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161.
Godderis L Vanderheyden W Van Geel J Moens G Masschelein R Veulemans H 《Journal of environmental monitoring : JEM》2005,7(12):1359-1363
To date the exposure, absorption and respiratory health effects of cast-house workers have not been described since most studies performed in the aluminium industry are focused on exposure and health effects of potroom personnel. In the present study, we assessed the external exposure and the absorbed dose of metals in personnel from the aluminium cast house. This was combined with an evaluation of respiratory complaints and the lung function of the personnel. 30 workers from an aluminium casting plant participated and 17 individuals of the packaging and distribution departments were selected as controls. The exposure was assessed by the quantification of total inhalable fume with metal fraction and by the determination of urinary aluminium, chromium, beryllium, manganese and lead concentration. Carbon monoxide (CO), carbon dioxide (CO2), aldehydes and polyaromatic hydrocarbons and man-made mineral fibres concentration were assessed as well. In order to evaluate their respiratory status each participant filled out a questionnaire and their lung function was tested by forced spirometry. Total inhalable fume exposure was maximum 4.37 mg m(-3). Exposure to the combustion gases, man-made mineral fibres and metal fume was well below the exposure limits. Beryllium could not be detected in the urine. The values of aluminium, manganese and lead in the urine were all under the respective reference value. One individual had a urinary chromium excretion above the ACGIH defined biological exposure index (BEI) of 30 microg g(-1) creatinine. There was no significant difference in any of the categories of the respiratory questionnaire and in the results of the spirometry between cast house personnel and referents (Chi-square, all p > 0.05). Exposure in cast houses seem to be acceptable under these conditions. However, peak exposure to fumes cannot be excluded and the potential risk of chromium and beryllium exposure due to the recycling of aluminium requires further attention. 相似文献
162.
163.
A ten year summary of concurrent ambient water column and sediment toxicity tests in the Chesapeake Bay watershed: 1990-1999 总被引:1,自引:0,他引:1
The goal of this study was to identify the relative toxicity ofambient areas in the Chesapeake Bay watershed by using a suiteof concurrent water column and sediment toxicity tests at seventy-five ambient stations in 20 Chesapeake Bay rivers from1990 through 1999. Spatial and temporal variability was examinedat selected locations throughout the 10 yr study. Inorganicand organic contaminants were evaluated in ambient water andsediment concurrently with water column and sediment tests toassess possible causes of toxicity although absolute causalitycan not be established. Multivariate statistical analysis wasused to develop a multiple endpoint toxicity index (TOX-INDEX) at each station for both water column and sediment toxicity data. Water column tests from the 10 yr testing period showed that49% of the time, some degree of toxicity was reported. The mosttoxic sites based on water column results were located inurbanized areas such as the Anacostia River, Elizabeth River andthe Middle River. Water quality criteria for copper, lead,mercury, nickel and zinc were exceeded at one or more of thesesites. Water column toxicity was also reported in localizedareas of the South and Chester Rivers. Both spatial and temporalvariability was reported from the suite of water column toxicitytests. Some degree of sediment toxicity was reported from 62% of the tests conducted during the ten year period. The ElizabethRiver and Baltimore Harbor stations were reported as the most toxic areas based on sediment results.Sediment toxicity guidelines were exceeded for one or more of thefollowing metals at these two locations: arsenic, cadmium,chromium, copper, lead, nickel and zinc. At the Elizabeth Riverstations nine of sixteen semi-volatile organics and two of sevenpesticides measured exceeded the ER-M values in 1990. Ambientsediment toxicity tests in the Elizabeth River in 1996 showedreduced toxicity. Various semi-volatile organics exceeded the ER-M values at a number of Baltimore Harbor sites; pyrene anddibenzo(a,h)anthracene were particularly high at one of thestations (Northwest Harbor). Localized sediment toxicity was alsoreported in the Chester, James, Magothy, Rappahannock, andPotomac Rivers but the link with contaminants was not determined.Both spatial and temporal variability was less for sedimenttoxicity data when compared with water column toxicity data. Acomparison of water column and sediment toxicity data for thevarious stations over the 10 yr study showed that approximatelyhalf the time agreement occurred (either both suite of testsshowed toxicity or neither suite of tests showed toxicity). 相似文献
164.
