Combating interference by unauthorised persons

Under the new threat situation it is necessary to impede and if necessary detect ingress by unauthorised persons into the relevant establishment. It may be necessary to take additional measures to protect installations or parts thereof that are especially hazardous or at risk from terrorist attacks from interference by unauthorised persons.

It is the duty of the state to take precautionary and preventive measures to impede or prevent external terrorist attacks or entry by force into establishments. The necessary resources for this purpose must be made available even in times of limited budgets.

Since total protection can never be guaranteed, external emergency measures have a particularly important role to play. The competent authorities in this sector must receive the necessary information from the operators and must take the measures within their sphere of responsibility without delay.

Much of the information necessary for assessment of the risk situation by the operators and the authorities is already available under the provisions on the safety report and the external alarm and emergency plans according to European Seveso II Directive (96/82/EC).

It is recommended that a restriction of disclosure of information on the grounds of public safety should only be permitted for establishments/installations which are to be regarded as security-relevant on the basis of the hazard and the risk analysis.

The outline of the systematic approach of a security analysis like it is proposed in Germany is described separately.     

Effective synthesis of sulfate metabolites of chlorinated phenols

Chlorophenols are an important class of persistent environmental contaminants and have been implicated in a range of adverse health effects, including cancer. They are readily conjugated and excreted as the corresponding glucuronides and sulfates in the urine of humans and other species. Here we report the synthesis and characterization of a series of ten chlorophenol sulfates by sulfation of the corresponding chlorophenols with 2,2,2-trichloroethyl (TCE) chlorosulfate using N,N-dimethylaminopyridine (DMAP) as base. Deprotection of the chlorophenol diesters with zinc powder/ammonium formate yielded the respective chlorophenol sulfate ammonium salts in good yield. The molecular structure of three TCE-protected chlorophenol sulfate diesters and one chlorophenol sulfate monoester were confirmed by X-ray crystal structure analysis. The chlorophenol sulfates were stable for several months if stored at −20 °C and, thus, are useful for future toxicological, environmental and human biomonitoring studies.     

Reciprocal effects of platinum and lead on the water household of poplar cuttings

In order to study the accumulation rates and effects of platinum as influenced by lead, experiments were performed with poplar cuttings in a growth chamber. The heavy metals were added at a final concentration of 34.8 ppb each to nutrient solutions as PtCl₄ and Pb(NO₃)₂. The variants were 1) control; 2) permanent Pt treatment for 6 weeks; 3) pretreatment with Pt plus subsequent treatment with Pb (three weeks each), and 4) heavy metal application in inverse order to variant 3. The experiments revealed that platinum accumulates in the roots of poplar cuttings to a higher degree than lead. It is translocated from the roots to other plant parts to an extremely low degree. Lead is displaced from the roots by subsequent Pt treatment. Insoluble platinum was found to be associated especially on the cell walls of the rhizodermis and exodermis of the root tips. Accumulation of platinum in the roots leads to a gradual depletion of the plants’ water supply. The disturbance of the water household causes a reduction of the transpirational surface, lowered transpiration rates and enhanced root growth. All these alterations are induced as a means of coping water stress. From the results of this experiment, the conclusion can be drawn that, under the chosen experimental conditions, platinum manifests a higher toxicity than lead in plant roots because of its higher accumulation rates.