全文获取类型
收费全文 | 3604篇 |
免费 | 202篇 |
国内免费 | 960篇 |
专业分类
安全科学 | 334篇 |
废物处理 | 162篇 |
环保管理 | 290篇 |
综合类 | 1983篇 |
基础理论 | 593篇 |
污染及防治 | 862篇 |
评价与监测 | 150篇 |
社会与环境 | 210篇 |
灾害及防治 | 182篇 |
出版年
2024年 | 1篇 |
2023年 | 38篇 |
2022年 | 137篇 |
2021年 | 131篇 |
2020年 | 123篇 |
2019年 | 118篇 |
2018年 | 134篇 |
2017年 | 139篇 |
2016年 | 140篇 |
2015年 | 200篇 |
2014年 | 235篇 |
2013年 | 304篇 |
2012年 | 236篇 |
2011年 | 296篇 |
2010年 | 228篇 |
2009年 | 218篇 |
2008年 | 256篇 |
2007年 | 268篇 |
2006年 | 220篇 |
2005年 | 190篇 |
2004年 | 140篇 |
2003年 | 167篇 |
2002年 | 160篇 |
2001年 | 129篇 |
2000年 | 117篇 |
1999年 | 86篇 |
1998年 | 60篇 |
1997年 | 74篇 |
1996年 | 44篇 |
1995年 | 44篇 |
1994年 | 36篇 |
1993年 | 34篇 |
1992年 | 22篇 |
1991年 | 12篇 |
1990年 | 10篇 |
1989年 | 5篇 |
1988年 | 9篇 |
1987年 | 3篇 |
1983年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有4766条查询结果,搜索用时 203 毫秒
421.
采集了4个市售飞灰螯合剂样品,分析其在20,40℃下挥发性污染物的释放规律.结果表明,释放的挥发性污染物主要有甲醛、乙醛、苯、异戊醛/异丙醇、甲硫醇、乙硫醇等;其中3个螯合剂样品甲醛的释放浓度在20℃为748~1325 μg/L-螯合剂,占释放的易挥发污染物的68%~96%(质量比),在40℃为4282~6822 μg/L-螯合剂,占释放的易挥发污染物的87%~95%(质量比).随着温度升高,释放的挥发性污染物种类变多,部分污染物浓度增加,40℃时,4个螯合剂样品释放的易挥发污染物浓度比20℃时增加了142%~444%.元素分析、拉曼光谱和热重分析结果表明,4个螯合剂的主要有效成分相似,为二硫代氨基甲酸盐类物质.因此,推测这种飞灰螯合剂在稀释和飞灰稳定化过程中,对工作人员的健康可能有潜在的危害风险,应收集释放的气体并进行处理;且在飞灰填埋过程中,可能会导致渗滤液中NH4+-N等物质的浓度升高,增加渗滤液的处理难度. 相似文献
422.
跟踪拍照识别白鱀豚的研究 总被引:1,自引:0,他引:1
作者从1986年起开展了照相识别白豚的研究。通过反复试验,采用多船弧形跟踪、单船切入拍照的方法,在观察到白豚的48天中,共拍得1600张照片并从中识别出10头白暨豚。除了白暨豚背鳍上的自然标记能有效地用于个体识别之外,豚体上的色斑、图象等亦能用于个体识别。作者由此获得了白豚群体组成变化和迁移距离等科学资料,对深入研究白暨豚生态学有重要意义。 相似文献
423.
Nitrobenzene is an important raw material and product,which presents a heavy threat to the ecosystem.The potential impacts of nitrobenzene on sediment oxygen demand (SOD) were studied in lake sediment ... 相似文献
424.
425.
426.
427.
以云南荞麦地流域为研究区域,对该区域2017年24个地下水样品中5种重金属指标(Cr、Pb、Co、Mn、Hg)和1种无机毒理指标(氟化物)进行测定和分析,并基于半方差模型等地学统计方法,对地下水健康风险评价进行空间分析.结果表明:地下水通过饮水途径所引起的成人和儿童的健康风险分别为9.27×10-10~4.59×10-5a-1和1.10×10-8~5.46×10-4a-1.地下水健康风险评价值以Cr为主导,成人与儿童存在较高的一致性.地下水健康风险存在很强的空间规律性,在南北方向上呈条带状分布.受位于中游的药山镇影响,研究区南部下游地区地下水健康风险显著增加. 相似文献
428.
