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H.W. Ou M.L. Fang M.S. Chou T.F. Shiao 《Journal of the Air & Waste Management Association (1995)》2020,70(6):641-648
ABSTRACT
In this study, granular activated carbon (GAC) was used as an adsorbent for biogas desulfurization. Biogas containing 932–2,350 ppm of H2S was collected from an anaerobic digester to treat the wastewater from a dairy farm with about 200 cows. An adsorption test was performed by introducing the biogas to a column that was packed with approximately 50 L of commercial GAC. The operation ceased if the effluent gas had an H2S concentration of over 100 ppm. The GAC was replaced by a given weight of new GAC in a subsequent test. According to the results, for H2S concentrations in the range of 932–1,560 ppm (average±SD = 1,260 ± 256 ppm), 1 kg of the GAC yielded biogas treatment capacities of 568 ± 112 m3 and H2S adsorption capacities of 979 ± 235 g. For the higher influent H2S concentrations of 2,110 ± 219 ppm, the biogas treatment and H2S-adsorption capacities decreased to 229 ± 18 m3 and 668 ± 47 g, respectively. An estimation indicated a requisite cost of US$16.5 for the purification of 1,000 m3 of biogas containing 2,110 ppm of H2S. This cost is approximately 5% of US$330, the value of 1,000 m3 of biogas. 相似文献
226.
Acute toxicity of benzene derivatives to the tadpoles (Rana japonica) and QSAR analyses 总被引:2,自引:0,他引:2
Acute lethal toxicity (the negative logarithm of molar concentrations of 12 h acute median lethal, expressed as 12 h-log1/LC50) of 46 benzene derivatives to Rana japonica tadpoles was determined. 1-octanol/water partition coefficient (logKow)-dependent models were developed to study the toxicity of different categories chemicals. In an effort to model all chemicals, response surface analyses and stepwise multiple regression analyses were performed and successful models were obtained. A general and robust QSAR model was achieved with the combined application of variables reflecting hydrophobicity, electric property, and molecular size respectively (12h-log1/LC50 = 0.393logKow - 0.428Elumo + 0.0110Vol. + 1.362 n = 51, r2 = 0.834) using stepwise multiple regression analyses. Because of strong dissociation of carboxyl group greatly decreasing their observed toxicity, using logDow in instead of logKow the quality of the models is greatly improved. The conventional r2 and cross-validation r2(CV) were 0.914 and 0.785, respectively, indicating that QSAR was both internally consistent and highly predictive. 相似文献
227.
生活水污泥油化试验研究 总被引:10,自引:0,他引:10
用碳酸钠与污泥混合,在压力4 ̄5kgf/cm^2、温度300 ̄450℃获得燃料油16%左右,气体各C1 ̄C3烃类占体积的约19%,臭气物质主要10种。 相似文献
228.
Thomas JE Allen LH McCormack LA Vu JC Dickson DW Ou LT 《Journal of environmental science and health. Part. B》2004,39(5-6):709-723
The fumigant 1,3-dichloropropene (1,3-D) is considered to be a potential replacement for methyl bromide when methyl bromide is phased out in 2005. This study on surface emissions and subsurface diffusion of 1,3-D in a Florida sandy soil was conducted in field beds with or without plastic covers. After injection of the commercial fumigant Telone II by conventional chisels to field beds at 30cm depth which were covered with polyethylene film (PE), virtually impermeable film, or no cover (bare), (Z)- and (E)-1,3-D rapidly diffused upward. Twenty hours after injection, majority of (Z)- and (E)-1,3-D had moved upward from 30 cm depth to the layer of 5-20 cm depth. Downward movement of the two isomers in the beds with or without a plastic cover was not significant. (Z)-1,3-D diffused more rapidly than (E)-1,3-D. Virtually impermeable films (VIF) had a good capacity to retain (Z)- and (E)-1,3-D in soil pore air space. Vapor concentrations of the two isomers in the shallow subsurface of the field bed covered with VIF were greater than that in the two beds covered with polyethylene film (PE) or no cover (bare). In addition, VIF cover provided more uniform distribution of (Z)- and (E)-1,3-D in shallow subsurface than PE cover or no cover. Virtually impermeable film also had a better capability to retard surface emissions of the two isomers from soil in field beds than PE cover or no cover. 相似文献
229.
本文以文献中提出的结构体系可靠度分析的最弱失效模式法为基础,充分考虑结构体系的造价和结构的损失期望与结构体系可靠度的关系,以及结构构件的可靠度约束,提出了结构体系目标可靠度的优化决策方法;基于优化决策的结果,提出了结构体系的最优设计准则;最后,依所提出的最优设计准则,实现了高层建筑基于构件和结构可靠度约束的结构优化设计。 相似文献
230.
本文介绍两类环保型棉纺织品耐久阻燃系统,一类是无卤锑系统,另一类是无甲醛或低甲醛系统。前一类包括磷氮系膨胀型阻燃剂、有机磷酸酯及多元醇磷酰氯;后一类包括低甲醛的磷氮系、磷酸酯-膦酸酯齐聚物-低甲醛含量树脂复合系统、烷基氨基磷酸酯-氯化铵加合物、多羧酸酯等。后两者系无甲醛配方。 相似文献