CF-TiO2的制备及其在模拟太阳光下的光催化性能

以十六烷基三甲基溴化铵(CTAB)和氟化钠分别为碳源和氟源,采用溶胶-凝胶法制备了CF-TiO2光催化剂,并对其进行了SEM、XRD、N2吸附、XPS、UV-visDRS和PL表征。研究了CF-TiO2在模拟太阳光下光催化降解亚甲基蓝溶液的活性,并讨论了氟掺杂量以及CTAB加入量对催化性能的影响。结果表明,CF-TiO2为锐钛矿型,孔结构丰富、比表面积大,氟碳共掺后使TiO2光催化剂的禁带宽度变窄为2.40 eV,在可见光区吸收增强,有效提高TiO2在模拟太阳光下的光催化活性,而且当n(F/Ti)(氟钛摩尔比)为0.1,加入碳源CTAB量为2 g时,其光催化活性最好。     

硫酸钙晶须对磷的静态吸附

以磷石膏废渣为原料制备硫酸钙晶须,考察了硫酸钙晶须对模拟含磷废水中磷的去除效果,分析了初始废水pH、初始磷质量浓度、硫酸钙晶须加入量对磷吸附效果的影响,研究了硫酸钙晶须对磷的吸附等温线,同时对吸附机理进行了探讨。实验结果表明：硫酸钙晶须在碱性条件下对磷的去除率较酸性条件下高,且初始废水pH为10时去除效果最佳;最佳硫酸钙晶须加入量为0.03 g/mg（以磷计）;在初始废水pH为10、初始磷质量浓度为50 mg/L、硫酸钙晶须加入量为1.5 g/L的条件下,于25 ℃下反应1 h,磷的去除率达到99.16%,上清液TP为0.419 mg/L;与Freundlich模型相比,Langmuir等温吸附模型更适合描述硫酸钙晶须对磷的吸附过程,采用该模型拟合得出25 ℃下磷的饱和吸附量为140.4 mg/g。     

Anatomical and physiological responses of Colorado blue spruce to vehicle exhausts

In order to examine whether the leaves of the Colorado blue spruce (Picea pungens) are damaged or not by traffic pollution, the traits of the anatomy and physiology of its leaves are investigated by exposure to vehicle exhausts in a laboratory experiment lasting 30 days. The results show that both the anatomical structures and physiological traits of the leaves are significantly affected by vehicle exhausts. The anatomical structures, including epidermis, cuticle, palisade, and spongy parenchyma are modified when exposed to the high concentrations (≥0.4 mg/m³) of vehicle exhausts. However, physiological traits such as total chlorophyll content are not changed when exposed to different concentrations of vehicle exhaust. Unlike the total chlorophyll content, the electrical conductivities increased, whereas the POD activities decreased when presented in vehicle exhausts. The present study indicates that the Colorado blue spruce changes its anatomical structures and physiological traits to avoid possible damage by vehicle exhausts.     

Three major nucleolar proteins migrate from nucleolus to nucleoplasm and cytoplasm in root tip cells of Vicia faba L. exposed to aluminum

Results from our previous investigation indicated that Al could affect the nucleolus and induce extrusion of silver-staining nucleolar particles containing argyrophilic proteins from the nucleolus into the cytoplasm in root tip cells of Vicia faba L. So far, the nucleolar proteins involved have not been identified. It is well known that nucleophosmin (B23), nucleolin (C23), and fibrillarin are three major and multifunctional nucleolar proteins. Therefore, effects of Al on B23, C23, and fibrillarin in root tip cells of V. faba exposed to 100 μM Al for 48 h were observed and analyzed using indirect immunofluorescence microscopy and Western blotting. The results from this work demonstrated that after 100 μM of Al treatment for 48 h, B23 and C23 migrated from the nucleolus to the cytoplasm and fibrillarin from the nucleolus to the nucleoplasm. In some cells, fibrillarin was present only in the cytoplasm. Western blotting data revealed higher expression of the three major nucleolar proteins in Al-treated roots compared with the control and that the B23 content increased markedly. These findings confirmed our previous observations.     

多效膜蒸馏技术浓缩回收废水中的二甲基亚砜

利用具有内部潜热回收功能的气隙式多效膜蒸馏(MEMD)组件对含二甲基亚砜(DMSO)的化纤废水进行了浓缩回收研究,考察了料液中DMSO浓度、进料流量、进料温度和膜侧进口温度对膜通量、造水比、分离因子和回收率的影响。结果表明,多效膜蒸馏可以将DMSO废水浓缩至200~300 g/L;初始浓度为6.2 g/L时,造水比和分离因子最高值分别为12.4和76.0;虽然膜通量、造水比和分离因子均随料液浓度增大而下降,但是当DMSO浓度达到200 g/L时,膜通量、造水比、分离因子仍分别高达3.74 L/(m2·h)、7.1、32.1;在整个浓缩过程中,回收率维持在99.6%以上;当DMSO废水浓缩达到150 g/L以上时,含有少量DMSO的渗透液可作为二次料液继续用MEMD过程浓缩。膜组件在连续运行的1个月内保持了良好的操作性能。该实验研究表明,多效膜蒸馏过程可以高效节能地浓缩回收化纤废水中的DMSO。     

