Sorption of Perfluorooctane sulfonate（PFOS） including its isomers on hydrargillite as a function of pH,humic substances and Na2SO4

Perfluorooctane sulfonate（PFOS） is a persistent organic pollutant（POP） and emergent contaminant that are widespread in the environment. Understanding the mechanisms controlling the distribution of PFOS and its isomers between hydrargillite and the water phase is important in order to study their redistribution and mobility in the environment. This study investigated the effects of pH, humic acid, fulvic acid and Na₂SO₄ on sorption of PFOS isomers to hydrargillite. A mixture...     

Effects of exogenous acylated homoserine lactones on biofilms in biofilters for gaseous toluene treatment

● Biofilm formation was enhanced by exogenous AHLs. ● EPS production and microbial adhesive strength of biofilm were promoted. ● Exogenous AHLs improved the performance of biofilters treating toluene. Biofilters are typical biofilm reactors, and they usually have poor biofilm formation resulting in limited reactor performance. Exogenous acylated homoserine lactones (AHLs) can enhance biofilm formation in many bioreactors based on quorum sensing regulation. However, their effect on biofilm in biofilters utilized for volatile organic compound (VOC) removal is unknown and needs to be investigated. In this study, the effects of the exogenous AHLs on biofilters for gaseous toluene removal were investigated. Analysis of biofilms in biofilters showed that the addition of exogenous AHLs considerably enhanced biofilm growth; the average biofilm concentration increased by 18%. Furthermore, the average biofilm coverage proportions in biofilters with and without exogenous AHLs were 17 % and 13 %, respectively, demonstrating the positive effect of exogenous AHLs on biofilm coverage. In particular, exogenous AHLs promoted the production of extracellular polymeric substances and the microbial adhesive strength of the biofilm. In addition, the exogenous AHLs showed no significant effect on the gaseous toluene removal efficiency of the biofilter. These results show that exogenous AHLs can enhance biofilm formation and can guide the application of exogenous AHLs in VOC biofilters.     

Characteristics of fungal flora in onion farmlands with potential link to human mycotic keratitis

Acquisition of mycotic keratitis has been linked to agricultural activities. Although fungi were identified in injured eyes, data derived directly from farmlands are limited. Following five cases of fungal corneal ulcers in onion harvesters in the monsoon area of Taiwan, the present study further determined fungi genera and their concentrations in onion crops and surface soils of onion farmlands. In total, 52, 100 and 100 samples of soils, onion leaves and bulb scales, respectively, were collected from three monsoon and one non-monsoon farmlands. Fungal colonies were counted and microscopically examined after incubation at 25°C for 4–7 days on malt extract agar with 40?g?mL^?1 chloramphenicol. Results showed the peak fungi levels were mostly observed at harvest time. Among keratitis-related fungi, Aspergillus predominated in soils as well as in onion bulb scales, while Alternaria in onion leaves. Cladosporium was also prevalent in soils, onion leaves and scales. Other keratitis-related fungi included Acremonium, Curvalaria, Fusarium, Mycelia, Penicillium, Rhizoctonia and Rhizopus. The present study provides an exposure link between onion harvesters and presence of keratitis-related fungi from onion crops and soils, which may account for mycotic ocular infection via hand-to-eye contact and airborne transmission during the monsoon season.     

Effects of the Ellagic acid on the N‐Acetyltransferase activity and Acetylation of 2‐aminofluorene in the rat

The effects of the ellagic acid on the in vitro and in vivo acetylation of 2‐aminofluorene were investigated in male Sprague‐Dawley rats. For in vitro examination, cytosols with or without ellagic acid co‐treatment showed different percentage of 2‐aminofluorene acetylation. For in vivo examination, pre‐treatment of male rats with ellagic acid (10 mg/kg) 24h prior to the administration of 2‐aminofluorene (50 mg/kg) resulted in a 26% and 29%, respectively, decrease in the urinary and fecal recovery of N‐acetyl‐2‐aminofluorene, and a 37% decrease in the metabolic clearance of 2‐aminofluorene to N‐acetyl‐2‐aminofluorene. This is the first demonstration that ellagic acid decrease the N‐acetylation of carcinogens in vitro and in vivo.     

Urban planning and sustainable development under transitional economy: a case study of Guangzhou

There are always conflicts between the need for conservation and economic growth in the developing countries. Planning plays a primary role in balancing these conflicts. This is particularly obvious in Chinese cities since China adopted its open door policy in 1978. Foreign investment has been a major driving force for rapid growth of the Chinese economy. Planners in China have been facing the dilemma of protecting the natural environment on the one hand while, on the other hand, supporting the overall national goal of attracting foreign investment to maintain continuous economic growth. The planning system in China, which has been largely based on a planned economy, soon found itself handicapped in safeguarding the environment from rapid industrialization and urbanization fostered by market forces. This paper takes Guangzhou as an example to study challenges to the planning system in Chinese cities in the past two decades of rapid economic growth and urbanization. By means of a case study on an industrial development within a protected orchard area in Guangzhou, this study illustrates the conflict between the need for rural conservation and the pressure for economic development in the Chinese cities. In particular, it analyzes the pressures on the present urban planning system in China in terms of the following categories: the emergence of private investors in urban development; the goal of pursuing a high economic growth rate; the implications of a transitional economy for urban planning; and the weakness of the present urban planning system. It concludes that the role of urban planning in China should change from simply providing guidelines on board land-use strategy, to a combination of a strategic plan with specific development control laws at the operational level. Finally, some recommendations are suggested as to how to improve the planning system in China.     

