生物质转化能源技术的发展现状及趋势探讨

能源短缺问题已成为制约经济社会发展的瓶颈,研究开发新的能源代替传统不可再生能源成为急需要解决的焦点问题。生物质能是由植物的光合作用固定于地球上的太阳能,通过生物质能转换技术可以高效地利用生物质能源,生产各种清洁燃料,替代煤炭、石油和天然气等燃料。对近些年生物质能源技术的发展现状进行了简要讨论,指出了生物质能的利用具有广阔的发展前景,在不久的将来,生物质能源必将成为能源结构中重要一部分,实现能源结构良好可持续发展。     

生物法在炼化污水深度处理中的应用

目前,国内炼化企业大多采用“隔油-浮选-生化”的“老三套”工艺处理污水,二级出水中仍含有较多的COD、氨氮、有毒物质、悬浮物质等,直接排放会给水体自净过程增加负担,造成水体富营养化等问题;若回用于工艺,则会造成堵塞系统,腐蚀设备等问题。因此国家制定了GB8978—1996污水综合排放标准。为满足新的排放标准,结合国内外发展现状,介绍了几种常用的生物深度处理技术,作为选择相关污水达标排放及回用处理方法的参考。     

硫酸粘菌素对土壤反硝化细菌nirS、nosZ基因多样性的影响

建立室内的土壤硫酸粘菌素暴露胁迫模型,采用末端限制性片段长度多态性分析(terminal restriction fragment length polymorphism,T-RFLP)技术分析不同浓度硫酸粘菌素残留对土壤反硝化细菌的影响。结果表明,每个处理组nirS、nosZ基因的分类操作单元(Operational Taxonomic Units,OTU)总数均比对照组低,且nirS基因呈现剂量依赖效应;各组优势细菌nirS基因主要集中在10个片段中,nosZ基因主要集中在18个片段中,nirS基因较nosZ基因丰度变化大;多样性指数分析表明,nirS基因Shannon指数在7 d时,高浓度组较对照组差异显著(P0.05); Simpson指数在各浓度处理组较对照组差异均显著(P0.05); Pielou指数在7 d、49 d时,高浓度处理组与对照组差异显著(P0.05); nosZ基因Shannon指数在35 d时,中浓度组与对照组差异显著(P0.05); 49 d时,低浓度组与对照组差异显著(P0.05); Simpson指数在21 d、35 d时,低浓度组与对照组差异显著(P0.05); Pielou指数在各处理组之间差异均不显著(P0.05)。当药物含量≥5 mg·kg~(-1)时,反硝化细菌的均匀度、群落多样性降低,优势度升高,群落结构特征均发生改变,其中对nirS基因影响显著。nirS基因更适合作为硫酸粘菌素污染的指示基因。     

Estimating the removal of atmospheric particulate pollution by the urban tree canopy in Beijing北大核心CSCD

Urban green space, particularly the tree canopy, plays an important role in potential mitigation against atmospheric particulate pollution and protecting human health. In this study, current and future air particulate matter [including total suspended particulate (TSP), particulate matter 10 (PM10), and particulate matter 2.5 (PM2.5)] removal by the urban tree canopy of Beijing was estimated. A modeling approach was used based on the distributed measurement evaluation and a modified version. The urban tree canopy of Beijing, including mostly Platycladus sp., Pinus sp., Quercus sp., Robinia pseudoacacia, and economic forests, currently removes about 8.33 million kg/a air particulates, in which TSP accounted for 4.51 million kg/a, PM10 accounted for 2.74 million kg/a, and PM2.5 accounted for 1.08 million kg/a. The study on the removal of air particulates by different aged tree canopies showed that in coniferous trees, the ability to capture air particulates changed in the order of mature and over-mature > near-mature forest > young forest; in broadleaf forest, the ability changed in the order of near-mature forest > mature and over-mature > young forest. For total particulate matter, the biggest contribution was coarse particulates (60.74%); the contribution rate of fine particulates was different owing to different tree species groups. The results suggested that the ability of different trees to capture particles and age of forests varied widely and that suitable trees should be chosen to enhance pollution mitigation for city greening. © 2018 Science Press. All rights reserved.     

Insight into the promotion mechanism of activated carbon on the monolithic honeycomb red mud catalyst for selective catalytic reduction of NOx

