全文获取类型
收费全文 | 2556篇 |
免费 | 132篇 |
国内免费 | 1073篇 |
专业分类
安全科学 | 156篇 |
废物处理 | 137篇 |
环保管理 | 207篇 |
综合类 | 1547篇 |
基础理论 | 409篇 |
环境理论 | 1篇 |
污染及防治 | 965篇 |
评价与监测 | 115篇 |
社会与环境 | 105篇 |
灾害及防治 | 119篇 |
出版年
2024年 | 6篇 |
2023年 | 62篇 |
2022年 | 158篇 |
2021年 | 115篇 |
2020年 | 105篇 |
2019年 | 97篇 |
2018年 | 92篇 |
2017年 | 122篇 |
2016年 | 171篇 |
2015年 | 201篇 |
2014年 | 186篇 |
2013年 | 244篇 |
2012年 | 223篇 |
2011年 | 241篇 |
2010年 | 210篇 |
2009年 | 182篇 |
2008年 | 169篇 |
2007年 | 162篇 |
2006年 | 149篇 |
2005年 | 70篇 |
2004年 | 68篇 |
2003年 | 88篇 |
2002年 | 74篇 |
2001年 | 58篇 |
2000年 | 70篇 |
1999年 | 73篇 |
1998年 | 62篇 |
1997年 | 56篇 |
1996年 | 55篇 |
1995年 | 45篇 |
1994年 | 39篇 |
1993年 | 35篇 |
1992年 | 17篇 |
1991年 | 11篇 |
1990年 | 9篇 |
1989年 | 7篇 |
1988年 | 4篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1977年 | 1篇 |
1972年 | 2篇 |
1918年 | 1篇 |
1917年 | 1篇 |
1916年 | 1篇 |
排序方式: 共有3761条查询结果,搜索用时 0 毫秒
111.
Enhancement of solubilization and acidification of waste activated sludge by pretreatment 总被引:2,自引:0,他引:2
The effects of various pretreatment methods, including thermo-acid, thermo-alkaline, ultrasonic-alkaline and ultrasonic-acid, on solubilization and subsequent acidification efficiency of waste activated sludge (WAS) were investigated. The results showed that both thermo-alkaline and ultrasonic-alkaline significantly improved the solubilization of WAS at a high concentration (7.4% of total solids). Solubilization of volatile solids (VS) and crude protein was 60.2-61.6% and 66.8-67.5%, respectively. Thermo-alkaline or ultrasonic-alkaline pretreatment also enhanced the efficiency of subsequent WAS acidification. Experimental results showed that they had similar effects on the acidification of WAS. The conversion ratio from VS to total volatile fatty acids (TVFAs) was 0.230 in the case of the ultrasonic-alkaline pretreatment. Through this pretreatment, the level of TVFAs was 68% more than the untreated WAS after 252 h of fermentation. The mechanism of TVFAs production under different pretreatment methods was further investigated and the results indicated that soluble protein was the main substrate for TVFAs production from the WAS after the thermo-alkaline or ultrasonic-alkaline pretreatment. 相似文献
112.
X. Qu V.A. Vavilin L. Mazéas M. Lemunier C. Duquennoi P.-J. He T. Bouchez 《Waste management (New York, N.Y.)》2009,29(6):1828-1837
Utilizing stable carbon isotope data to account for aceticlastic and non-aceticlastic pathways of methane generation, a model was created to describe laboratory batch anaerobic decomposition of cellulosic materials (office paper and cardboard). The total organic and inorganic carbon concentrations, methane production volume, and methane and CO2 partial pressure values were used for the model calibration and validation. According to the fluorescent in situ hybridization observations, three groups of methanogens including strictly hydrogenotrophic methanogens, strictly aceticlastic methanogens (Methanosaeta sp.) and Methanosarcina sp., consuming both acetate and H2/H2CO3 as well as acetate-oxidizing syntrophs, were considered. It was shown that temporary inhibition of aceticlastic methanogens by non-ionized volatile fatty acids or acidic pH was responsible for two-step methane production from office paper at 35 °C where during the first and second steps methane was generated mostly from H2/H2CO3 and acetate, respectively. Water saturated and unsaturated cases were tested. According to the model, at the intermediate moisture (150%), much lower methane production occurred because of full-time inhibition of aceticlastic methanogens. At the lowest moisture, methane production was very low because most likely hydrolysis was seriously inhibited. Simulations showed that during cardboard and office paper biodegradation at 55 °C, non-aceticlastic syntrophic oxidation by acetate-oxidizing syntrophs and hydrogenotrophic methanogens were the dominant methanogenic pathways. 相似文献
113.
