不同预处理对电镀污泥电动过程的影响

以风干电镀污泥为电动处理试验材料,水为阳极电解液,柠檬酸柠檬酸铵缓冲液为阴极电解液,施加25 V直流电压条件下电动运行5 d,研究了水、低浓度木钙和硝酸等预处理对电镀污泥电动过程的影响。结果表明,各处理的阴极电解液pH值变化平稳,都维持在3～3.5较理想的范围。而1％木钙、1％硝酸饱和预处理电镀污泥,明显改变了电动过程中电渗流和电流密度的大小,对电镀污泥Cu、Ni的去除率也有明显增加。其中,木钙、硝酸预处理后对Cu的去除率由对照的13.24％分别提高到19.05％和25.55％,即去除量分别增大3 516.35 mg/kg和7 457.62 mg/kg;木钙、硝酸预处理后对Ni的去除率由对照的14.68％分别提高到16.47％和28.85％,即去除量分别增大800.91 mg/kg和6 359.92 mg/kg。     

硅酸盐和磷酸盐矿物对土壤重金属化学固定的研究进展

根据重金属离子的迁移转化规律,可以采用物理、化学、生物等方法来治理土壤的重金属污染,每种修复方法都有其优缺点,而环境矿物法具有成本低廉和效率较高的特点,因此,本文叙述了两种具有代表性的环境矿物(硅酸盐和磷酸盐),从硅酸盐和磷酸盐矿物的性能、反应机理以及对土壤重金属离子的作用效果等方面综述了硅酸盐和磷酸盐修复重金属污染土壤的研究进展,并且阐述了硅酸盐和磷酸盐对不同重金属离子的作用效果,以及影响其作用的各种因素,提出了其中存在的问题和不足。     

以第二方审核促进承包商自主HSE管理

分析了承包商HSE监督管理方面存在的不足,提出第二方审核作为监督管理的延伸和补充,在促进承包商自主管理、自我提升和培养长期合作承包商的作用和意义,指出针对不同类型承包商开展第二方审核的实施重点。     

Resolving Trade and Environment Conflicts： A Focus on Sustainable Trade in China

This paper begins by analysing the mutual influence between international trade and the environment, and then proceeds to explore the environment and trade conflicts. On the basis of sustainable development theories and the above discussion, the article suggests taking sustainable trade as a solution to the existing conflicts. This paper aims to find the way to strike a balance between international trade and environment based on the present situation in China.     

就森林资源谈林副产品加工专业的发展前景

本文通过对国内外森林资源利用概况及我校林副产品加工专业的现状分析,阐述了该专业的发展前景。     

TiO2/Schwertmannite nanocomposites as superior co-catalysts in heterogeneous photo-Fenton process

The heterogeneous photo-Fenton reaction is an effective technique in combating organic contaminants for both soil and water remediation,and extensive studies have focused on enhancing its efficiency and reducing its costs.In this work,we developed novel photoFenton catalysts by simply milling commercially available TiO_2(P25)with Schwertmannite(Sh),a natural iron-oxyhydroxysulfate nanomineral.We expect that the photo-generated electrons from TiO_2could continuously migrate to Sh,which then could enhance the separation of electron-hole pairs on TiO_2and accelerate the reduction of Fe(III)to Fe(II)on Sh,leading to high degradation efficiency of the target organic contaminants.SEM and TEM results showed the distribution of TiO_2on Sh surface for the nanocomposites(TiO_2/Sh).Under simulated sunlight irradiation,the much higher content of Fe(II)was determined on TiO_2/Sh than on Sh via a common method in the iron ore,and the consumption of H_2O_2and the production of·OH were more significant in the TiO_2/Sh system than those in the TiO_2and Sh systems.These results well support our hypothesis that the photo-generated electrons could migrate from TiO_2to Sh on the composites,and can also explain the much higher degradation efficiency of Rhodamine B(RhB)in the TiO_2/Sh system.Besides,TiO_2/Sh had lower Fe dissolution as compared with Sh,and retained high catalytic stability after four repeated cycles.Above merits of the TiO_2/Sh composites,in combining with their simple synthesis method and low-cost property,indicated that they should have promising applications as heterogeneous photo-Fenton catalysts.     