基于ASAR GM数据时序特征的农田表层土壤水分的反演

了解农田表层土壤水分的时空变化对反演涝渍害有着十分重要的意义, 针对ASAR GM数据特点提出了在没有地面观测数据地区农田大尺度土壤水分的反演方法,即运用MODIS NDVI数据（空间分辨率为250 m）的农田作物时序特征提取土地利用现状,并以此来校正ASAR GM数据（空间分辨率为1 km）中的混合像素;利用大面积降水后土壤表层湿度水平差异不大的特点,运用非线性回归模型,获取水云模型中的经验系数,运用水云模型将植被和土壤对后向散射的贡献区分开;在获得一个地方长时间土壤后向散射系数空间分布集后,假设其土壤粗糙度不变的情况下,其后向散射系数与土壤表层湿度成正比,运用其时序特征计算出其土壤表层相对体积含水量。运用上述方法,利用79景ASAR GM数据和同时期的MODIS数据,反演了湖北省四湖地区棉田的土壤表层相对体积含水量的时空分布,将其计算值与观测值比较分析后发现,其变化趋势相同、相关系数（R2=0779,n=25）也很高,圴方根误差为963%,表明上述反演方法还是可行了,适用于大尺度农田土壤墒情的反演     

堑秋湖渔业模式对鄱阳湖南矶湿地越冬候鸟种群数量的影响和保育对策

鄱阳湖是我国最大的淡水湖、国际重要湿地。“堑秋湖”是当地老百姓根据鄱阳湖夏涨秋落的规律,在湖底低洼处堑壕沟、围矮堤,以便在秋季退水时截留更多的鱼和水,最后将鱼类资源一网打尽的渔业方式;也是长江流域中下游湖区以及鄱阳湖流域老百姓利用季节性浅水蝶形湖泊中渔业资源最主要的捕鱼和管理方式。采用PRA方法对江西鄱阳湖南矶湿地国家级自然保护区“堑秋湖”历史及现状进行问卷调查,采用样线样点结合方法对越冬候鸟种群数量进行调查分析。研究表明：鄱阳湖南矶湿地国家级自然保护区拥有蝶形湖泊26个,均已承包给个人管理并存在养鱼虾蟹等行为,为典型的“堑秋湖”渔业模式;不同月份越冬候鸟数量变化呈“M”型,不同样线候鸟数量差异较大,而候鸟种类在月份和样线方面差异不大;“堑秋湖”渔业模式对鄱阳湖越冬候鸟的种群数量、分布及栖息地生态功能的发挥存在明显正负面影响。对于建立经济社会可持续发展的“堑秋湖”经营模式进行了探讨,提出了有利于越冬候鸟栖息的保育对策     

Knowledge-based system,equipped with cluster analysis for eco-material selection: an automobile structure case study

The aim of this study is to develop a material selection framework structured around a knowledge-based system (KBS). Specifically, a hybrid data mining technique is employed to extract knowledge from large datasets using cluster analysis techniques; the mined knowledge then serves as the inference logic within the KBS designed for material selection purposes. Cluster analysis results are used as a basis for the tree-based structure of the KBS where if–then rules are developed based on the general cluster properties; that is, inference logic is structured in a way such that it can predict general sustainability characteristics of the material as well as its exact mechanical, cost and physical properties. To develop the structure of the KBS, the selection structure employs sustainable material indices. Additionally, the proposed material selection model of the KBS is purposefully composed of material sustainability, functionality and cost indices. The constructed knowledge is then demonstrated for selecting automobile structural panels.     

NaOH预处理对杂交狼尾草厌氧发酵产沼气的影响

研究了Na OH预处理对杂交狼尾草厌氧消化制沼气的影响。采用质量分数分别为0%、2%、4%、6%和8%的Na OH溶液对杂交狼尾草进行碱预处理,在中温(35℃)、TS质量分数6%、接种率20%及初始p H为7.0条件下,进行厌氧发酵实验。对比了处理前后原料木质纤维素含量,探讨了不同浓度预处理对发酵过程沼气产量、甲烷浓度、p H以及产气速率的影响。结果表明,Na OH预处理有助于提高杂交狼尾草厌氧发酵的产气量和产气速率,其中4%Na OH预处理为较优条件。经4%Na OH溶液常温浸润24 h后,杂交狼尾草木质素降解率最大,比未处理实验组提高了31.2%;厌氧发酵总产气量比未处理实验组提高了31.6%。     

改性木屑对水中Cr(Ⅵ)的吸附性能

在木屑上接枝季氨基团制备了改性木屑,并用傅里叶红外光谱(FT-IR)对其进行了表征。通过静态实验研究了改性木屑对水溶液中六价铬Cr(Ⅵ)的吸附特性,并探讨了温度、p H、多组分共存离子等对Cr(Ⅵ)吸附效果的影响。结果表明,在30℃时,改性木屑对Cr(Ⅵ)的饱和吸附容量为218.33 mg/g,吸附规律符合Langmuir等温方程式。在p H为3~10时,改性木屑对Cr(Ⅵ)均有显著的吸附效能,吸附过程符合准二级动力学方程,反应活化能为21.71 k J/mol,对吸附热力学参数△G0、△H0和△S0的计算表明,吸附过程是吸热的自发过程。多组分干扰离子共存时,对Cr(Ⅵ)的吸附影响不大。