生物填料地下渗滤系统对生活污水的脱氮

将草甸棕壤、炉渣和活性污泥等基质按体积比13∶6∶1配制生物填料,研究了生物填料地下渗滤系统（subsurface wastewater infiltration system,SWIS）在不同的水力负荷和污染负荷条件下对校园生活污水的脱氮效果。场地实验结果表明,当BOD5负荷为12.0 g BOD5/（m2·d）,表面水力负荷为0.04-0.10 m3/（m2·d）时,SWIS对NH＋4-N和TN的平均去除率分别为92.4%和82.0%。当水力负荷为0.08 m3/（m2·d）,BOD5负荷9.3-16.8 g BOD5/（m2·d）时,SWIS对NH＋4-N和TN的平均去除率为92.7%和81.2%。SWIS中氧化还原电位（oxygen reduction potential,ORP）随进水水力负荷和BOD5负荷的增加而降低,脱氮效率下降。综合出水水质和处理效率,适宜的水力负荷和污染负荷分别为0.065 m3/（m2·d）和12.0 g BOD5/（m2·d）。在此条件下,SWIS的启动周期为25-30 d。出水水质均优于《城市污水再生利用-景观环境用水水质》（GB/T18921-2002）标准,且处理效果稳定,抗负荷冲击能力强。     

改性膨润土作为垃圾渗透液防渗层的实验研究

本文以天然钠基膨润土为原料,采用水溶液聚合法,在室温条件下,通过改性聚丙烯酰胺对膨润土进行直接插层改性,制备了一种新型聚丙烯酰胺改性膨润土防渗材料。以此防渗材料作为防渗层,选用沈阳大辛填埋场的垃圾渗透液为处理对象,在动态实验下,就其对实际垃圾渗滤液中主要污染物去除的有效性和控制垃圾渗滤液渗透的可行性进行研究。抗渗性能测试结果表明,改性膨润土防渗性能较好,渗透系数为1．0×10^-7cm/s,达到固体废物填埋场的防渗材料国家标准1．0×10^-7cm／s的使用要求。改性膨润土防渗层对COD、氨氮、重金属离子去除效果较好,吸附作用较强,COD和氨氮最大去除率分别达到81％和91％,TFe、Zn^2＋和TCr的最大去除率分别达到71％、58％和73％。实验结果验证了本研究所制备的改性膨润土防渗材料具有优良的抗渗、截污性能。     

Source identification and characterization of the accumulating non-biodegradable organics in Korean reservoirs

An increase in the chemical oxygen demand (COD) has been noticed in most Korean reservoirs. Therefore, this research systematically investigated the causes of organic accumulation. Samples of soil affecting the quality of water of reservoirs were collected at various sources and analyzed for their organic characteristics. The COD to biochemical oxygen demand (BOD) ratio was used as the key parameter in the evaluation of non-biodegradable (NBD) organic accumulation in the reservoirs. Soil samples containing plant roots were agitated, with the supernatant showing COD/BOD ratios of less than 2.8, while those of the composted tree leaves were greater than 5.0, suggesting that humic substances produced in forest areas are a major cause of NBD organic accumulation in reservoirs. In addition, the organic fractionation of the leachate from leaching tests showed that of the various types of hydrophobic natural organic matter (NOM), the larger molecular weight humic acid makes a greater contribution than fulvic acid to the increase in the NBD COD in Korean reservoirs.     

信息共享平台在环境管理中的支撑作用

建立环境信息共享平台,使环境管理数据实现共享,实现各类数据及时的关联,是环境管理工作发展的必然趋势,将为环境管理提供强有力的技术支撑.信息共享平台利用了大型数据库在性能、安全性、可靠性、数据一致性、分布式处理等方面的优势,将各主要环境业务部门的统计、收费、审批、监测等数据集中管理起来,数据管理人员、各级领导、业务部门员工通过统一的Web界面进行管理、查询分析大量的环境数据,从而简化环境数据管理的难度,提高环境数据管理的水平,大大方便用户对环保数据的访问,提高了数据利用效率.     

高职教育考试方法改革的探索与实践

根据高职教育教学的要求和课程特点,尤其是为适应培养应用型人才的教学模式,打破“高分低能”的现象,充分发挥考试在高职教育中的指导性作用,本文以食品质量与安全专业的课程为例,对考试考核方法的改革进行了探索与实践。高职教育的考试应突出应用能力考核,加强实践技能检验,坚持在实践中学习、在实践中考核,全面推行操作技能考核,施行“考教分离”,考试形式多样化的原则。     

Distribution characteristics of nonylphenolic chemicals in Masan Bay environments, Korea

