全文获取类型
收费全文 | 2496篇 |
免费 | 158篇 |
国内免费 | 941篇 |
专业分类
安全科学 | 232篇 |
废物处理 | 134篇 |
环保管理 | 193篇 |
综合类 | 1541篇 |
基础理论 | 444篇 |
污染及防治 | 700篇 |
评价与监测 | 129篇 |
社会与环境 | 128篇 |
灾害及防治 | 94篇 |
出版年
2024年 | 13篇 |
2023年 | 72篇 |
2022年 | 142篇 |
2021年 | 150篇 |
2020年 | 122篇 |
2019年 | 106篇 |
2018年 | 122篇 |
2017年 | 136篇 |
2016年 | 100篇 |
2015年 | 156篇 |
2014年 | 202篇 |
2013年 | 207篇 |
2012年 | 219篇 |
2011年 | 219篇 |
2010年 | 156篇 |
2009年 | 153篇 |
2008年 | 192篇 |
2007年 | 137篇 |
2006年 | 147篇 |
2005年 | 86篇 |
2004年 | 60篇 |
2003年 | 84篇 |
2002年 | 88篇 |
2001年 | 86篇 |
2000年 | 63篇 |
1999年 | 55篇 |
1998年 | 51篇 |
1997年 | 43篇 |
1996年 | 51篇 |
1995年 | 36篇 |
1994年 | 38篇 |
1993年 | 21篇 |
1992年 | 20篇 |
1991年 | 11篇 |
1990年 | 8篇 |
1989年 | 7篇 |
1988年 | 8篇 |
1987年 | 5篇 |
1986年 | 3篇 |
1984年 | 2篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1973年 | 1篇 |
1972年 | 2篇 |
1971年 | 1篇 |
排序方式: 共有3595条查询结果,搜索用时 156 毫秒
811.
Morton Corn Robert T. Cheng 《Journal of the Air & Waste Management Association (1995)》2013,63(11):870-875
A laboratory study was conducted of the heterogeneous catalysis of sulfur dioxide at ppm concentrations in air by insoluble particles of CaCO2, V2O5, Fe203, flyash from a coal-burning power plant, MnCO2, activated carbon, and suspended particulate matter from urban air. The investigalion was performed by utilizing a new technique for aerosol stabilization which consists of depositing the aerosol on Teflon beads in a fluidized bed. The Teflon beads with deposited aerosol particles were then packed into a flow reactor. Progress of the chemical reaction of SO2 with deposited particles was continuously monitored by determining the SO2 concentrations in the reactor effluent with a microcoulometer. In this investigation, CaCOg, V2O5, and flyash were essentially inert to SO2 at room temperature. Fe2O3, activated carbon, MnO2, and suspended particulate matter from urban air sorbed SO2 from air streams with up to 14.4 ppm SO2 in air. Evidence is presented which suggests that a substantial part of the sorbed SO2 was physically adsorbed. Bioassay procedures which utilize pulmonary flow resistance changes in guinea pigs to monitor response to inhaled SO2-aerosol mixtures in air have indicated the weak or non-potentiating capacity of insoluble aerosols as contrasted to soluble aerosols. Potentiating response of an aerosol appears to be strongly associated with reaction of SO2 in a water droplet containing aerosol ions and not with physically adsorbed SO2 on an insoluble aerosol. 相似文献
812.
S. Mackinson G. Daskalov J.J. Heymans S. Neira H. Arancibia M. Zetina-Rejón H. Jiang H.Q. Cheng M. Coll F. Arreguin-Sanchez K. Keeble L. Shannon 《Ecological modelling》2009
Fishing mortality and primary production (or proxy for) were used to drive the dynamics of fish assemblages in 9 trophodynamic models of contrasting marine ecosystems. Historical trends in abundance were reconstructed by fitting model predictions to observations from stock assessments and fisheries independent survey data. The model fitting exercise derives values for otherwise unknown parameters that specify the relative strength of trophic interactions and, in some instances, a time series anomaly for changes in primary production. We measured how much better or worse were model predictions when bottom-up forcing by primary production were added to top-down forcing by fishing. Searching for cross system patterns, the relative contribution of fishing and changes in primary production, mediated through trophic interactions, are evaluated for the ecosystems as a whole and for selected similar species in different ecosystems. The analysis provides a simple qualitative way to explain which forcing factors have most influence on modeled dynamics. Both fishing and primary production forcing were required to obtain the best model fits to data. Fishing effects more strongly influenced 6 of 9 of the ecosystems, but primary production was more often found to be the main factor influencing the selected pelagic and demersal fish stock trends. Examination of sensitivity to ecological and model parameters suggests that the results are the product of complex food-web interactions rather than simple deterministic responses of the models. 相似文献
813.
