Advances In Out Door Lysimeter Techniques

Different methods exist for measuring soil water and solute fluxes in and below the root zone and have been critically reviewed. Besides indirect methods (e.g. water balance, tensiometer, time domain reflectometry – TDR, frequency domain reflectometry – FDR, environmental tracer) direct methods (e.g. drainage-type lysimeter, water fluxmeter) have a long tradition and have been successfully used in seepage research. A large weighable out door lysimeter is the best method for obtaining reliable data about seepage water quantity and quality, but it involves significant investment and additional expenses for maintenance. To tackle this problem new methods for the vertical collection of large volume soil monoliths (up to 6 m³) as well as for the horizontal collection (up to 6 m³) have been developed. For the placement of the lysimeter a container lysimeter unit was constructed, which is cheaper than a conventional steel or concrete cellar. Furthermore, the technical design of the newly developed lysimeter types as a weighable gravitation lysimeter, a weighable groundwater lysimeter and a lateral flow lysimeter are presented.     

Environmental risks of farmed and barren alkaline coal ash landfills in Tuzla, Bosnia and Herzegovina

The disposal of coal combustion residues (CCR) has led to a significant consumption of land in the West Balkan region. In Tuzla (Bosnia and Herzegovina) we studied previously soil-covered (farmed) and barren CCR landfills including management practises, field ageing of CCR and the transfer of trace elements into crops, wild plants and wastewaters. Soil tillage resulted in mixing of cover soil with CCR. Medicago sativa showed very low Cu:Mo ratios (1.25) which may cause hypocuprosis in ruminants. Total loads of inorganic pollutants in the CCR transport water, but not pH ( approximately 12), were below regulatory limits of most EU countries. Arsenic concentrations in CCR transport water were <2microgl(-1) whereas reductive conditions in an abandoned landfill significantly enhanced concentrations in leachates (44microgl(-1)). The opposite pattern was found for Cr likely due to large initial leaching of CrVI. Public use of landfills, including farming, should be based on a prior risk assessment due to the heterogeneity of CCR.     

Measurements of dissolved methylmercury in natural waters using diffusive gradients in thin film (DGT)

A diffusive gradient in thin films (DGT) technique for measuring methylmercury (MeHg) concentrations in natural waters was developed using 3-mercaptopropyl-functionalized silica gel to preconcentrate the methylmercury. The new resin was characterized and calibrated. Methylmercury is efficiently accumulated at a pH range of 3-9. Basic performance tests of the new DGT device confirmed the applicability of Fick's first law for such DGT measurements. The diffusion coefficient of methylmercury in polyacrylamide gel was 5 x 10(-6) cm(2) s(-1). Methylmercury concentrations determined by DGT deployed for different time periods in the field are statistically not different from results obtained through direct measurements. The DGT technique represents therefore an alternative in situ sampling method for methylmercury. The detection limit of the overall method is 1 pg of MeHg, which correspond to approximately 30 pg L(-1) of MeHg in a water sample, when deploying a typical DGT device for 24 hours. Lower MeHg concentrations are measurable using longer deployment times or thinner diffusive gel layers.     

Deposition Loads of Sulphur and Nitrogen in Germany

High spatial resolution maps of deposition loads in Germanyare produced as an input for abatement strategy research andfor critical loads exceedance calculations on a nationalscale. In this paper methods ofmapping total deposition loads in Germany and preliminarymaps of nitrogen and sulphur deposition loads for the year1993 are presented. A comparison of these mapping resultswith EMEP deposition mapping results has been carried out.The differences in the results of the German national and theEuropean EMEP mapping, due to different databases anddifferent methods, are quantified and discussed. Highresolution maps of deposition loads are compared to Europeanlow resolution maps on the same temporal and spatial scale,assuming that on average both should lead to similar results.However, the average differencescalculated for 23 EMEP 150 × 150 km² grid cells over Germanywere found to be 33% higher for sulphur (S) total depositionby the German method 65% higher for S dry deposition and1% lower for S wet deposition. The German results fornitrogen (N) total deposition are 2% higher than the EMEPresult 22% higher for N dry deposition and 10% lower for Nwet deposition.     

