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161.
Soares EV Soares HM 《Environmental science and pollution research international》2012,19(4):1066-1083
The release of heavy metals into the environment, mainly as a consequence of anthropogenic activities, constitutes a worldwide
environmental pollution problem. Unlike organic pollutants, heavy metals are not degraded and remain indefinitely in the ecosystem,
which poses a different kind of challenge for remediation. It seems that the “best treatment technologies” available may not
be completely effective for metal removal or can be expensive; therefore, new methodologies have been proposed for the detoxification
of metal-bearing wastewaters. The present work reviews and discusses the advantages of using brewing yeast cells of Saccharomyces cerevisiae in the detoxification of effluents containing heavy metals. The current knowledge of the mechanisms of metal removal by yeast
biomass is presented. The use of live or dead biomass and the influence of biomass inactivation on the metal accumulation
characteristics are outlined. The role of chemical speciation for predicting and optimising the efficiency of metal removal
is highlighted. The problem of biomass separation, after treatment of the effluents, and the use of flocculent characteristics,
as an alternative process of cell–liquid separation, are also discussed. The use of yeast cells in the treatment of real effluents
to bridge the gap between fundamental and applied studies is presented and updated. The convenient management of the contaminated
biomass and the advantages of the selective recovery of heavy metals in the development of a closed cycle without residues
(green technology) are critically reviewed. 相似文献
162.
Olof Regnell Mark Elert Lars Olof Höglund Anna Helena Falk Anders Svensson 《Ambio》2014,43(7):878-890
Methylation of mercury (Hg) to highly toxic methyl Hg (MeHg), a process known to occur when organic matter (OM) decomposition leads to anoxia, is considered a worldwide threat to aquatic ecosystems and human health. We measured temporal and spatial variations in sediment MeHg, total Hg (THg), and major elements in a freshwater lagoon in Sweden polluted with Hg-laden cellulose fibers. Fiber decomposition, confined to a narrow surface layer, resulted in loss of carbon (C), uptake of nitrogen (N), phosphorus (P), and sulfur (S), and increased MeHg levels. Notably, fiber decomposition and subsequent erosion of fiber residues will cause buried contaminants to gradually come closer to the sediment–water interface. At an adjacent site where decomposed fiber accumulated, there was a gain in C and a loss of S when MeHg increased. As evidenced by correlation patterns and vertical chemical profiles, reduced S may have fueled C-fixation and Hg methylation at this site. 相似文献
163.
Pasi Kaarakainen Helena Rintala Teija Meklin Päivi Kärkkäinen Anne Hyvärinen Aino Nevalainen 《Journal of the Air & Waste Management Association (1995)》2013,63(12):1382-1392
ABSTRACT Microbial particles can readily be released into the air from different types of man-made sources such as waste operations. Microbiological emissions from different biological sources and their dispersion may be an issue of concern for area planning and for nearby residents. This study was designed to determine the concentrations and diversity of microbiological emissions from four different man-made source environments: waste center with composting windrows, sewage treatment plant, farming environment, and cattle manure spreading. Samples of airborne particles were collected onto polyvinyl chloride filters at three distances along the prevailing downwind direction, from each source environment during a period of approximately 1 week. These samples were analyzed for 13 species or assay groups of fungi, bacterial genus Streptomyces, and Gram-positive and -negative bacteria using quantitative polymerase chain reaction (PCR). Samples for determining the concentrations of viable fungi and bacteria were collected from all environments using a six-stage impactor. The results show that there were variations in the microbial diversity between the source environments. Specifically, composting was a major source for the fungal genera Aspergillus and Penicillium, particularly for Aspergillus fumigatus, and for the bacterial genus Streptomyces. Although the microbial concentrations in the sewage treatment plant area were significantly higher than those at 50 or 200 m distance from the plant area, in the farming environment or cattle manure spreading area, no significant difference was observed between different distances from the source. In summary, elevated concentrations of microbes that differ from background can only be detected within a few hundred meters from the source. This finding, reported earlier for culturable bacteria and fungi, could thus be confirmed using molecular methods that cover both culturable and nonculturable microbial material.