Min Zhu Fan Lü Li-Ping Hao Pin-Jing He Li-Ming Shao 《Waste management (New York, N.Y.)》2009,29(7):2042-2050
In this study, the effects of micro-aeration and liquid recirculation on the hydrolysis of vegetable and flower wastes during two-phase solid–liquid anaerobic digestion were assessed. To accomplish this, we evaluated the hydrolysis of five batches of waste that were treated under the following conditions: anaerobic, insufficient micro-aeration (aeration for 5 min every 24 h), and sufficient micro-aeration (aeration for 5 min every 12, 4 and 1 h). Hydrolysis was found to depend on the level of micro-aeration. Specifically, insufficient micro-aeration led to unstable and decreased performance. Conversely, sufficient micro-aeration promoted the hydrolysis of easily biodegradable carbohydrates and proteins, but the microbial activity was later impaired by liquid recirculation using methanogenic effluent. The hydrolysis efficiency under anaerobic conditions was comparable to the efficiency observed under sufficient micro-aeration, while the cumulative TOC of the anaerobic batch was 1.4–2.4 times higher than that of the micro-aerated batches. In addition, liquid recirculation did not have a negative effect on the development of microbial activity under anaerobic conditions, which resulted in the lignocelluloses having a higher hydrolysis efficiency. 相似文献
114.
115.
116.
利用刷涂法制备了Ti/SnO2-RuO2电极,并通过SEM、XRD等测试手段对其进行形貌及结构表征。利用该电极为阳极处理黑索金(RDX)废水,考察了电解质种类、电解质质量浓度、废水pH、电流密度以及电解时间等对RDX电催化氧化效果的影响。实验结果表明,当处理100 mL质量浓度为50 mg/L的RDX废水时,以Na2SO4为电解质、Na2SO4质量浓度为5.0 g/L、废水pH为7、电流密度为15 mA/cm2、电解时间为300 min的条件下,RDX去除率达到82.55%,COD去除率达到55.41%。 相似文献
117.
Evaluation of a classification method for biodegradable solid wastes using anaerobic degradation parameters 总被引:1,自引:0,他引:1
Wei Zheng Khamphe Phoungthong Fan Lü Li-Ming Shao Pin-Jing He 《Waste management (New York, N.Y.)》2013,33(12):2632-2640
We studied the biochemical and anaerobic degradation characteristics of 29 types of materials to evaluate the effects of a physical composition classification method for degradable solid waste on the computation of anaerobic degradation parameters, including the methane yield potential (L0), anaerobic decay rate (k), and carbon sequestration factor (CSF). Biochemical methane potential tests were conducted to determine the anaerobic degradation parameters of each material. The results indicated that the anaerobic degradation parameters of nut waste were quite different from those of other food waste and nut waste was classified separately. Paper was subdivided into two categories according to its lignin content: degradable paper with lignin content of <0.05 g g VS?1, and refractory paper with lignin content >0.15 g g VS?1. The L0, k, and CSF parameters of leaves, a type of garden waste, were similar to those of grass. This classification method for degradable solid waste may provide a theoretical basis that facilitates the more accurate calculation of anaerobic degradation parameters. 相似文献
118.
Pyrolysis has been examined as an attractive alternative to incineration for municipal solid waste (MSW) disposal that allows energy and resource recovery; however, it has seldom been applied independently with the output of pyrolysis products as end products. This review addresses the state-of-the-art of MSW pyrolysis in regards to its technologies and reactors, products and environmental impacts. In this review, first, the influence of important operating parameters such as final temperature, heating rate (HR) and residence time in the reaction zone on the pyrolysis behaviours and products is reviewed; then the pyrolysis technologies and reactors adopted in literatures and scale-up plants are evaluated. Third, the yields and main properties of the pyrolytic products from individual MSW components, refuse-derived fuel (RDF) made from MSW, and MSW are summarised. In the fourth section, in addition to emissions from pyrolysis processes, such as HCl, SO2 and NH3, contaminants in the products, including PCDD/F and heavy metals, are also reviewed, and available measures for improving the environmental impacts of pyrolysis are surveyed. It can be concluded that the single pyrolysis process is an effective waste-to-energy convertor but is not a guaranteed clean solution for MSW disposal. Based on this information, the prospects of applying pyrolysis technologies to dealing with MSW are evaluated and suggested. 相似文献
119.
120.
本文概述了在当前面临地震队伍结构调整和人员分流的新形势下,如何进一步深化改革,追踪地震研究的世界先进水平,筛选和确定地震科研的前沿课题,为制定地震工作的深化改革政策提供科学依据。通过对30年地震预报实践的反思,提出今后发展方向。 相似文献