Sustainable recycling model: A comparative analysis between India and Tanzania

Higher economic growth in developing countries has caused higher amounts of wastes. Local government authorities in these countries usually fail to provide adequate services to dispose the increasing amounts of waste, resulting in threats for both the population and environment health. There is therefore an urgent need for recycling as a form of waste management in order to stop the devastating effects of solid waste in developing countries. Using a qualitative method of analysis, this study presents a model to measure and rank the sustainability of recycling programs in India and Tanzania. The model consists of six main constructs including “production, economic, governmental, social, technological, and international factors”. The results showed that India outperforms Tanzania in sustainable recycling programs: per capita waste generated per day in Delhi is higher than in Dar es Salaam; the government of India focuses more on developing recycling plans and techniques as compared to the government of Tanzania where the country is not actively involved in the recycling process; and the solid waste management planning in India is being performed better than Tanzania.     

Benefits of Bt cotton counterbalanced by secondary pests? Perceptions of ecological change in China

In the past, scientific research has predicted a decrease in the effectiveness of Bt cotton due to the rise of secondary and other sucking pests. It is suspected that once the primary pest is brought under control, secondary pests have a chance to emerge due to the lower pesticide applications in Bt cotton cultivars. Studies on this phenomenon are scarce. This article furnishes empirical evidence that farmers in China perceive a substantial increase in secondary pests after the introduction of Bt cotton. The research is based on a survey of 1,000 randomly selected farm households in five provinces in China. We found that the reduction in pesticide use in Bt cotton cultivars is significantly lower than that reported in research elsewhere. This is consistent with the hypothesis suggested by recent studies that more pesticide sprayings are needed over time to control emerging secondary pests, such as aphids, spider mites, and lygus bugs. Apart from farmers?? perceptions of secondary pests, we also assessed their basic knowledge of Bt cotton and their perceptions of Bt cotton in terms of its strengths and shortcomings (e.g., effectiveness, productivity, price, and pesticide use) in comparison with non-transgenic cotton.     

Development of a Local-Scale Spatially Refined Multimedia Fate Model (LSRMFM) for Urban-Scale Risk Assessment: Model Formulation, GIS-Based Preprocessing, and Case Study

A local-scale spatially refined multimedia fate model (LSRMFM) was developed to evaluate in detail the multimedia transport of organic compounds at a spatial level. The model was derived using a combination of an advection?Cdispersion?Creaction partial differential equation, a steady-state multimedia fugacity model, and a geographical information system. The model was applied to predicting four major volatile organic compounds that are produced as emissions (benzene, toluene, xylene, and styrene) in an urban and industrial area (the 50?×?50-km area was divided into 0.5?×?0.5-km segments) in Korea. To test the accuracy of the model, the LSRMFM was used to predict the extent of dispersion and the data compared with actual measured concentrations and the results of a generic multimedia fate model (GMFM). The results indicated that the method developed herein is appropriate for predicting long-term multimedia pollution. However, the comparison study also illustrated that the developed model has some limitations (e.g., steady-state assumption) in terms of explaining all the observed concentrations, and additional verification and study (e.g., validation using a large observed data set, integration with a more accurate runoff model) would be desirable. In comparing LSRMFM and GMFM, discrepancies between the LSRMFM and GMFM outputs were found, as the result of geographical effects, even though the environmental parameters were identical. The geographical variation for LSRMFM output indicated the existence of considerable local human and ecological risks, whereas the GMFM output indicated less average risk. These results demonstrate that the model has the potential for improving the management of pollutant levels under these refined spatial conditions.     

STOCHASTIC WATER QUALITY ANALYSIS USING RELIABILITY METHOD1

ABSTRACT: This study developed a QUAL2E‐Reliability Analysis (QUAL2E‐RA) model for the stochastic water quality analysis of the downstream reach of the main Han River in Korea. The proposed model is based on the QUAL2E model and incorporates the Advanced First‐Order Second‐Moment (AFOSM) and Mean‐Value First‐Order Second‐Moment (MFOSM) methods. After the hydraulic characteristics from standard step method are identified, the optimal reaction coefficients are then estimated using the Broyden‐Fletcher‐Goldfarb‐Shanno (BFGS) method. Considering variations in river discharges, pollutant loads from tributaries, and reaction coefficients, the violation probabilities of existing water quality standards at several locations in the river were computed from the AFOSM and MFOSM methods, and the results were compared with those from the Monte Carlo method. The statistics of the three uncertainty analysis methods show that the outputs from the AFOSM and MFOSM methods are similar to those from the Monte Carlo method. From a practical model selection perspective, the MFOSM method is more attractive in terms of its computational simplicity and execution time.     

Bioabsorbable Soy Protein Plastic Composites: Effect of Polyphosphate Fillers on Biodegradability

The use of biodegradable polymers made from renewable agricultural products such as soy protein isolate has been limited by the tendency of these materials to absorb moisture. A straightforward approach for controlling the inherent water absorbency of the biodegradable polymers involves blending special bioabsorbable polyphosphate fillers, biodegradable soy protein isolate, plasticizer, and adhesion promoter in a high-shear mixer followed by compression molding. The procedure yields a relatively water-resistant, biodegradable soy protein polymer composite, as previously reported. The aim of the present study is to determine the biodegradability of the new polyphosphate filler/soy protein plastic composites by monitoring the carbon dioxide released over a period of 120 days. The results suggest that the composites biodegrade satisfactorily, with the fillers having no significant effect on the depolymerization and mineralization of the soy protein plastic, processes that would otherwise result in nonbiodegradable composites. Further, the results indicate that the biodegradation and useful service life of these biocomposites may be controlled by changing the filler concentration, making the biocomposites useful in applications in which the control of water resistance and biodegradation is critical.