Concentrations and compositions of organochlorine contaminants in sediments, soils, crustaceans, fishes and birds collected from Lake Tai, Hangzhou Bay and Shanghai city region, China

Contamination by persistent organochlorines (OCs), such as DDTs, hexachlorocyclohexane isomers (HCHs), chlordane compounds (CHLs), hexachlorobenzene (HCB) and polychlorinated biphenyls (PCBs) were examined in sediments, soils, fishes, crustaceans, birds, and aquaculture feed from Lake Tai, Hangzhou Bay, and in the vicinity of Shanghai city in China during 2000 and 2001. OCs were detected in all samples analyzed, and DDT and its metabolites were the predominant contaminants in most sediments, soils and biota. Concentrations of p,p'-DDT and ratio of p,p'-DDT to SigmaDDTs were significantly higher in marine fishes than those in freshwater fishes. While the use of DDTs has been officially banned in China since 1983, these results indicate a recent input of technical DDTs into the marine environment around Hangzhou Bay. Comparison of organochlorine concentrations in fishes collected from Lake Tai and Hangzhou Bay suggests the presence of local sources of HCHs, chlordanes and PCBs at Lake Tai. Higher proportions of penta- and hexa-PCB congeners in fishes at Lake Tai may suggest the use of highly chlorinated PCB product, such as PCB(5), around this lake. To our knowledge, this is a first comprehensive study to examine the present status of organochlorine contamination in various environmental media, such as sediments, soils and wildlife, in China.     

Assessing high impacts of climate change: spatial characteristics and relationships of hydrological ecosystem services in northern Japan (Teshio River watershed)

Ecosystem services (ESs) provide information on the tendency of ecosystems to reach and form a state of equilibrium. The process of ES changes is important in order to identify the climate change-related causes that occur regionally to globally. ES-based management plays an important role in mitigation strategies for the negative impact of global climate change on ecosystem. Therefore, it is necessary to evaluate spatial characteristics and relationships among these multiple services from different spatial scales which could aid in multiple ES sustainable development from local to global scales. In this study, we developed a framework for analyzing the spatial characteristics and interactive relationships of multiple ESs. We analyzed the spatial distributions of six hydrological ESs that are important in the northernmost part of Japan (Teshio River watershed) by using hydrology and nutrient model (Soil and Water Assessment Tool, SWAT) under baseline climate conditions and climate change derived from the global circulation model (GCM). We then explored the spatial characteristic scales of ESs by multiscale analysis (lacunarity estimation) to reveal provision flow and spatial distribution characteristics for hydrological ESs. We observed a strong relationship between the spatial characteristics of land uses and ES provision. The spatial characteristics of individual hydrological ESs were totally different and had different spatial homogeneity and cluster (indicated by initial lacunarity index and lacunarity dimension). The results also showed trade-offs between inorganic nutrient retention (provision ESs) and organic nutrient and sediment retentions (regulating ESs), and synergies between organic nutrient retention and sediment retention under all climate change scenarios. The different stakeholders will take different mitigation programs (e.g., establishing riparian vegetation, planning nutrient management practices, and integrating climate change model into systematic conservation planning of ESs) to avoid negative impacts of climate change on ESs. Application of this proposed framework to study the spatial characteristics and relationships of hydrological ESs under climate change could provide understanding on the impact of climate change on ES changes and solutions to mitigate strategies to cope with those changes in the future.     

Biodegradation of synthetic surfactants by river microorganisms

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Photocatalytic oxidation and removal of arsenite from water using slag-iron oxide-TiO2 adsorbent

Photocatalytic oxidation of arsenite and simultaneous removal of the generated arsenate from aqueous solution were investigated. The whole process was performed using an adsorbent developed by loading iron oxide and TiO2 on municipal solid waste melted slag. The loading was carried out through chemical reactions and high-temperature process. In the removal process, arsenite was first oxidized to arsenate, and then was removed by adsorption. The oxidation of arsenite was rapid, but the adsorption of the generated arsenate was slow. A concentration of 100 mg l(-1) arsenite could be entirely oxidized to arsenate within 3 h in the presence of the adsorbent and under UV-light irradiation, but the equilibrium adsorption of the generated arsenate needed 10 h. Arsenite could also be oxidized to arsenate only by UV-light, but the reaction rate was approximately 1/3 of that of the photocatalyzed reaction. Both acidic and alkaline conditions were favorable for the oxidation reaction, and the optimum pH value for the oxidation and adsorption was proposed to be around 3. To oxidize and remove original 20 mg l(-1) or 50 mg l(-1) arsenite from aqueous solution, the necessary adsorbent amount was 2 g l(-1) or 5 g l(-1), respectively. Furthermore, the surface properties of the adsorbent were examined and the oxidation mechanism of arsenite was discussed. It is believed that the adsorbent developed in this study is efficient, cost-effective and environment-friendly for application in arsenic-contaminated wastewater treatment.     

Formation of dioxin analogs by open-air incineration of waste wood and by fire of buildings and houses concerning Hanshin Great Earthquake in Japan

Ash samples were collected from site of open-air incineration and fire concerning Hanshin Great Earthquake which occurred in western Japan in the early morning of 17 January 1995. The average concentrations of total sum of PCDDs, PCDFs and Co-PCBs in ash collected from wood scrap of broken building fire site, house fire site, shoe-making factory fire site and electric appliances store fire site were 541, 442, 859 and 22,800 pgTEQ/g, respectively. Particularly, PCDFs among dioxin analogs generated remarkably at sites with a high TEQ. In addition, 79,000 t of ash was totally produced at five open-air incineration sites, and consequently the formation amount of PCDDs, PCDFs and Co-PCBs was estimated to be 70.7 gTEQ on the basis of these analytical data.