Magnuson ML Kelty CA Urbansky ET Owens JH Kelty KC Speth TF 《Journal of environmental monitoring : JEM》2002,4(1):102-108
Analytical chemistry is an important tier of environmental protection and has been traditionally linked to compliance and/or exposure monitoring activities for environmental contaminants. The adoption of the risk management paradigm has led to special challenges for analytical chemistry applied to environmental risk analysis. Namely, methods developed for regulated contaminants may not be appropriate and/or applicable to risk management scenarios. This paper contains examples of analytical chemistry applied to risk management challenges broken down by the analytical approach and analyte for some selected work in our laboratory. Specific techniques discussed include stable association complex electrospray mass spectrometry (cESI-MS), gas chromatography-mass spectrometry (GC-MS), split-flow thin cell (SPLITT) fractionation and matrix-assisted laser desorption time of flight mass spectrometry (MALDI-ToF-MS). Specific analytes include haloacetic acids (HAA9), perchlorate, bromate, triazine degradation products, metal-contaminated colloids and Cryptosporidium parvum oocysts. 相似文献
165.
B. Beck-Friis M. Pell U. Sonesson H. Jönsson H. Kirchmann 《Environmental monitoring and assessment》2000,62(3):317-331
Composting can be a source of N2O andCH4 production. In this investigation, differentcompost heaps of organic household waste weremonitored with the focus on potential formation ofCH4 and N2O in the heaps and emission ofthese gases from the heaps. The studied compost heapshad different compost ages, turning intervals andcompost sizes. The analysed compost gases containedbetween 1–3421 L of N2O-N L-1 and 0–470 mL of CH4 L-1. The emission rates ofN2O and CH4 from the compost heaps werebetween 1–1464 mg N2O m-2 day-1 and0–119 000 mg CH4 m-2 day-1. These verylarge differences in compost gas composition andemission indicate the importance of compostmanagement. The results also give an understanding ofwhere in the composting process an increasing emissionof N2O and CH4 can occur. 相似文献
166.
This paper discusses the REAP1 model and its application for the analysis of CO2 reduction and waste management policies for Japanese petrochemicals. The pros and cons of this modelling approach in comparison to other tools is elaborated. This is followed by a discussion of the model code and the modelling results. The results show that CO2 policies can have significant impacts on waste flows and waste policies can have significant CO2 benefits. As a consequence both effects must be considered in policy assessment. Pricing instruments are recommended instead of regulations because of the complex physical relations in the materials life cycle that extend beyond sector boundaries. A taxation approach is superior to a subsidy approach because rebound effects can be avoided. 相似文献
167.
Luyssaert S Raitio H Mertens J Vervaeke P Lust N 《Journal of environmental monitoring : JEM》2002,4(3):408-412
Foliar analysis is a valuable tool for evaluating the pollution status of forests. However, the use of foliar diagnosis in large-scale surveys is a complicated process owing to the high variability within the crown. The method used to express foliar concentrations has often been found to diminish the variability. The effect of the method used to express element concentrations on the spatial variability of cadmium (Cd) in the leaves of crack willow (Salix fragilis L.) was investigated by sampling the leaves of one willow at 292 locations in the crown, each sampling location having a volume of 0.027 m3 (0.3 m x 0.3 m x 0.3 m). Cadmium showed a distinct spatial trend in the crown of the tree. Concentrations as low as 2.4 mg kg(-1) dry weight (DW) or 23.1 mg kg(-1) dry ash weight (DAW) were obtained in the top of the crown, and 10.6 mg kg(-1) DW or 73.0 mg kg(-1) DAW in the bottom of the crown. The lower relative standard deviation and weaker correlation with the sampling height support the use of DAW in large-scale surveys especially. The lower variability of the DAW Cd concentration makes this variable less sensitive to fluctuations caused by differences in growing conditions and sampling methodology. However, the majority of publications in this field report metal concentrations on a DW basis. Therefore, the restrictions set on the use of results expressed on a DAW basis in large-scale surveys of foliar metal concentrations have to be offset against the advantages offered by a reduction of the variability in metal concentrations. 相似文献
168.
