On the barrier and nature of [1.2]-hydrogen migrations in HCN/HNC and their cation radicals

The Science of Nature -     

Synthesis of environmentally relevant fluorinated surfactants--a review

In the past years there has been a growing interest in fluorinated persistent organic pollutants such as perfluorooctanesulfonic acid, perfluorooctanesulfonamides, perfluorinated carboxylic acids and fluorotelomer alcohols. Although these compounds have probably been present in the environment for many decades, we are only now beginning to realize that these environmental contaminants may have serious environmental and health effects. This article gives a state-of-the-art review of synthetic approaches that have been employed for the synthesis of these environmentally relevant fluorinated compounds. Perfluorooctanesulfonic acid derivatives, in particular, pose a problem because only a few perfluorooctanesulfonic acid derivatives are available from commercial sources--a fact that limits the ability of researchers worldwide to further study these compounds. Because of the limited literature available, this article also describes synthetic approaches for shorter chain homologues or perfluoroether analogues that can potentially be applied for the synthesis of perfluorooctanesulfonic acid derivatives. The preparation of typical starting materials for the synthesis of perfluorooctanesulfonic acid derivatives such as the perfluoroalkanesulfonyl fluorides and chlorides will be discussed. Subsequently, their conversion into relevant perfluoroalkane sulfonate salts (R(F)SO3M), sulfonamides (R(F)SO2NH2), N-alkyl sulfonamides (R(F)SO2NHR, R = alkyl), N,N-dialkyl sulfonamides (R(F)SO2NR2, R = alkyl), sulfonamidoethanol (R(F)SO2NRCH2CH2OH, R = -H, -CH3 or -C2H5) and sulfonamidoacetates (R(F)SO2NRCH2CO2H, R = -H, -CH3 or -C2H5) will be described. Many perfluorinated carboxylic acids and fluorotelomer alcohols are available from commercial sources. The review of the synthesis of these two classes of fluorinated compounds includes a review of their industrial synthesis and the synthesis of relevant degradation products.     

Source identification of PCDD/Fs in a sewage treatment plant of a German village

The PCDD/F levels in the sewage sludge of a village in North-East Germany were substantially above the limit of 100 pg I-TEq/g for sludge applied to land. A study was initiated to identify the PCDD/F sources in the sewage of this treatment plant. It was found that the PCDD/F contamination entered the plant through the faecal inlet, where the content of faecal storage tanks was emptied into the treatment plant. The isomeric patterns of the higher chlorinated homologues were similar to that of PCP, while incineration showed some influence on the lower chlorinated homologues. Cluster analysis revealed a profile similar to that of PCP.     

Umweltdatenbanken bei STN International — ihre Nutzung in der Praxis

Der Beitrag umfa?t eine übersicht über die Entwicklung wesentlicher Segmente des in Deutschland und international zug?nglichen Angebots an Umweltdatenbanken. Anschlie?end werden wichtige Umweltdatenbanken im Angebot von STN International dargestellt. Anhand ausgew?hlter Beispiele aus der Recherchepraxis werden schlie?lich Ablauf (Stufen der Vorbereitung, Durchführung und Nachbereitung) sowie Ergebnisse der Online-Recherche in wichtigen STN-Umweltdatenbanken dargestellt.     

Toward a high-rate enhanced biological phosphorus removal process in a membrane-assisted bioreactor.

A membrane enhanced biological phosphorus removal (MEBPR) process was studied to determine the impact of hydraulic retention time (HRT) and solids retention time (SRT) on the removal of chemical oxygen demand (COD), nitrogen, and phosphorus from municipal wastewater. The MEBPR process was capable of delivering complete nitrification independent of the prevailing operating conditions, whereas a significant improvement in COD removal efficiency was observed at longer SRTs. In the absence of carbon-limiting conditions, the MEBPR process was able to achieve low phosphorus concentrations in the effluent at increasingly higher hydraulic loads, with the lowest HRT being 5 hours. The MEBPR process was also able to maintain optimal phosphorus removal when the SRT was increased from 12 to 20 days. However, at higher suspended solids concentrations, a substantial increase was observed in carbon utilization per unit mass of phosphorus removed from the influent. These results offer critical insights to the application of membrane technology for biological nutrient removal systems.     

A rule-based screening environmental risk assessment tool derived from EUSES

Within the context and scope of the forthcoming European Union chemical regulations (REACH), there is a need to be able to prioritise the chemicals for evaluation. Therefore, a simple, pragmatic and adequately conservative approach for the identification of substances of very low or no immediate concern at an early stage is presented. The fundamental principles and basic concepts are derived from the EU Technical Guidance Document and EUSES, and are translated into an easy-to-use rule-based system. For this development, the effect on risk characterisation ratios (RCRs) of the key environmental parameters in EUSES was quantified (taking into account several standardised chemical release scenarios). Using statistical analysis, ranges were identified for each key parameter, within which the end result of the assessment was not significantly affected. This information was then translated into a lookup table from which environmental risk characterisation ratios can be directly read as a function of a few parameters.