IMPLICATIONS Concentrations and diversity of airborne microbes increase due to particle emissions from different biological waste treatment applications. However, these emissions cannot be separated from the background concentrations after more than a few hundred meters from the source. As part of a risk assessment, it may be necessary to confirm the behavior of microbial emissions from a specific source. Quantitative PCR is a useful tool for estimating total concentrations of different microbial species or groups as it detects both culturable and nonculturable microbial material. 相似文献
164.
Damásio JB Barata C Munné A Ginebreda A Guasch H Sabater S Caixach J Porte C 《Chemosphere》2007,66(7):1206-1216
Three biomarkers of hydrocarbon exposure, liver 7-ethoxyresourfin-O-deethylase activity (EROD), fluorescent hydrocarbon compounds (FACs) in bilis, and the liver antioxidant enzyme catalase (CAT) were examined in the autochthonous fish species Barbus meridionalis collected in the river Fluvià (NE Catalunya, Spain) after an oil spillage. Four different locations were sampled, including the impacted site, upstream and downstream sites and a reference site. Biomarker responses were compared with diatom and macroinvertebrate community assemblage metrics (Specific Pollution Sensitivity index - IPS, and Iberian Biological Monitoring Working Party - IBMWP, respectively). Chemical analyses denoted that polycyclic aromatic hydrocarbon levels in sediment were much higher at the impacted site than in downstream reaches. Four fold increase of EROD activity together with increased levels of biliary FACs in barbs collected at the spilled site indicated exposure of inhabiting fish to the oil. Additionally, CAT activity was significantly depressed (four fold) when compared to other stations, thus suggesting that fish collected from the impacted sites could be more susceptible to suffer oxidative stress. Biological indices (particularly that of the diatom community IPS) showed slight significant effects between control and impacted sites, indicating that more tolerant taxa were favoured because of the oil spillage. These results support the need to include biochemical responses measured in local species in monitoring programmes aimed to diagnose specific pollution effects in stressed river ecosystems. 相似文献
165.
Misík M Micieta K Solenská M Misíková K Pisarcíková H Knasmüller S 《Environmental pollution (Barking, Essex : 1987)》2007,145(2):459-466
Aim of the study was to monitor changes of genotoxic activity of urban air caused by an incinerator and a petrochemical plant in Tradescantia micronucleus (Trad-MCN) and pollen fertility assays with wild plants (Chelidonium majus, Clematis vitalba, Cichorium intybus, Linaria vulgaris, Robinia pseudoacacia). While in the first sampling period (1997-2000) significantly (on average 80%) more MN were found at the polluted site in comparison to controls from a rural area, no significant effects were observed during a later period (between 2003 and 2005). A similar pattern was observed in the pollen abortion assays in which the most pronounced effects were found in chicory and false acacia. The differences of the results obtained in the two periods can be explained by a substantial reduction of air pollution by use of new technologies. In particular the decrease of SO(2) emissions may account for the effects seen in the present study. 相似文献
166.
Block CN Shibata T Solo-Gabriele HM Townsend TG 《Environmental pollution (Barking, Essex : 1987)》2007,148(2):627-633
The objective of this study was to evaluate the performance of handheld XRF analyzers on wood that has been treated with a preservative containing arsenic. Experiments were designed to evaluate precision, detection limit, effective depth of analysis, and accuracy of the XRF arsenic readings. Results showed that the precision of the XRF improved with increased sample concentration and longer analysis times. Reported detection limits decreased with longer analysis times to values of less than 1mg/kg or 18 mg/kg, depending on the model used. The effective depth of analysis was within the top 1.2 cm and 2.0 cm of sample for wood containing natural gradients of chemical preservative and concentration extremes, respectively. XRF results were found to be 1.5-2.3 times higher than measurements from traditional laboratory analysis. Equations can be developed to convert XRF values to results which are consistent with traditional laboratory testing. 相似文献
167.