Critical Loads Exceedances in Germany and their Dependence on the Scale of Input Data

Critical load exceedances have been used as an effects-related parameter for guiding international air emission control negotiations. High-resolution critical load data are combined with low-resolution deposition data.This article shows that doing so systematicallyunderestimates `true' critical load exceedances as obtainedfrom combining critical load and deposition data of identicalhigh spatial resolution. 95th percentile critical loadexceedances in EMEP grids based on high resolution depositiondata are 60 and 150% higher (mean values for nutrientnitrogen and acidity, respectively) than critical loadexceedances based on the low resolution EMEP depositionmodel. The latter are used in international negotiations. Differences in individual EMEP grid squares vary betweeninsignificantly different from zero and 340%, depending onregional deposition and critical load characteristics andcritical load types (nutrient nitrogen versus acidity).Exceedances based on high-resolution deposition values arealso compared to EMEP grid averages of these values forforests only. This comparison excludes the effect ofsystematically higher depositions to forests. Still, thescale difference of (averaged, low-resolution) deposition and(high-resolution) critical loads data yields underestimatesof the 95th percentiles by on average ca. 20%.These systematic errors due to the scale dependence should beborne in mind when interpreting effects of internationalemission control measures.     

Historical development and future outlook of the flood damage potential of residential areas in the Alpine Lech Valley (Austria) between 1971 and 2030

In the recent past, the Alpine Lech valley (Austria) experienced three damaging flood events within 6 years despite the various structural flood protection measures in place. For an improved flood risk management, the analysis of flood damage potentials is a crucial component. Since the expansion of built-up areas and their associated values is seen as one of the main drivers of rising flood losses, the goal of this study is to analyze the spatial development of the assets at risk, particularly of residential areas, due to land use changes over a historic period (since 1971) and up to possible shifts in future (until 2030). The analysis revealed that the alpine study area was faced to remarkable land use changes like urbanization and the decline of agriculturally used grassland areas. Although the major agglomeration of residential areas inside the flood plains took place before 1971, a steady growth of values at risk can still be observed until now. Even for the future, the trend is ongoing, but depends very much on the assumed land use scenario and the underlying land use policy. Between 1971 and 2006, the annual growth rate of the damage potential of residential areas amounted to 1.1 % (‘constant values,’ i.e., asset values at constant prices of reference year 2006) or 3.0 % (‘adjusted values,’ i.e., asset values adjusted by GDP increase at constant prices of reference year 2006) for three flood scenarios. For the projected time span between 2006 and 2030, a further annual increase by 1.0 % (‘constant values’) or even 4.2 % (‘adjusted values’) may be possible when the most extreme urbanization scenario ‘Overall Growth’ is considered. Although socio-economic development is regarded as the main driver for increasing flood losses, our analysis shows that settlement development does not preferably take place within flood prone areas.     

Brood defense and age of young: a test of the vulnerability hypothesis

Summary In many altricial species including the great tit (Parus major) the intensity of brood defense against predators has been shown to increase with the age of the offspring. This effect has been ascribed amongst others to the young becoming more vulnerable as they age (vulnerability hypothesis). In a great tit population suffering heavy losses from brood depredation by the great spotted woodpecker (Dendrocopus major), we rendered first and second broods more vulnerable by artificially enlarging the entrance of the nest hole. Contrary to the vulnerability hypothesis, 16 experimental pairs defended their brood against a dummy great spotted woodpecker less vigorously than did 16 control pairs. Nest concealment behavior potentially compromising active defense was minimized by simultaneous playback of nestling distress calls, thus simulating the act of nest predation. This leaves the brood value hypothesis as an alternative functional explanation of the defense level — age effect. It predicts that parents should defend their brood in proportion to the reproductive value (or some more suitable cohortal equivalent measure) of their offspring. At present, this explanation pertains to one predator species. In first broods, but not in second broods, males defended them more vigorously than did their females. While this parallels previous experiments on brood defense against predators posing a much greater risk to the parents, two functional explanations previously put forward can hardly apply.