• Activated carbon was proposed to be an efficient accelerant for molded red mud catalyst. • The surface acidity and reducibility were highly improved, as well as the pore structure. • The enrichment of the surface Fe²⁺ and the adsorbed oxygen account for the improvement. Our previous study proved that the acid-pretreatment process could efficiently activate red mud (RM) for the selective catalytic reduction (SCR) of NO_x. However, in terms of the molding process, which is the key step determining whether it can be applied in large-scale industrial, the surface acidity and reducibility of catalyst always decreased dramatically, and part of surface area and pore structure were lost. In this study, we prepared monolithic honeycomb red mud (MHRM) catalysts with activated carbon (AC) as an accelerant and investigated the effect of AC on the MHRM. The results showed that the MHRM with 3 wt.% of AC (MHRM-AC3) exhibited the best SCR performance, and kept more than 80% NO_x conversion in the range of 325°C–400°C. Compared with the MHRM, MHRM-AC1, and HMRM-AC5, the MHRM-AC3 has more mesoporous and macroporous structures, which can provide more adsorption active sites. The AC significantly improved NH₃ adsorption and surface reducibility, which was mainly due to the increase of the surface acid sites (especially the Brönsted acid sites), the concentration of Fe(II), and the surface adsorbed oxygen. The presence of more Fe(II) enriched the surface oxygen vacancies, as well as the surface adsorbed oxygen, due to the charge imbalance and unsaturated chemical bond. And surface adsorbed oxygen exhibited more active than lattice oxygen owing to its higher mobility, which was conducive to NO_x reduction in the SCR reaction.     

反渗透处理糖厂二效汽凝水回用锅炉的研究

糖厂以二效汽凝水取代原水回用锅炉是"节能减排"的重要措施,但含糖量过高的二效汽凝水回用锅炉后,将影响锅炉高效、安全使用。故此采用一级反渗透装置对二效汽凝水进行除糖净化处理。实验结果表明:反渗透系统的脱盐率能够稳定在87.82%左右,出水水质完全达到中压锅炉补充给水水质标准。建议拥有中压锅炉的糖厂采用糖厂锅炉补充给水除糖净化新工艺。     

Fenton氧化处理对土壤中芘的生物可利用性的影响

研究发现蚯蚓吸收土壤中污染物芘的速率很快,10 d后蚯蚓体内富集污染物浓度基本达到稳定态;土壤中的有机质是影响污染物迁移的重要因素,土壤有机质的含量越高对芘滞留(吸附)能力越强,蚯蚓富集芘的量越低,蚯蚓富集到体内污染物的浓度越低.这也说明土壤对污染物的吸附/解吸行为决定了土壤中污染物的生态风险;氧化处理降低了土壤中的有机质含量,改变土壤有机质的组成,氧化处理也降低了土壤中被吸附污染物芘对蚯蚓的生物有效性.     

Impact of product heterogeneity and soft budget constraint on excess capacity in Chinese energy industry based on the duopoly model

Chinese energy industries are facing serious problems such as excess capacity, homogeneous product, and soft budget constraint. This paper provides a duopoly model to investigate the influence of heterogeneity and soft budget constraint on production capacity decision and internal action mechanism, respectively, under Cournot and Bertrand competitions, which reveals the formation mechanism of excess capacity. We conclude that excess capacity would exist when the products are not wholly heterogeneous under Cournot competition, and the higher level of the soft budget constraint or the more homogeneous the products are, the worse the excess capacity will be. The insufficient capacity would exist provided that products are not wholly heterogeneous under Bertrand competition, and the higher level of soft budget constraint or the more homogeneous the products are, the more insufficient capacity will be. Both soft budget constraint and product heterogeneity mutually affect to decision-making of capacity and output.     

掺粉煤灰和二灰上海软土的力学特性∗

粉煤灰和二灰(粉煤灰与石灰的混合料)均为改良软土地基的添加材料。以掺粉煤灰和二灰的上海软土为研究对象,进行次固结试验和直剪试验,研究了掺入率和养护龄期对掺粉煤灰和二灰上海软土的次固结特性和强度特性的影响。次固结试验结果表明,掺粉煤灰和二灰上海软土的次固结系数随着粉煤灰和二灰掺入量的增加而大幅减小,且在相同掺入率条件下,二灰的掺入对其次固结系数影响较大。直剪试验结果表明,粉煤灰和二灰的掺入均能提高上海软土的抗剪强度,与纯上海软土相比,其抗剪强度随着养护龄期的增长而显著增大,最后均会在某一养护龄期趋于稳定。掺粉煤灰的上海软土抗剪强度随粉煤灰掺入率基本成线性增长,最佳养护龄期建议为56 d,二灰的掺入率在10%即可有效提高上海软土的抗剪强度,其最佳养护龄期建议为28 d。上述试验结论可为科学和经济的处理软土地基提供参考。     

电动力学技术去除剩余污泥中铜、锌条件优化

电动力学去除剩余污泥中重金属受到多种因素的影响,其中电解电压、电极面积、电极材料等都有较大的影响,很有必要进行条件优化研究。针对存在的问题,系统的研究了电解电压、电极面积、电极材料对电动力学修复过程的影响。研究表明,影响污泥中重金属Cu和Zn去除率的因素大小顺序为:电压电极面积电极材料;采用等于或低于氢析出电压进行电动力学修复时,更有利于提高污泥中重金属去除率;增大电极面积,提高了电流强度,有利于污泥中重金属的转化、迁移,从而提高污泥中重金属去除率;研究表明,采用低于氢析出电压和惰性电极可以有效避免电极被腐蚀。