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731.
A strategy for aromatic hydrocarbon bioremediation under anaerobic conditions and the impacts of ethanol: a microcosm study 总被引:7,自引:0,他引:7
Increased use of ethanol-blended gasoline (gasohol) and its potential release into the subsurface have spurred interest in studying the biodegradation of and interactions between ethanol and gasoline components such as benzene, toluene, ethylbenzene and xylene isomers (BTEX) in groundwater plumes. The preferred substrate status and the high biological oxygen demand (BOD) posed by ethanol and its biodegradation products suggests that anaerobic electron acceptors (EAs) will be required to support in situ bioremediation of BTEX. To develop a strategy for aromatic hydrocarbon bioremediation and to understand the impacts of ethanol on BTEX biodegradation under strictly anaerobic conditions, a microcosm experiment was conducted using pristine aquifer sand and groundwater obtained from Canadian Forces Base Borden, Canada. The initial electron accepter pool included nitrate, sulfate and/or ferric iron. The microcosms typically contained 400 g of sediment, 600 approximately 800 ml of groundwater, and with differing EAs added, and were run under anaerobic conditions. Ethanol was added to some at concentrations of 500 and 5000 mg/L. Trends for biodegradation of aromatic hydrocarbons for the Borden aquifer material were first developed in the absence of ethanol, The results showed that indigenous microorganisms could degrade all aromatic hydrocarbons (BTEX and trimethylbenzene isomers-TMB) under nitrate- and ferric iron-combined conditions, but not under sulfate-reducing conditions. Toluene, ethylbenzene and m/p-xylene were biodegraded under denitrifying conditions. However, the persistence of benzene indicated that enhancing denitrification alone was insufficient. Both benzene and o-xylene biodegraded significantly under iron-reducing conditions, but only after denitrification had removed other aromatics. For the trimethylbenzene isomers, 1,3,5-TMB biodegradation was found under denitrifying and then iron-reducing conditions. Biodegradation of 1,2,3-TMB or 1,2,4-TMB was slower under iron-reducing conditions. This study suggests that addition of excess ferric iron combined with limited nitrate has promise for in situ bioremediation of BTEX and TMB in the Borden aquifer and possibly for other sites contaminated by hydrocarbons. This study is the first to report 1,2,3-TMB biodegradation under strictly anaerobic condition. With the addition of 500 mg/L ethanol but without EA addition, ethanol and its main intermediate, acetate, were quickly biodegraded within 41 d with methane as a major product. Ethanol initially present at 5000 mg/L without EA addition declined slowly with the persistence of unidentified volatile fatty acids, likely propionate and butyrate, but less methane. In contrast, all ethanol disappeared with repeated additions of either nitrate or ferric iron, but acetate and unidentified intermediates persisted under iron-enhanced conditions. With the addition of 500 mg/L ethanol and nitrate, only minor toluene biodegradation was observed under denitrifying conditions and only after ethanol and acetate were utilized. The higher ethanol concentration (5000 mg/L) essentially shut down BTEX biodegradation likely due to high EA demand provided by ethanol and its intermediates. The negative findings for anaerobic BTEX biodegradation in the presence of ethanol and/or its biodegradation products are in contrast to recent research reported by Da Silva et al. [Da Silva, M.L.B., Ruiz-Aguilar, G.M.L., Alvarez, P.J.J., 2005. Enhanced anaerobic biodegradation of BTEX-ethanol mixtures in aquifer columns amended with sulfate, chelated ferric iron or nitrate. Biodegradation. 16, 105-114]. Our results suggest that the apparent conservation of high residual labile carbon as biodegradation products such as acetate makes natural attenuation of aromatics less effective, and makes subsequent addition of EAs to promote in situ BTEX biodegradation problematic. 相似文献
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733.
734.
蒙古冷涡影响下宁夏两次典型冰雹天气对比分析 总被引:2,自引:0,他引:2
基于常规气象资料和宁夏中尺度区域数值模式MM5输出结果,应用天气学及诊断分析方法,对2004年6月14日和2005年5月30日发生在宁夏的两次典型冰雹天气过程,从环流背景、影响系统、冰雹落区、大气层结稳定度及动力条件等方面进行了对比分析。结果表明:两次冰雹天气过程均发生在宁夏冰雹易发期夏初季节的午后,是在"西高东低"有利于强对流天气发生的环流背景下,受蒙古冷涡影响而形成的。由于环流形势及其演变的不同,使蒙古冷涡移动路径有所差异,造成宁夏不同区域受到冰雹袭击。 相似文献
735.
736.
火灾高温下CFRP加固钢筋混凝土梁温度场分析 总被引:1,自引:0,他引:1
综合国外CFRP加固混凝土结构抗火试验相关研究,总结了CFRP的高温热工性能参数。用ANSYS软件对火灾高温下不同情况(无防火保护层和有防火保护层)和不同工况(防火涂料涂抹形式)下CFRP加固后的钢筋混凝土梁进行了温度场数值模拟研究。结果表明,防火涂料厚40 mm时,梁耐火极限可达2.5小时以上,且底面和两侧面全面涂抹防火涂料的防火效果最好。本文研究有助于进一步深入认识CFRP加固钢筋混凝土结构在高温下的力学性能和耐火极限,且对CFRP加固后的结构防火设计具有一定的指导意义。 相似文献
737.
738.
长江流域地质—生态环境的演化机制及综合自然灾害区划 总被引:13,自引:3,他引:10
地质-生态环境是新一轮国土资源大调查的新概念, 同时也是现代地学研究的一个重要的范畴,在分析地质-生态环境系统及其演变的动力学机制的基础上,本文首先探索了长江流域地质-生态环境的演化机制,结合其自然环境状况,揭示了长江流域自然灾害形成的综合机制及其分布规律;并在此基础上,依托图文信息可视化系统技术手段,采取自上而下和自下而上两种进行综合自然灾害区划,其区划等级体系为3个自然灾害区和9个自然灾害亚区,为合理利用自然资源及防治自然灾害和环境退化提供了基本依据。 相似文献
739.
云南近期3次中强震的天文背景 总被引:2,自引:1,他引:1
分析了澄江地震至丘北地震间云南发生的3次中强震时的天体位置、地球自转与太阳活动等天文背景,分析结果表明,尽管这3次地震的震级都较小,但都发生在震中所受引潮力变化较大时刻和太阳活动局部下降时段。 相似文献
740.
蒽醌染料中间体溴氨酸降解酶的特性 总被引:5,自引:0,他引:5
从污染地分离筛选出的菌株BX26对蒽醌染料中间体溴氨酸有显著的降解脱色作用,降解过程受降解酶的控制,试验结果表明,降解酶为溴氨酸诱导的胞外酶,该酶在温度高于50℃处理后失活,盐度对该酶失活有影响,盐度高于1%会显著降低该酶活力,酶对溴氨酸的催化脱色要有氧参加,氮气气氛中酶活受抑制。 相似文献