树脂固载纳米铁对偶氮染料直接湖蓝5B的脱色性能研究

以FeSO4和NaBH4水溶液为前驱溶剂,以聚苯乙烯型阳离子交换树脂为载体,制备了树脂固载的纳米铁,室温下用于对偶氮染料直接湖蓝5B水溶液进行脱色研究。研究结果发现,脱色反应遵循准一级反应动力学,在初始pH为3~10的范围内,反应进行14 m in时,50 mg/L的染料溶液脱色率均能达到83%以上。固载的纳米铁材料可多次重复利用,溶液中释放的铁离子浓度不超过0.1 mg/L。     

活性炭吸附和脱附-等离子体氧化净化有机废气的研究

根据滑动弧放电等离子体适于降解高浓度有机物废气的特性,结合活性炭吸附法,提出了吸附器的吸附浓缩和热脱附-等离子体氧化净化有机废气的方法。在活性炭吸附过程中,最初2 h内甲苯净化率达到100%,随着时间的增加净化率下降;在热脱附滑动弧放电等离子体净化过程中,甲苯降解效率最高为97.3%。将滑动弧放电等离子体反应器出口气相产物收集进行FT-IR检测,发现放电后有CO2、CO、H2O和NO2产生,并分析了甲苯的降解机理。     

我国城市居民健康状况及影响因素研究

随着中国城市化、工业化快速推进,城市居民的健康日益受到环境、外部压力等因素的影响,加上生活方式和健康观念方面的原因,城市居民健康状况的改善缓慢.利用2006年中国健康与营养调查(CHNS)截面数据,描述了我国城市居民的健康及其分布状况,利用Ordered Probit模型分析了影响城市居民的健康状况的各类因素.结果发现:家庭状况、生活习惯、就医决策、医疗保险等因素均影响城市居民的健康水平;尤其是在收入、工作等经济因素之外,健康观念、就医决策和保险覆盖等社会和制度因素亦对城市居民个人健康产生影响.同时,通过逐步回归控制相关变量的方法,检验了Grossman模型的适用性,同时也检验了影响因素作用机制的稳定性.在总结研究结论与不足的基础上,提出了应从经济,社会和制度三个层面全面促进城市居民健康的综合改革框架.     

Fe_2O_3/膨润土微波诱导氧化处理染料废水

以膨润土为载体,采用直接沉淀法制备了Fe2O3/膨润土负载型催化剂。制备催化剂的最佳工艺条件:硝酸铁质量浓度为8.08g/L,硝酸铁与膨润土质量比为1.0,焙烧温度为350℃,焙烧时间为3h。用Fe2O3/膨润土负载型催化剂微波诱导氧化处理50mL质量浓度为50mg/L的模拟活性嫩黄废水的最佳工艺条件:催化剂加入量为0.5g,微波功率为900W,微波作用时间为5min。在此条件下模拟活性嫩黄废水脱色率达96.40%。微波诱导氧化处理模拟活性嫩黄废水的反应符合一级反应动力学方程。     

长江三角洲生产性服务业的空间分布特征分析

在国家层面,生产性服务业向大都市地区聚集的趋势十分明显;在地区层面,生产性服务业在都市核心区集群化发展日益凸显。长三角地区生产性服务业发展不平衡,总体上初步形成了以上海生产性服务业与其他城市现代制造业相互促进的发展局面,产业之间的联系更加紧密,横向联系日益加强,推动着长三角地区产业竞争力和区域竞争力的提升。     

浅谈阿克苏地区工业污染源排放现状及环境管理工作中存在的问题和对策

根据阿克苏地区工业污染源排放现状及特点,分析了阿克苏地区环境监督管理工作中存在的问题,从提高环境监管力度、"三同时"制度管理水平、在线监控能力、优化产业结构等方面提出了相应的对策和建议。     

Organochlorine pesticides and PCBs in fish from lakes of the Tibetan Plateau and the implications

High mountains may play significant roles in the global transport of persistent organic pollutants (POPs). This work aims to investigate the levels, patterns and distribution of semi-volatile organoclorine pollutants and to improve the understanding of the long-range atmospheric transport and fate of contaminants on the Tibetan Plateau. A total of 60 fish samples were collected from eight lakes located between 2813 and 4718 m above sea level across the Plateau. Concentrations of polychlorinated biphenyls (PCBs), organochlorine pesticides (OCPs) including dichlorodiphenyltrichloroethane and its metabolites (DDTs), hexachlorocyclohexanes (HCHs) and hexachlorobenzene (HCB) were measured in fish muscle. The results showed that concentrations of DDT, HCH and HCB were comparable to or lower than those found in remote mountains of Europe, Canada and US, while PCB concentrations in fish were, on average, about 4-150 times lower on Tibet than at other mountain areas. The transport and fate of contaminants in the Plateau are significantly influenced by the unique climatological and meteorological conditions, particularly by the summer Indian monsoon and winter westerly jet stream.     

Bio-immobilization of Cu and Zn in recirculated bioreactor landfill

Purpose  

To protect the environmental quality of soil, groundwater, and surface water near the landfill site, it is necessary to make an accurate assessment of the heavy metal mobility. This study aims to present the bio-immobilization behavior of heavy metals in landfill and provide some reference suggestion for the manipulation of heavy metal pollution control after closure.     

Enantioselectivity in environmental risk assessment of modern chiral pesticides

Chiral pesticides comprise a new and important class of environmental pollutants nowadays. With the development of industry, more and more chiral pesticides will be introduced into the market. But their enantioselective ecotoxicology is not clear. Currently used synthetic pyrethroids, organophosphates, acylanilides, phenoxypropanoic acids and imidazolinones often behave enantioselectively in agriculture use and they always pose unpredictable enantioselective ecological risks on non-target organisms or human. It is necessary to explore the enantioselective toxicology and ecological fate of these chiral pesticides in environmental risk assessment. The enantioselective toxicology and the fate of these currently widely used pesticides have been discussed in this review article.     

Formation of shaped barium sulfate-dye hybrids: waste dye utilization for eco-friendly treatment of wastewater

Purpose

Owing to the present complexity and difficulty of concentrated dye wastewater treatment, this work aimed to synthesize a reproducible waste-sorbing material for the treatment of wastewater by forming the dye-conjugating complex hybrid.

Methods

The inorganic/organic hybridization was applied to prepare the objective material by immobilizing waster dye-Mordant blue 9 (MB) with barium sulfate (BaSO₄). The composition and pattern of the formed material were determined by spectrometry and characterized by SEM and XRD, and their formation process was clarified. The adsorption of cationic dye-basic blue BO (BB) and copper ion was investigated..

Results

The hybrid of MB alone into growing BaSO₄ formed the pineapple-like particles while that of the MB/BB-conjugating complex was the rhombus material. The adsorption of BB on the MB–BaSO₄ hybrid was probably attributed to ion-pair equilibrium and that of Cu²⁺ may result from the complexation. The treatment of dye and heavy metal wastewaters indicated that the MB hybrid material removed 99.8% BB and 97% Cu²⁺ and the dye-conjugating hybrid with growing BaSO₄ 100% MB, 99.5% BB, and 44% Cu²⁺.

Conclusion

The waste MB–BaSO₄ hybrid material is efficient to treat cationic dye and Cu²⁺ wastewater. The dye-conjugating hybridization method is the first to be advanced for in situ wastewater treatment, and it showed a combined effect for the removal of both organic dyes and heavy metals.