为研究铀矿区周边水体中典型放射性核素分布特征及其潜在的健康风险,对该地区周边浅层地下水及河水中放射性活度浓度进行分析测定.运用改进内梅罗综合污染指数法和健康风险评价模型对放射性污染及不同年龄段人群健康风险进行评估.结果表明,地下水与河水中放射性核素238U、226Ra、232Th活度浓度(地下水:0.012~0.102,0.013~0.036,0.002~0.033Bq/L,河水:0.001~0.066,0.013~0.034,0.001~0.013Bq/L)均未超过WHO饮用水水质准则规定的标准限值,但远远高于江西省水体背景值.河水中各核素活度浓度随水流流向呈递减趋势,地下水中各核素空间分布无明显规律性特征.河水中综合污染指数高于地下水,最高值分别为9.21和6.83,属严重污染和中度污染.健康风险评价结果表明,幼儿和少儿致癌风险要高于成人,幼儿终身致癌风险均超过ICRP最大可接受风险值5.0×10-5,少儿和成年超标率为33.3%和16.7%,即使未超标但也高于USEPA推荐可忽略风险水平10-6,具有潜在致癌风险.各核素致癌风险水平呈现为226Ra > 232Th > 238U,因而对于铀矿区周边饮用水中226Ra和232Th要更加重视研究. 相似文献
429.
Pathogenic viruses in drinking water are great threats to public health. Visible-light-driven photocatalysis is a promising technology for virus inactivation. However, the existing photocatalytic antiviral research studies have mostly been carried out in single-component systems, neglecting the effect of natural organic matter, which exists widely in actual water bodies. In this paper, electrospun Cu-TiO2 nanofibers were prepared as photocatalysts, and their photocatalytic antiviral performance in the presence of humic acid (HA) was comprehensively studied for the first time. The properties of the reaction mixture were measured during the reaction. In addition, the safety, reliability and stability of photocatalytic disinfection in the mixed system were evaluated. The results showed that the virus removal efficiency decreased with the increase of the HA concentration. The type of reaction solution, such as PBS buffer solution or water, did not affect the removal efficiency noticeably. Under acidic conditions, the electrostatic forces between photocatalysts and viruses were strengthened, leading to higher virus removal efficiency. As the reaction time went on, the pH value in the solution increased first and then tended to be stable, the conductivity remained stable, and the dissolved oxygen increased first and then decreased. The safety test showed that the concentration of Cu ions released into the solution was lower than specified by the international standards. No photoreactivation was observed, and the addition of HA significantly reduced the reutilization efficiency of the photocatalysts. 相似文献
430.
Polymer hydrogel-based materials have been shown to act as novel Fenton catalysts for water treatment, but the rational design of hydrogel-based catalysts with good stability has been a great challenge. To increase the stability and activity of polymer-based Fenton catalysts, uniform urchin-like α-Fe_2O_3 was grown in situ in a PVA carrier matrix here. PVA molecules promoted the growth of urchin-like α-Fe_2O_3, and then the PVA hydrogel acted as a barrier and carrier to reduce agglomeration. Through coordination by hydroxyl groups,PVA had good combination with Fe ions and α-Fe_2O_3. The formation of Fe–O–C bonds between iron oxides and polymers was reported for the first time, enhancing the material stability during catalysis. Under higher PVA concentrations, the resulting composite hydrogel could generate more ˙OH due to the increase in the number of active sites because of the hairy urchin-like structure. In tetracycline degradation through a heterogeneous Fenton reaction, the resulting material had good catalytic activity from pH 2 to pH 10 with low iron leaching, good reusability and remained at a level of nearly 90%after five consecutive cycles. Density functional theory calculations were used to further prove the mechanism of structural change of the iron oxides. The HOMO and LUMO energies of the iron oxides changed from 5.428 and 4.899 eV to 5.926 and 5.310 eV,indicating that the presence of PVA could influence the charge of the iron atom. The results provide new insights into the preparation of polymer hydrogel-based heterogeneous Fenton catalysts with enhanced stability for water treatment. 相似文献