K2Cr2O7溶液同时脱硫脱硝实验研究

采用K2Cr2O7溶液作为吸收液,在自制的鼓泡反应器内,对模拟烟气进行同时脱硫脱硝的实验研究,考察多种因素对SO2脱除率(即脱硫率)和NO脱除率(即脱硝率)的影响。实验结果表明:K2Cr2O7浓度、反应温度、NO浓度、SO2浓度、烟气流量对脱硫率、脱硝率影响显著;当烟气流量为0.4L/min,气相中O2体积分数为6%,SO2体积分数为0.09%,NO体积分数为0.100%,K2Cr2O7摩尔浓度为10mmol/L,反应温度为40℃时,脱硫率、脱硝率分别达到100%和64.3%。     

巴东官渡汇流口网箱养鱼对附近水域水质的影响

对巴东官渡汇流口网箱养殖区进行了现场调查和实验室分析,结果显示其水质变化规律为网箱养殖区劣于控制断面区域,控制断面劣于背景和削减断面,同一断面水质基本相同,控制断面水质由网箱向外逐渐变好。主成分分析表明,不同养殖区对水体污染影响依次为：中华鲟养殖区>鸭嘴鲟养殖区>黄颡鱼养殖区>鲤鱼、草鱼混养区。各水质指标相关性分析表明,官渡Chla与总磷和氨氮高度相关;氨氮、总氮、总磷和高锰酸盐指数4个指标明显相关,说明其污染源具有同源性,该水域污染主要受到网箱养殖的影响。以超河流背景断面浓度5％作为划定超背景污染带的标准,网箱养鱼引起的氨氮超背景污染面积最大,约为网箱面积的10倍,高锰酸盐指数超背景污染面积最小,约为网箱面积的5倍     

塔里木油田钻井废物处理技术研究

为实现钻井废物随钻即时处理,采用钻井废物处理技术。研究对钻井废物实验取样,将废物分离成岩屑、泥饼和水,对泥浆中的固体通过水洗、絮凝分离和化学反应处理,泥浆中的有害物质成分和氯离子被析出后,再用真空吸附脱水制成泥饼,同时将水循环利用。根据实验数据对本底值以及处理前后的数据进行对比分析,验证了该技术在塔里木油田的适用性。     

兽药抗生素潜在生态效应及其环境行为

在集约化畜禽养殖过程中,兽药抗生素被广泛地作为饲料添加剂,用于预防和治疗动物疾病以及促进动物生长。本文介绍了兽药抗生素在国内外的发展形势及其随着畜禽粪便排出体外的抗生素在环境中的残留和生态效应。最后,论述了兽药抗生素在环境中的行为特征,并重点介绍了在土壤中的降解行为和吸附解吸特征。     

旅游综合体开发——一种旅游房地产全新开发模式研究

随着产业结构升级,旅游结构从原有的单一旅游经济模式向多元化的、集合式的、综合性的旅游模式发展,产生了以旅游资源与土地为基础,以旅游休闲功能为主导,结合大型旅游休闲项目、高品质服务的配套设施、互动发展的休闲旅游地产等多功能的、集合式的土地利用模式及产业聚集模式。在观察和归纳大量这类开发实例的基础上定义了旅游综合体开发这一房地产全新开发模式的概念,分析了该模式的表现特征,总结性地提出开发的理论模式及应用模式,并在此基础上归纳出开发的战略措施。     

旅游概念规划内容体系创新研究——以重庆市璧山千亩荷园乡村旅游概念规划为例

在界定旅游概念规划的基础上,对其内容体系进行了研究,创新性地提出了一种新的旅游概念规划内容体系,即它由背景环境解析、理念融合创新、目标定位、发展战略确定、关键策略选择五大板块组成,内容涉及到发展背景认知、区域特征分析、特殊理念识别、特有思想梳理、关键概念提取、规划目标界定、发展战略选择、主题形象提升、空间构架部署、概念分区支撑、意象设计解码、发展模式生成、旅游策略选择等13个方面,并以《重庆市千亩荷园旅游概念规划》为例,在理论和实证双重层面上证实了这套新内容体系的实践价值和存在意义.     

Persistent organic pollutants in food items collected in Hong Kong

This study aims to investigate levels of POPs in meat, edible oils, nuts, milk and wine collected from Hong Kong. Naphthalene, pp-DDE, beta-, gamma-HCH and PBDE 47 were detected in most of the food items. Goose liver accumulated the highest PAHs (47.9 ng g⁻¹ wet wt), DDTs (25.6), HCHs (13.0), PCBs (4.17), PBDEs (468 pg g⁻¹ wet wt) among all the selected food. Meat and nut groups had significant (p < 0.01 or 0.05) correlations between lipid contents and concentrations of PAHs (meat: r = 0.878), HCHs (meat: r = 0.753), DDTs (meat: r = 0.937; nuts: r = 0.968) and PCBs (meat: r = 0.832; nut: r = 0.946). The concentrations of DDTs, HCHs and PCBs in vegetable oil were lower, but HCHs in fish oil were higher, when compared with other countries. The concentrations of PAHs, DDTs, PCBs and PBDEs in food tested in the present study were all below various safety guidelines.     

Effects of hydrodynamics on the distribution of trace persistent organic pollutants and macrobenthic communities in Bohai Bay

In recent years, the rapid economic development along Bohai Bay, has brought out continuous increasing of the pollution loads in the Bohai Sea, especially by the large coastal reclamation project, Tianjin Binhai New Area. In the period of 2007-2009, we collected the sediments of the main rivers, estuaries, intertidal zone, and near-shore area of Bohai Bay, and Macrobenthos associated with the marine sediments to assess the influence of hydrodynamics in the coastal environment on the pattern of trace contaminants and the macrobenthic community. Based on data derived from these samples, the levels of polycyclic aromatic hydrocarbons (PAHs), organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs) in sediments followed the order PAHs > OCPs > PCBs > PBDEs. The higher concentrations of PCBs, OCPs, PAHs and PBDEs were found in the estuarine and near-shore environment of the Dagu Drainage River. The spatial distribution of OCPs was different to that of PCBs due to the direction of the velocity field of Bohai Bay in its old and new topography, and the higher water-solubility of OCPs than that of PCBs. The results of the Pearson correlation and the PCA indicate that the medium diameter (MD) of sediments was the predominant factor influencing the distribution of PCBs and OCPs, most sampling sites were characterized mainly by TOC of sediments and biomass of macrobenthos. The results indicate that the distribution of trace contaminants and macrobenthic community in Bohai Bay are mainly affected by the hydrodynamic conditions.     

Na2S·HNO3改性活性炭对水中低浓度Pb2+吸附性能的研究

采用回流蒸煮、微波焙烧的方法改性活性炭,通过Boehm滴定法、TG和FT-IR分析了改性前后活性炭表面官能团的变化情况.Boehm滴定表明:改性活性炭的总酸度、羧基、内酯基皆有增加;TG曲线中的多个失重峰说明了改性活性炭表面含氧基团的增加;FT-IR谱图上500～720 cm-1范围内新峰的出现说明了改性活性炭表面增加...     

H2O和SO2对V2O5-WO3/TiO2催化剂催化氧化NO的影响

研究了在120℃的反应温度下,H2O和SO2对V2O5-WO3TiO2催化剂选择性催化氧化(SCO)NO的影响.结果表明,在H2O和SO2存在的情况下催化剂失活很快,停止通入H2O和SO2后活性不能恢复,但在加热到250℃后催化活性基本恢复.FT-IR分析表明,催化剂表面形成了金属硝酸盐和Ti的硫酸盐,对催化活性有一定...