电絮凝-H2O2氧化法处理邻苯二甲酸二甲酯废水的机理研究

采用电絮凝—H2O2氧化法处理邻苯二甲酸二甲酯(DMP)废水,利用多种分析手段对处理过程进行跟踪。实验结果表明整个处理过程可以分为两个阶段:当反应时间为0～8h时,以电Fenton氧化反应为主,产生的羟基自由基有效地降解了反应液中的DMP;当反应8h后,以絮凝作用和气浮作用为主。在氧化过程中,DMP中的甲基先被氧化生成邻苯二甲酸,苯环被开环并生成链状低级烃类,最后这些有机小分子几乎完全被矿化为CO2和H2O。     

固定化白腐真菌反应器与接触氧化反应器联用处理癸二酸生产废水

采用固定化白腐真菌(WRF)反应器与接触氧化反应器联用处理癸二酸废水。在WRF反应器中,以汽曝玉米秸秆为载体,并添加铜、铁促进白腐真菌生长和产酶作用,载体的使用寿命约为45 d。在进水苯酚平均质量浓度为69.36 mg/L、平均进水COD为1 648.81 mg/L的条件下,经WRF反应器处理后,苯酚平均质量浓度降至7.59 mg/L,平均出水COD降至478.03 mg/L;再经接触氧化反应器处理后,苯酚平均质量浓度降至1.65 mg/L,平均出水COD降至297.31 mg/L。     

化工园区空气中非甲烷总烃与挥发性有机物的定量关系

采用美国环保署(EPA)推荐的TO14/15方法和自动监测测定了某化工园区空气中挥发性有机物(VOC)以及非甲烷总烃,测定结果显示化工园区空气中非甲烷总烃与VOC的定量关系可以通过有效碳质量浓度建立,即非甲烷总烃有效碳质量浓度和VOC有效碳质量浓度之和相等。并藉此定义总有效碳解析度(R)以表征空气自动监测选定项目对空气有机污染的覆盖率指标,计算结果表明该空气自动监测选定的11项指标平均可表征该区域空气有机污染的71%。     

Influence of coal particles on methane/air mixture ignition in a heated environment

The temperature at which coal dust glows is normally much lower than the auto-ignition temperature (AIT) of methane/air mixtures, and thus a better understanding is needed regarding methane/air ignition in a heated environment in the presence of coal particles. A horizontal tube apparatus was used to test the effect of brown coal and two kinds of bituminous and anthracite on methane/air combustibility. For the four coal samples tested, the presence of coal particles significantly reduced the minimum temperature for ignition of methane/air mixtures in a heated environment. No. 1 bituminous coal with 12 mm diameter decreased the ignition temperature value from 595 to 500 °C. It is thought that pre-ignition of low-AIT volatiles emitted from the heated coal particles ignited the methane/air mixtures. Volatiles, sulfur content, and large porosity of piled coal particles all enhanced ignition of methane/air mixtures in a hot environment, while water content and small particle size reduced ignition. For anthracite, no ignition occurred when temperatures of the heated environment were lower than the AIT of methane (595 °C), except for the 12-mm-diameter sample. Anthracite did not readily ignite methane/air mixtures and the ignition mechanism was somewhat similar to that of a burning cigarette.     

Emergy analysis of cassava vinasse treatment

Vinasse has great pollution to the environment. A number of technologies have been explored for reducing the pollution of vinasse. Sustainability has become an important factor when discussing wastewater treatment techniques. Emergy analysis was used to evaluate the treatment of cassava vinasse in this paper. Cr (emergy consumption ratio) as a new emergy index was proposed to measure the impact of waste treatment to the society. Centrifugal solid–liquid separation, UASB (up-flow anaerobic sludge bed), and SBR (sequencing batch reactor activated sludge process) are used in the treatment process. The emergy indices for cassava vinasse treatment system were as follows: EYR (emergy yield ratio) was 6.20, ELR (environmental loading ratio) was 5.81, ESI (emergy sustainability index) was 1.07, and Cr was 4.60E+12 sej/m³. The emergy of coal electricity accounts for 46% of all purchased inputs. It is necessary to improve the treatment technology to reduce the electricity used.     

人体装甲测试用模拟破片的应用与发展

模拟破片是人体装甲防弹性能测试评价的主要试验弹体.本文对人体装甲和模拟破片进行了阐释,分析了模拟破片的应用背景,对国内外现状进行了对比分析,对标准模拟破片的确定以及爆炸破片的发展进行了探讨,提出了开展新型模拟破片及其测试技术研究的重要意义.     

软质防弹材料的发展

近年来,软质防弹材料发展非常迅猛,本文系统地分析了软质防弹材料的防弹机理及其影响因素,提出了防弹装备设计的关注点。     

重化工聚集区企业间资源循环利用调研与分析

解决经济社会发展过程中的资源短缺、环境污染和生态破坏等问题,需要构建有利于推进节能减排和资源循环利用的新型经济模式.通过文献研究和实地调研,总结了国内外先进重化工区的可持续发展经验,为我国重化工区推进循环经济提供了有益的启示.研究武汉市青山区重化工聚集区企业副产品和废弃资源的特点,从循环经济的角度提出了重化工聚集区企业间副产物和废弃资源循环利用的途径.青山区资源循环利用经验对国内外同类重化工集聚区具有典型示范作用.     

个体生理状态及体表微气候监测系统研究

本文对能够反映人体健康状况的生理特征和人体舒适感的体表微气候的指标进行了分析,探讨了将传感器技术、信息传输和显示技术应用于个体防护服装进行健康与安全监护的路径与方法,设计了应用于人体生理状态和体表微气候监测的信息采集、传输、显示和记录系统,研制了可以用于防护服装的智能化生理指征和微气候监测系统,赋予个体防护服对着装者生理状况和着装微环境进行监测的功能。同时也对系统的结构与功能进行了分析和介绍,以便为个体防护服装的智能化监测提供借鉴与参考。