Seixas TG Kehrig Hdo A Costa M Fillmann G Di Beneditto AP Secchi ER Souza CM Malm O Moreira I 《Environmental pollution (Barking, Essex : 1987)》2008,154(1):98-106
Selenium and total and organic mercury were determined in the liver and kidney of franciscana dolphin (Pontoporia blainvillei) incidentally caught in fishing nets along two Brazilian coastal areas (southeast and south). Regional differences in the concentrations of these contaminants were observed in P. blainvillei. Liver showed the highest organic and total mercury. In general, samples of individuals collected at the southern of Brazil had the highest concentrations of selenium and total and organic mercury. No significant gender differences were observed. Growth stage influenced the accumulation of these contaminants in both organs, and hepatic concentrations increased with the body length, according to the sampling area. Molar mercury and selenium concentrations in liver were significantly correlated, with a Se:Hg ratio close to 4. The among-site differences we found may be related to differences in preferred prey, bioavailability in the marine environment, environmental conditions, or these individuals may belong to distinct populations. 相似文献
168.
169.
Agnieszka Guzman Helena Janik Alicja Kosakowska 《Journal of Polymers and the Environment》2010,18(4):679-684
Several new biodegradable polymer materials have recently come onto the global market. Mostly the results on degradation kinetic
studies are presented. This paper suggests using one of the tests to estimate the impact of polymer packaging material on
sea life. The microorganism chosen was Anabaena variabilis (identified in many waters, including those of the Baltic Sea, especially in the Gulf of Gdańsk and Puck Bay; this cyanobacterium
has a tendency to move with deep-sea waters causing algal blooms that upset the ecological balance of the marine environment
[1]). The chosen polymer materials were polycaprolactone modified with thermoplastic starch (PCL/TPS > 85%) or with calcium
carbonate (60% PCL/40% CaCO3). They were incubated in seawater in the presence of A. variabilis. The chlorophyll a content was determined as the criterion of cyanobacterial growth in the presence of the tested polymers. The polymer surface
and colour changes in the cyanobacterium culture were recorded photographically. The experimental results indicate that the
addition of polymer samples to the cyanobacterium culture affects its biological balance. During the experiment in seawater,
cyanobacteria adhered to the polymer surfaces and their growth was stimulated to different degree by the polymers. Thus, the
suggested test differentiate the behaviour of both materials studied. Cyanobacterial growth was lower in the presence of PCL
modified with calcium carbonate than in the presence PCL/TPS blend. 相似文献
170.
Naresh?KumarEmail author Daisy?Ramirez-Ortiz Helena?M.?Solo-Gabriele Joseph?B.?Treaster Olveen?Carrasquillo Michal?Toborek Sapna?Deo Jim?Klaus Leonidas?G.?Bachas David?Whitall Sylvia?Daunert Jose?Szapocznik 《Environmental science and pollution research international》2016,23(3):2003-2013
Guánica Bay, located in southwestern Puerto Rico, has suffered oil spills and other pollution discharges since the 1960s. Previous research showed elevated concentrations of polychlorinated biphenyls (PCBs) in coral reef and sediment. This research examined PCB concentrations in sediment and fish. Sediment and fish sampling in the bay was facilitated by community members. This study identified the second highest reported PCB level (129,300 ng/g) in sediment in the USA. Fish samples also showed elevated concentrations (1623 to 3768 ng/g), which were higher than the thresholds of safe levels of PCBs in fish for human consumption. The alarmingly high concentration of PCBs calls for proactive community engagement to bring awareness about contamination of the bay and more extensive sampling to test for the concentration of PCBs in seafood and the people of Guánica. This study also underscores the value of the involvement of local communities during sampling design aimed at identifying hot spots of contaminants. 相似文献