荷电超滤膜的研究：Ⅰ.氯甲基化聚砜超滤膜的研究

膜材料本身的性质是决定膜性能的主要因素，对于荷电超滤膜，荷电性和荷电程度对膜性能有较大的影响，本文研究了含氯量对氯甲基化聚砜超滤膜性能的影响，就有关制膜条件对膜的物理性能和电性能的影响也进行了研究。     

农田土壤中铜的来源分析及控制阈值研究

农田土壤重金属污染直接危及到生态安全、食品安全和人体健康.从源头上控制农田土壤重金属污染是农业可持续发展和保障农产品质量安全的首要措施.本文采用物质流分析法与情景分析法,以水稻(双季稻、单季稻)、小麦-玉米、蔬菜(叶菜、根菜和果菜)的产地农田生态系统为研究对象,研究农田土壤中重金属铜的输入途径(大气沉降、磷肥、有机肥以及灌溉水)和输出途径(籽粒/可食部位、秸秆/残余物以及地表排水),并通过文献查阅和采样分析建立数据库,在平衡分析基础上为了保障100年土壤铜累积不超过设定的情景水平,当土壤铜背景值含量分别增加50％,100％和150％时,推导出磷肥、有机肥以及灌溉水的重金属含量安全阈值,磷肥中铜含量应控制在65～175 mg·kg-1范围内;畜禽粪肥中铜含量应控制在35～95 mg· kg-1范围内.灌溉水质标准应控制在40～70 μg·L-1范围内.这将为我国农产品产地安全管理和源头预防控制,保障我国农产品质量安全提供一定的技术指导作用.     

"t"检验法则在闽北抗寒速生邓恩桉优株筛选的应用

用材林优株筛选通常应用"11株标准木与5株优势木法",但在选择上,优良单株的选择标准确定存在主观性,所筛选的优良单株需反复试验,才能得到目的优良遗传性状,所需时间长.本文利用大样本调查方法,通过对引种地1～4 a生实生苗造林的邓恩桉不同林分优良单株进行预选.在不同年龄林分中,以预选的优势木为中心,依据早期林分各生长性状呈正态分布规律,利用正态分布的"t"检验法确定优株筛选的选择标准,应用所确定的选择标准筛选抗寒速生优株.从1-4 a生林分中分别筛选得优株6、5、2、2株.与优株所在林分平均值比较,1～4 a生树高分别增长90.5%、39.0%、45.2%、61.5%以上.2～4 a生胸径分别增长37.9%、81.2%、73.3%以上,2～4a生材积分别增长134%、378%、339%以上.该方法是基因重组的突变理论与数理统计的异常数据剔除法的综合,能一次性检验获得突变优良遗传性状,克服了上述两种方法的主观性,大大缩短了选择时间,提高了优良性状的利用率.该方法系本文首次提出并称作"t"检验选择法,在用材林优株筛选应用上具有良好的指导价值.表4参14     

Impacts of microbial redox conditions on the phase distribution of pyrene in soil-water systems

Variations in the soil/sediment organic matter (SOM)-hydrophobic organic contaminant (HOC) bindings upon microbially mediated redox conditions were examined. While the extractability of pyrene associated with soil declined after its biodegradation began during aerobic incubation, its variations were almost constant (±3.0-4.4%) during anoxic/anaerobic incubations. The dissolved organic matter released from the soil incubated under highly reduced conditions became more humified and aromatic, had a higher average molecular weight, and was more polydispersed compared to that obtained from oxic incubation, similar to the SOM alterations in the early stage of diagenesis (humification). The concentrations of pyrene in the aqueous phase increased significantly during the soil incubations under highly reduced conditions due to its favorable interaction with the altered DOM. Our results suggest that the microbially mediated redox conditions have significant impacts on SOM and should be considered for the transport, fate, bioavailability, and exposure risk of HOCs in the geo-environments.     

Acquired changes in stomatal characteristics in response to ozone during plant growth and leaf development of bush beans (Phaseolus vulgaris L.) indicate phenotypic plasticity

Bush bean (Phaseolus vulgaris L.) lines 'S156' (O3-sensitive)/'R123' (O3-tolerant) and cultivars 'BBL 290' (O3-sensitive)/'BBL 274' (O3-tolerant) were used to study the effects of O3 on stomatal conductance (gs), density, and aperture size on leaf and pod surfaces with the objective of establishing links between the degree of plant sensitivity to O3 and plasticity of stomatal properties in response to O3. Studies in open-top chambers (OTCs) and in continuously stirred tank reactors (CSTRs) established a clear relationship between plant developmental stages, degrees of O3 sensitivity and gs: while 'S156' had higher gs rates than 'R123' earlier in development, similar differences between 'BBL 290' and 'BBL 274' were observed at later stages. Gs rates on the abaxial leaf surfaces of 'S156' and 'BBL 290', accompanied by low leaf temperatures, were significantly higher than their O3-tolerant counterparts. Exposure to O3 in CSTRs had greater and more consistent impacts on both stomatal densities and aperture sizes of O3-sensitive cultivars. Stomatal densities were highest on the abaxial leaf surfaces of 'S156' and 'BBL 290' at higher O3 concentrations (60 ppb), but the largest aperture sizes were recorded on the adaxial leaf surfaces at moderate O3 concentrations (30 ppb). Exposure to O3 eliminated aperture size differences on the adaxial leaf surfaces between sensitive and tolerant cultivars. Regardless of sensitivity to O3 and treatment regimes, the smallest aperture sizes and highest stomatal densities were found on the abaxial leaf surface. Our studies showed that O3 has the potential to affect stomatal plasticity and confirmed the presence of different control mechanisms for stomatal development on each leaf surface. This appeared to be more evident in O3-sensitive cultivars.     

