旧路改造工程路堤稳定性安全监测方案设计

本文从旧路改造工程的特点出发,通过室内实验获取土力学参数并对沉降量进行预测计算.利用沉降仪、测斜管、孔隙水压力计、土压力盒等多种测试仪器,选取有代表性的观测断面,对经过土工格栅加筋处理的软土地基进行了高路堤施工期间的沉降与稳定观测,并提出适合工程特点的控制标准.从而达到控制路堤稳定、检验填筑质量、控制差异沉降、为路面施工提供技术支持的目的.     

四川青衣江上游若壁小沟泥石流及其防治对策

若壁小沟为四川青衣江上游左岸的一级支沟,该沟处于深切割高山峡谷区,地形坡度陡,构造发育,岩石破碎,加之较为丰富的降雨,使该沟具备泥石流暴发的条件。该沟如果暴发泥石流,将对某电站拟建厂房产生威胁。该沟泥石流具有成灾快、危害严重、松散固体物质以坡面崩塌补给为主、活动频率中等等特征。通过野外考察和取样分析,该沟泥石流的性质和类型为中频率—中~大规模—低~高粘度泥石质泥石流。分析预测了该沟泥石流在强烈地震条件下、近期出现不同频率暴雨情况下及人类活动影响下的发展趋势。在此基础上,提出了该沟泥石流减灾工程规划方案。     

东北地区降水年内分配的不均匀性

利用东北地区93个台站1961-2005年的逐日降水资料,通过降水集中度和降水集中期,讨论了该地区降水的年内分配不均匀分布特征.结果表明,东北地区的降水集中度自东南向西北逐渐递减;集中期具有南北高中问低的变化特点.从长期趋势上看,降水集中度的减小趋势显著,在该地区的东北部和西北部各有一个趋势明显的区域(通过0.05的显著性检验),但集中期的减小趋势不显著,只有2个台站通过显著性检验.年降水量与降水集中度和降水集中期的相关系数表明:东北地区年降水量与降水集中度呈显著的正相关,即年降水量越多(少)的地区,年内降水越集中(均匀);年降水量与降水集中期的关系并不显著.     

人工神经网络在预测深基坑周边地表沉降变形中的应用研究

深基坑开挖引起的周边地表变形预测是一个复杂非线性问题,引起地表沉降的影响因素很多,各因素之间呈高度的非线性关系。传统的基坑用边地表沉降变形预测方法存在着一定的局限性,其预测精度有待提高,而人工神经网络是一种多元非线性动力学系统,可以灵活方便地对多成因的复杂未知系统进行高度建模,实现全面考虑各种主要影响因素的深基坑周边地表沉降变形预测。本文介绍了误差反向传播(BP)网络模型的结构、学习过程及其算法的改进,径向基函数(RBF)网络模型的结构及其学习过程;分析了影响深基坑开挖周边土体沉降变形的主要影响因素;以25个基坑工程的地表沉降实测资料为训练样本,建立了11个输入影响因素的BP神经网络模型和RBF神经网络模型,通过对样本的学习训练过程及对5个检验样本的预测精度,说明了人工神经网络用于预测基坑周边地表沉降的可行性和准确性。     

人工甜味剂环境行为研究进展

人工甜味剂是一类人工合成或半合成的蔗糖取代物,由于人们对饮食健康的关注而被越来越广泛地应用于食品和饮料中.但是大多数人工甜味剂在人体内几乎不被代谢就随尿液和粪便直接排到生活污水中.近年,几种典型的甜味剂在水体中广泛被检出且浓度较高,同时研究发现部分甜味剂难以降解,因此人工甜味剂已被视为新型有机污染物而得到关注.本文就人工甜味剂在水处理设施中的行为及其在环境来源和分布的相关研究进行了综述,总结了水处理设施和水环境中甜味剂的污染特征规律,并对今后的研究进行了展望.     

