海岛生态环境、海岛开发利用、海岛自然灾害和国防安全五个方面问题。本文通过对海南省海岛的利用现状、存在的问题进行综合分析,最后提出了海岛开发对策,为保护和合理开发利用海岛资源,促进海洋经济强省建设,助推海南省国际旅游岛建设都具有非常积极意义。     

基于模糊综合评价法的城市生态环境质量综合评价——以大连市为例

论文针对城市快速发展过程中的生态环境问题,在查阅大量国内外相关文献,结合实地调研的基础上,对城市生态环境现状和问题进行了分析。运用可持续发展理论和生态经济学原理,从白然、社会、经济的角度,选取了20个单项指标,构建了大连生态环境质量评价指标体系,采用专家打分法、层次分析法和模糊综合评判法构建出城市生态环境质量评价的模型。并对大连市的生态环境质量进行了实证研究,定量地对大连的生态环境进行了综合评价。通过MapInfo软件生成大连市生态环境质量空间分布图。结论为全市生态环境质量总体保持优良,中心城区、长海县生态环境质量为优,金州区、旅顺口区、瓦房店市、庄河市为良,普兰店市为中。     

土壤及固体废弃物中有机磷农药残留分析方法研究

有机磷农药是继有机氯农药以后被广泛应用的一类农药,它对生物体具有一定毒性,因此对有机磷农药的充分提取及检测就密切关系到人们的饮食安全。传统提取底质中有机磷的方法为索式提取或者采用有机溶剂对土壤直接萃取,而本文采用亲水溶剂对土壤进行萃取,并通过固相萃取技术对其进一步纯化,气相色谱-质谱法检测,对多种有机磷农药的分离度较好。     

人工湿地污水处理系统中氧化亚氮的释放规律研究

利用静态箱-气相色谱法研究了潜流和表面流人工湿地系统中N2O的释放规律和相关的氨氧化细菌.结果表明,潜流和表面流人工湿地的N2O平均通量分别为296.5μg.(m2.h)-1和28.2μg.(m2.h)-1,总体上均表现为大气N2O的排放源,前者的N2O平均释放通量高于农田、森林、草原和沼泽湿地等生态系统,潜流方式促进了N2O的释放.潜流和表面流人工湿地N2O通量有较大的月份差异和明显的日变化特征,最高值出现在7月,分别为(762.9±239.3)μg.(m2.h)-1和(91.9±20.3)μg.(m2.h)-1,一天中的极大值和极小值分别出现在中午和凌晨.温度和芦苇的生长情况对N2O通量有一定的影响.人工湿地系统进水端,较高浓度的污水和充足的碳、氮源,促进了硝化和反硝化过程,使得N2O通量均高于出水端.克隆结果表明,人工湿地污水处理系统中与N2O产生相关的氨氧化细菌主要为Nitrosomonas和Nitrosospira.     

汶川Ms8．0地震地质灾害发育特征及诱发因素分析——以北川县为例

地面破坏效应强烈和地震地质灾害严重是汶川Ms8．0地震震害效应的显著特点。地震地质灾害的分布与地震断层的分布密切相关,同时还受自然地理、地层岩性、地质构造和人类活动的影响和控制。论文结合北川县场地条件的分析,对汶川Ms8．0地震中北川县地震地质灾害的发育特征、形成条件及诱发因素进行了系统总结。地震地质灾害分布与地震断层的关系表明地震对次生地质灾害起到了主要的控制与触发作用。     

Total pollution effect of urban surface runoff

For pollution research with regard to urban surface runo , most sampling strategies to date have focused on di erences in land usage. With single land-use sampling, total surface runo pollution e ect cannot be evaluated unless every land usage spot is monitored. Through a new sampling strategy known as mixed stormwater sampling for a street community at discharge outlet adjacent to river, this study assessed the total urban surface runo pollution e ect caused by a variety of land uses and the pollutants washed o from the rain pipe system in the Futian River watershed in Shenzhen City of China. The water quality monitoring indices were COD (chemical oxygen demand), TSS (total suspend solid), TP (total phosphorus), TN (total nitrogen) and BOD (biochemical oxygen demand). The sums of total pollution loads discharged into the river for the four indices of COD, TSS, TN, and TP over all seven rainfall events were very di erent. The mathematical model for simulating total pollution loads was established from discharge outlet mixed stormwater sampling of total pollution loads on the basis of four parameters: rainfall intensity, total land area, impervious land area, and pervious land area. In order to treat surface runo pollution, the values of MFF30 (mass first flush ratio) and FF30 (first 30% of runo volume) can be considered as split-flow control criteria to obtain more e ective and economical design of structural BMPs (best management practices) facilities.