To understand the distribution characteristics of nonylphenolics and sterols, samples such as in creek water, sea surface water, waste water treatment plant (WWTP) effluent water, sediment and mussel were collected and analyzed. The principal analytes are nonylphenol (NP), nonylphenol monoethoxylate (NP1EO), nonylphenol diethoxylate (NP2EO), coprostanol (5beta) and cholestanol (5alpha). All these target pollutants showed 100% detection frequency in all of the samples analyzed. Total concentration of nonylphenolic compounds ranged from 334 to 3628ngl(-1) (average: 1331ngl(-1)) in creek water, from 15 to 36400ngl(-1) (average: 1013ngl(-1)) in sea surface water, from 131 to 2811ngg(-1) dry weight (average: 581ngg(-1) dry weight) in sediment and from 50.5 to 289ngg(-1) dry weight (average: 139ngg(-1) dry weight) in mussel. For water samples, levels of nonylphenolics determined in summer season were higher than those in spring season. Among them, nonylphenol and NP1EO was dominant in creek water and seawater, respectively. The highest concentration was recorded in sediment near a WWTP effluent outlet. And high levels of nonylphenolics and sterols were found in about 3km area surrounding WWTP effluent outlet. Coefficient of linear regression (R(2)) for NP in mussel and in sediment was 0.90. Similarly good correlation (R(2)=0.98) was obtained between concentration in water and in mussel indicating that a steady state has been reached in this bay. The calculated bio concentration factor (BCF=2990) for NP in Masan Bay agrees well with reported values in the literature.     

Sorption of polar and nonpolar organic contaminants by oil-contaminated soil

Sorption of nonpolar (phenanthrene and butylate) and polar (atrazine and diuron) organic chemicals to oil-contaminated soil was examined to investigate oil effects on sorption of organic chemicals and to derive oil–water distribution coefficients (K_oil). The resulting oil-contaminated soil–water distribution coefficients (K_d) for phenanthrene demonstrated sorption-enhancing effects at both lower and higher oil concentrations (C_oil) but sorption-reducing (competitive) effects at intermediate C_oil (approximately 1 g kg⁻¹). Rationalization of the different dominant effects was attempted in terms of the relative aliphatic carbon content which determines the accessibility of the aromatic cores to phenanthrene. Little or no competitive effect occurred for butylate because its sorption was dominated by partitioning. For atrazine and diuron, the changes in K_d at C_oil above approximately 1 g kg⁻¹ were negligible, indicating that the presently investigated oil has little or no effect on the two tested compounds even though the polarity of the oil is much less than soil organic matter (SOM). Therefore, specific interactions with the active groups (aromatic and polar domains) are dominantly responsible for the sorption of polar sorbates, and thus their sorption is controlled by available sorption sites. This study showed that the oil has the potential to be a dominant sorptive phase for nonpolar pollutants when compared to SOM, but hardly so for polar compounds. The results may aid in a better understanding of the role of the aliphatic and aromatic domains in sorption of nonpolar and polar organic pollutants.     

江苏省危险化学品生产状况调查分析及监管对策

根据《危险化学品名录》,分析江苏省取得危险化学品安全生产许可证的1774家企业的化学品种类、数量、生产企业类型分布情况.结果表明,江苏省危险化学品生产企业在地域分布上苏南多于苏北;化工、建材行业的危险化学品生产企业所占比例较高;危险化学品涉及除爆炸品外的6大类,达3 790种,以生产易燃液体的企业数目为最多;有31家企业生产10种以上危险化学品.笔者建议,通过评估摸清企业安全生产状况,严格控制危险化学品企业安全生产许可证发放,实现危险化学品运输企业的动态管理,建立安全监测预警技术平台.     

平行钢丝吊索强度安全性分析与评估

评估不同断丝数目时吊索的安全性能.在对某大跨径钢管混凝土拱桥三维有限元实体模型仿真分析的基础上,以拉索在恒载及汽车活载作用下的拉力安全系数为拉索失效判据,建立拉索失效功能函数.确定拉索失效功能函数中各参数的概率分布,采用Matlab计算软件生成各参数的随机样本,进而通过编程实现功能函数的计算机求解.采用Monte-Carlo法(蒙特卡洛法)评估吊索在不同损伤程度时的强度安全概率,计算各工况下吊索强度可靠性指标值并推导出吊索失效的临界断丝数.结果表明,吊索失效概率随断丝数的增加而急剧增大,吊索强度安全可靠性指标值随断丝数的增加近似呈线性衰减趋势.确定吊索失效的临界断丝数对吊索宏观检查和评估具有较大的工程实用价值.     

ABR反应器的启动研究

研究了添加填料对折流式厌氧反应器(ABR)启动性能的影响.反应器启动时,控制COD负荷为0.15 kg/(m3*d),逐渐提升至0.6 kg/(m3*d).未加填料的反应器经过约60 d,加入填料的反应器经过约35 d的连续运行,出水COD去除率稳定,启动基本完成.研究表明,添加填料的复合式反应器启动速度明显快于普通ABR,且运行稳定性更好,COD去除率较高,能够较好地截留污泥,有利于反应器生物效应的形成.