Role of water chemistry on estrone removal by nanofiltration with the presence of hydrophobic acids

Hydrophobic acid organic matter (HpoA) extracted from treated effluent has been known to improve the rejection of steroid hormone estrone by reverse osmosis (RO) and nanofiltration (NF) membranes. In this study, the effects of solution chemistry (solution pH and ionic strength) on the estrone rejection by NF membrane with the presence of HpoA were systematically investigated. Crossflow nanofiltration experiments show that the presence of HpoA significantly improved estrone rejection at all pH and ionic strength levels investigated. It is consistently shown that the “enhancement effect” of HpoA on estrone rejection at neutral and alkaline pH is attributed to the binding of estrone by HpoA macromolecules via hydrogen bonding between phenolic functional groups in feed solutions, which leads to an increase in molecular weight and appearance of negative charge. The membrane exhibited the best performance in terms of estrone rejection at pH 10.4 (compared to pH 4 and pH 7) as a result of strengthening the electrostatic repulsion between estrone and membrane with the presence of HpoA. At neutral pH level, the ability of HpoA macromolecules to promote estrone rejection became stronger with increasing ionic strength due to their more extended conformation, which created more chances for the association between estrone and HpoA. The important conclusion of this study is that increasing solution pH and salinity can greatly intensify the “enhancement effect” of HpoA. These results can be important for NF application in direct/indirect potable water reuse.     

Sulfamethoxazole sorption by sediment fractions in comparison to pyrene and bisphenol A

The environmental behavior of antibiotics has attracted great research attention. However, their sorption mechanisms in soils/sediments are still unknown. Comparison of the sorption properties between the widely-studied hydrophobic organic contaminants (HOCs) and antibiotics may provide valuable insight to antibiotic sorption mechanisms. Thus, in this study batch experiments for pyrene (PYR), bisphenol A (BPA), and sulfamethoxazole (SMX) sorption were conducted on a sediment sample and its separated fractions. Our results showed the high sorption of PYR on black carbon and organic matter. Although high sorption of SMX was observed for both separated organic fractions (humic acids) and inorganic mineral particles, the original sediment particles showed relatively low sorption. Competitive sorption between SMX and dissolved humic acid on mineral particles was observed in this study. This competitive interaction is a unique process for antibiotic sorption in soils/sediments compared with apolar HOCs and may be one of the important factors controlling the antibiotic sorption.     

基于两步优劣解距离法的地下水污染监测网优化

地下水污染监测网的优化能让监测网以合理监测成本获取精确的地下水水质信息.为兼顾监测网空间特征与统计特征,综合考虑区域地下水水质状况和水文地质状况,提出了两步优劣解距离法优化监测网.首先以地下水典型污染物加权综合污染指数和防污性能指数为指标,采用优劣解距离法对现有监测网各监测井评分,并筛选得到不同监测井数量条件下的备选优...     

城区与郊区空间相互作用动力机制研究

我国城市化水平逐渐提高,城区地域不断扩张,这在一定程度上促进了城区与郊区一体化发展。但城区地域扩张并不是城区与郊区相互作用的唯一方式,且城区地域扩张在促进两者互动上力量薄弱,难以有效推进城区与郊区社会经济一体化发展。在分析城区与郊区相互作用背后隐藏的理论及其影响因子的基础上,探讨了城区与郊区相互作用的主要机制,为今后制定政策、促进城区与郊区快速一体化发展提供理论依据。     

Aging activity of DDE in dissimilar rice soils in a greenhouse experiment

A green-house study was conducted in late 2005 to investigate the aging behavior of p,p'-DDE in two types of soil, Hydragric Anthrosols (An) and Hydragric Acrisols (Ac), according to the World Reference Base (WRB) [FAO/ISRIC/ISSS. 1998. World reference base for soil resources. World soil resources reports, Rome. p. 87]. Paddy rice and dry rice were grown in submerged paddy soils and non-submerged upland soils, respectively. The concentration of extractable p,p'-DDE in fresh DDE-spiked soils was 746.2ngg(-1). During the first few weeks of the experiment, the extractability of p,p'-DDE became increasingly low as the aging period prolonged. However, certain amount of p,p'-DDE that had been captured by soil minerals and organic matter (OM) could be released and became extractable in the later period. The extractability of p,p'-DDE in submerged soils was significantly lower than that in non-submerged soil, because flooding could increase the binding of pollutants to soil particles. The plantation of both dry rice and paddy rice slowed down the aging process of p,p'-DDE. After one month's growth of rice, p,p'-DDE bound to soil particles was released and became extractable. The OM and silt content of An are higher than that of Ac, resulting in more bound residues and relative lower extractability of p,p'-DDE in An. In addition, the extractability of p,p'-DDE could be reduced by the addition of rice straw to soils.