Impacts of Dung Combustion on the Carbon Cycle of Alpine Grassland of the North Tibetan Plateau 总被引:2,自引:0,他引:2
Zengrang Xu Shengkui Cheng Lin Zhen Ying Pan Xianzhou Zhang Junxi Wu Xiuping Zou G. C. Dhruba Bijaya 《Environmental management》2013,52(2):441-449
Alpine grassland of Tibet is a frangible ecosystem in terms of carbon (C) emission. Yak dung is an important resident energy with about 80 % of yak dung combusted for energy in the north Tibetan plateau. This paper investigated the impact of dung combustion on the C cycle of the alpine grassland ecosystem in north Tibet, China. During the growing season of 2011, from a field survey and household questionnaires, the main impacts of dung collection for fuel on the C cycle of the ecosystem were identified. (1) The C sequestration and storage capacity, including the dung-derived C stored in soil and C captured by vegetation, decreased. The net primary production decreased remarkably because of the reduction of dung returned to soil. (2) In a given period, more C was emitted to the atmosphere in the dung combustion situation than that in the dung returned to soil situation. (3) The energy grazing alpine meadow ecosystem changed into a net C source, and the net biome production of the ecosystem dropped to ?15.18 g C/m2 year in the dung combustion situation, 42.95 g C/m2 year less than that in the dung returned situation. To reduce the CO2 emission derived from dung use, the proportion of dung combustion should be reduced and alternative renewable energy such as solar, wind, or hydro energy should be advocated, which is suitable for, and accessible to, the north Tibetan plateau. 相似文献
814.
Yongyang Fu Feifei Li Ting Xu Sanjuan Cai Weiyue Chu Han Qiu Sha Sha Guangyu Cheng Qinsong Xu 《Environmental science and pollution research international》2014,21(4):2935-2942
Bioaccumulation, subcellular distribution, and acute toxicity of yttrium (Y) were evaluated in Nymphoides peltata. The effects of Y concentrations of 1–5 mg L?1 applied for 4 days were assessed by measuring changes in photosynthetic pigments, nutrient contents, enzymatic and non-enzymatic antioxidants, and ultrastructure. The accumulation of Y in subcellular fractions decreased in the order of cell wall > organelle > soluble fraction. Much more Y was located in cellulose and pectin than in other biomacromolecules. The content of some mineral elements (Mg, Ca, Fe, Mn, and Mo) increased in N. peltata, but there was an opposite effect for P and K. Meanwhile, ascorbate, and catalase activity decreased significantly for all Y concentrations. In contrast, peroxidase activity was induced, while initial rises in superoxide dismutase activity and glutathione content were followed by subsequent declines. Morphological symptoms of senescence, such as chlorosis and damage to chloroplasts and mitochondria, were observed even at the lowest Y concentration. Pigment content decreased as the Y concentration rose and the calculated EC50 and MPC of Y for N. peltata were 2 and 0.2 mg L?1 after 4 days of exposure, respectively. The results showed that exogenous Y was highly available in water and that its high concentration in water bodies might produce harmful effects on aquatic organisms. N. peltata is proposed as a biomonitor for the assessment of metal pollution in aquatic ecosystems. 相似文献
815.
Zhengwen Xu Ling Cheng Jing Shi Jiangang Lu Weiming Zhang Yunlong Zhao Fengying Li Mindong Chen 《Environmental science and pollution research international》2014,21(10):6571-6577
Phthalate acid esters are becoming an important class of pollutants in wastewaters. This study addresses the kinetics of removal of dimethyl phthalate (DMP) using the anion exchange resin D201-OH from an aqueous solution. The effects of various factors on the removal rate and efficiency were investigated. An overall initial removal rate (OIRR) law and a pseudo first-order kinetic (PFOK) model were also developed. The internal diffusion of DMP within the resin phase of D201-OH is the rate-controlling step. Optimization of the particle size and pore structure of the resin D201-OH, the DMP concentration, and the reaction temperature can improve the DMP removal rate. The hydrolysis reaction of DMP catalyzed by D201-OH indicates an overall reaction order of 1.76, a value that is between the first order and the second order. The apparent activation energy of the reaction is 34.6 kJ/mol, which is below the homogeneous alkaline hydrolysis activation energy of 44.3 kJ/mol. The OIRR law can quantify the initial removal rate under different conditions. The results also show that the theoretical DMP removal efficiency predicted by the PFOK model agrees well with the experimentally determined values. Our research provides valuable insights into the primary parameters influencing the kinetic process, which enables a focused improvement in the removal or hydrolysis rate for similar processes. 相似文献
816.
817.
818.
819.
820.
Zhu Yunqing Wang Tian Wang Wenjuan Chen Siyu Lichtfouse Eric Cheng Cheng Zhao Jie Li Yingxuan Wang Chuanyi 《Environmental Chemistry Letters》2019,17(1):481-486
Environmental Chemistry Letters - Contamination of waters by pharmaceuticals is a major health issue. Therefore, there is a need for efficient techniques to remove pharmaceutical pollutants. Here,... 相似文献