A. M. Cicero M. Mecozzi R. Morlino D. Pellegrini E. Veschetti 《Environmental monitoring and assessment》2001,71(3):297-316
Dredging is a very important procedure for harbor management. InItaly the guidelines for the offshore dumping of dredged materials are issued by the Ministry of Environment. Theydescribed a few steps of dredging activities, such as thesampling strategy, but do not deal with limits or guide-valuesfor the chemical, physical and biological composition of theresulting sediments. The quality of dredged materials is mainlydependent on the presence of inorganic and organic pollutants.In particular, polychlorinated biphenyls (PCBs) and organo-chlorinated pesticides are seen as a high priority inmarine environment by international organizations because oftheir persistence, toxicity and bioaccumulation capacity.In this article the presence of some PCBs and organo-chlorinatedpesticides in sediment samples collected from the harbor ofLivorno (Northern Tyrrhenian Sea) was investigated. Theconcentration of HCHs, Aldrin, Chlordanes, DDEs, DDTs, and PCBsin 12 representative sites ranged between <1 g kg–1and 95, 19, 32, 35, 107, and 111 g kg–1, respectively.The application of univariate and multivariate statisticaltechniques, such as linear regression analysis and principalcomponent analysis, to the experimental data showed a differentdistribution of PCBs in the two sediment layers. On thecontrary, the vertical distribution of the other investigatedpollutants was more homogeneous and affected by randomvariability. The multivariate approach was an important tool to establish more rational criteria for the management of dredged materials. 相似文献
169.
The article describes the use of Scots pine bark to identifynitrogen sources in eastern Germany, as well as background areas in Russia and Bulgaria, by using natural isotope ratios of total nitrogen (Nt) and individual N compoundssuch as ammonium (NH4
+), nitrate (NO3
-)and amid nitrogen (amide-N). The samples collected were analysed using an elemental analyser in connection with a gas isotope mass spectrometer (EA-IRMS). Natural 15N abundances in pine bark from impact areas suggest that the ammonium accumulated on the surface of the bark is releasedfrom livestock management. Bark of Scots pines growing near agricultural land had highly depleted 15Nt values (between –8 and –12), while bark from background areas (unpolluted areas) displayed slightly negative 15Nt values (mean 15Nt = –3.8). It is assumed that part of the N adsorbed on the bark surface is mainly derived from ammonia(mean 15Nt = –40.3) escaping from livestock housing and during the application of manure. This assumption is confirmed by experiments under controlled conditions in which manure samples were spread on soil. In addition, temporal and spatial variations of 15Nt abundances in pine bark from various locations in eastern Germany as wellas pine stands in Nature Park Dübener Heath are discussed. 相似文献
170.
Fagundez LA Fernández VL Marino TH Martín I Persano DA Rivarola Y Benítez M Sadañiowski IV Codnia J Zalts A 《Environmental monitoring and assessment》2001,71(1):61-70
Passive diffusion samplers were employed in San Miguel(Buenos Aires Metropolitan Area) for a preliminary airpollution monitoring. The highest loads were observedin downtown, compared with an urban background site.Total suspended particulate matter (TSPM) varied from0.257 to 0.033 mg cm-2 month-1; dust was examinedfor particle nature and size distribution. A similartrend was observed for nitrogen dioxide (NO2) andTSPM spatial distribution, suggesting that traffic isthe major pollution source. Sulphur dioxide (SO2)values were low and rather homogeneous. Levels for theinvestigated pollutants are below EPA's guide linevalues. Geographic (flat area, near to Rio de LaPlata) and climatologic factors (rainfalls andvariable wind directions) contribute to disperse pollutants. 相似文献