Microbial structure and chemical components of aerosols caused by rotating brushes in a wastewater treatment plant

Purpose

Bacterial community structure and the chemical components in aerosols caused by rotating brushes in an Orbal oxidation ditch were assessed in a Beijing municipal wastewater treatment plant.

Methods

Air samples were collected at different distances from the aerosol-generating rotating brushes. Molecular culture-independent methods were used to characterize the community structure of the airborne bacteria in each sample regardless of cell culturability. A clone library of 16S rDNA directly amplified from air DNA of each sample was constructed and sequenced to analyze the community composition and diversity. Insoluble particles and water-soluble ions emitted with microorganisms in aerosols were analysis by a scanning electron microscope together with energy dispersive X-ray spectroscopy and ion chromatogram analyzer.

Results

In total, most of the identified bacteria were Proteobacteria. The majority of sequences near the rotating brushes (the main source of the bioaerosols) were Proteobacteria (62.97 %) with ??-(18.52 %) and ??-(44.45?%) subgroups and Bacteroidetes (29.63 %). Complex patterns were observed for each sampling location, suggesting a highly diverse community structure, comparable to that found in water in the Orbal oxidation ditch. Accompany with microorganisms, 46.36???g/m³ of SO ₄ ^2? , 29.35???g/m³ of Cl^?, 21.51???g/m³ of NO ₃ ^? , 19.76???g/m³ of NH ₄ ⁺ , 11.42???g/m³ of PO ₄ ^3? , 6.18???g/m³ of NO ₂ ^? , and elements of Mg, Cl, K, Na, Fe, S, and P were detected from the air near the aerosols source.

Conclusions

Differences in the structure of the bacterial communities and chemical components in the aerosols observed between sampling sites indicated important site-related variability. The composition of microorganisms in water was one of the most important sources of bacterial communities in bioaerosols. Chemical components in bioaerosols may provide a media for airborne microorganism attachment, as well as a suitable microenvironment for their growth and survival in the air. This study will be benefit for the formulation of pollution standards, especially for aerosols, that take into account plant workers?? health.     

染料结构-光催化降解活性关系初步研究

以近20种水溶性染料为研究对象,选择正辛醇-水分配系数(Kow)、分子最高占据轨道能(EHOMO)及分子最低空轨道能(ELUMO)等理化参数,建立了染料的定量结构-光催化降解反应活性关系模型,得到定量关系式为:lgk＝0.016 28×lgKow 0.132 46×(ELUMO-EHOMO)-2.148 56,很好地表示反应活性与结构之间的定量关系,为水溶性染料的光催化降解活性预测提供了有效的工具.     

油田含油污泥超声脱油的研究

在油田含油污泥的热洗处理中引入超声辐照处理技术,研究考察了超声脱油技术中超声强度,超声辐照时间,含油污泥预热温度,清洗液用量和清洗液回用4个试验操作条件对污泥脱油的影响,认为在优化条件（超声发生器输出电压175 V,辐照时间15 min,预热温度55 ℃,清洗液和含油污泥以质量比8∶1）下,超声脱油技术可以把污泥的干基油含量由0.35 g/g降低到0.14 g/g,同时也证明清洗液可以反复使用。根据简单的经济核算,处理1 t含油污泥可以产出66元的效益。研究表明,使用超声处理可以有效地提高含油污泥的污油脱除效率,明显降低污泥清洗的操作温度。     

再生水用于都市绿地灌溉的研究进展

污水再利用具有节水和治污双重功能,用于绿地灌溉意义重大。综述了再生水灌溉对绿地土壤、植物、地下水的影响。着重介绍了国外的研究情况,分析了其试验结果及影响因素,表明虽然再生水中的一些有害成分会发生积累,但由于处理工艺、降雨等因素影响,对绿地生态系统影响不大,使用再生水灌溉绿地是切实可行的。     

基于功能需求导向的城市综合体震后修复路径优化方法研究∗

城市综合体内部功能繁多,强震作用下综合体结构功能失效会影响城市区域功能的正常运转。建筑震后修复期望综合体内部重要功能优先、快速恢复并投入使用,合理规划其震后修复路径是满足此类结构功能需求的关键。既有研究中建筑震后多采取自下而上的修复路径,未考虑震后功能需求。基于此,提出了一种基于功能需求导向的城市综合体震后修复路径优化方法。考虑综合体具有的多功能特性及不同功能区内构件间的功能相关性特点,建立了基于故障树的功能损失分析模型,并以此为基础结合建筑功能区划分功能修复单元;以各功能的期望修复时间作为功能需求目标,对比功能修复单元的实际修复时间,提出功能需求目标完成率指标;在此基础上建立震后修复路径优化模型,结合遗传算法,形成了综合体震后修复路径优化方法。对某城市综合体开展震后修复路径优化,结果表明：所提方法可高效完成功能需求目标,使重要功能震后快速恢复并投入使用。