Mercury accumulation and dynamics in montane forests along an elevation gradient in Southwest China

Understanding atmospheric mercury (Hg) accumulation in remote montane forests is critical to assess the Hg ecological risk to wildlife and human health. To quantify impacts of vegetation, climatic and topographic factors on Hg accumulation in montane forests, we assessed the Hg distribution and stoichiometric relations among Hg, carbon (C), and nitrogen (N) in four forest types along the elevation of Mt. Gongga. Our results show that Hg concentration in plant tissues follows the descending order of litter > leaf, bark > root > branch > bole wood, indicating the importance of atmospheric Hg uptake by foliage for Hg accumulation in plants. The foliar Hg/C (from 237.0 ± 171.4 to 56.8 ± 27.7 µg/kg) and Hg/N (from 7.5 ± 3.9 to 2.5 ± 1.2 mg/kg) both decrease along the elevation. These elevation gradients are caused by the heterogeneity of vegetation uptake of atmospheric Hg and the variation of atmospheric Hg° concentrations at different altitudes. Organic soil Hg accumulation is controlled by forest types, topographic and climatic factors, with the highest concentration in the mixed forest (244.9 ± 55.7 µg/kg) and the lowest value in the alpine forest (151.9 ± 44.5 µg/kg). Further analysis suggests that soil Hg is positively correlated to C (r² = 0.66) and N (r² = 0.57), and Hg/C and Hg/N both increase with the soil depth. These stoichiometric relations highlight the combined effects from environmental and climatic factors which mediating legacy Hg accumulation and selective Hg absorption during processes of organic soil mineralization.     

A survey on heavy metal concentrations in residential neighborhoods: The influence of secondary water supply systems

Water quality deterioration often occurs in secondary water supply systems (SWSSs), and increased heavy metal concentrations can be a serious problem. In this survey, twelve residential neighborhoods were selected to investigate the influence of SWSSs on the seasonal changes in heavy metal concentrations from input water to tank and tap water. The concentrations of nine evaluated heavy metals in all groups of water samples were found to be far below the specified standard levels in China. The concentrations of Fe, Mn, and Zn increased significantly from the input water samples to the tank and tap water samples in spring and summer (p < 0.05), especially for the water samples that had been stagnant for a long time. Negative correlations were found between most of the heavy metals and residual chlorine (Fe, Cu, Zn, and As, r = -0.186 to -0.519, p < 0.05). In particular, a high negative correlation was observed between Fe and residual chlorine (r = -0.489 to -0.519, p < 0.01) in spring and summer. Fe and Mn displayed positive correlations with turbidity (r = 0.672 and 0.328, respectively; p < 0.05). In addition, Cr and As were found to be positively associated with some nutrients (NO₃⁻, TN, and SO₄²⁻; r = 0.420-0.786, p < 0.01). The material of the storage tanks had little influence on the difference in heavy metal concentrations. Overall, this survey illustrated that SWSSs may pose a chronic threat to water quality and could provide useful information for practitioners.     

A novel speed model for safety evaluation of freeway alignment in Euclidean 3D space

Objective: Operating speed is a critical indicator to evaluate consistency of road alignment and safety. Although extensive studies have been conducted on developing operating speed models, few researchers have considered the interactive influence of horizontal and vertical alignment in 3D space. The purpose of this study is to develop a speed model based on 3D alignment in Euclidean space rather than traditional horizontal and vertical alignment.

Methods: According to the curve theory of differential geometry, a novel method to estimate operating speed is proposed in our study using 3D space curvature instead of traditional horizontal or vertical parameters to describe the spatial geometric properties for a freeway alignment. Speeds of 54 different alignment segments are observed to develop the speed model. Several observing sites of each segment are selected beforehand, and the speeds of more than 300 vehicles in each site are observed. Space curvature is used as an important index to estimate operating speed.

Results: The findings of this study indicated that both horizontal alignment and vertical alignment contribute to space curvature. Space curvature mainly affects direction control operating performance. However, vehicles overcome the effects of gravity along the vertical alignment in the z direction. Results indicate that operating speed exponentially declines with space curvature and that quadratic parabola decline with vertical grade.

Conclusions: It can be concluded that there is a clear correlation between velocity and spatial curvature, which is proved by variance analysis. The estimation results of the speed models are reliable as tested using a real engineering example. The study would provide a scientific basis for safety evaluation of freeway alignment.