Solubilization of mixed polycyclic aromatic hydrocarbons through a rhamnolipid biosurfactant

The solubilization of phenanthrene (PHE) and pyrene (PYR) by rhamnolipid biosurfactant was systematically investigated. The solubilities of both polycyclic aromatic hydrocarbons (PAHs) were increased linearly with the biosurfactant concentration at above critical micelle concentration. A competitive effect was observed between PHE and PYR. The solubility of PHE in a mixed system was lower than that in a single PAH system, whereas the solubility of PYR in a mixed system was enhanced. This is because the hydrophobicity of PYR is higher than that of PHE, so PYR is favored in the competitive solubilization. The combined effect of biosurfactant and dissolved organic matter (DOM) on PAH solubilization was also examined. Two kinds of DOM (derived from soil and from compost) were used. There was an obvious enhancement of solubility for PHE and PYR in systems with concurrence of DOM and biosurfacrant compared with systems with only DOM or biosurfactant; however, the enhancement in the mixed system was less than their additive. This could be explained as the formation of a DOM-biosurfactant complex. In addition, the solubility enhancement of PAHs in a compost-DOM system was higher than that in a soil-DOM system. This could be explained as functional group differences of two DOM types.     

可靠性增长摸底试验方法研究分析

介绍了可靠性增长摸底试验方法的适用范围,对其试验对象进行了探讨,并对如何确定最佳试验时间的两种方法进行了研究.分析指出试验应力的选取也是影响可靠性增长摸底试验效果的关键因素,并用具体试验方案举例说明其有效性,证明了开展可靠性增长摸底试验这项工作可达到快速有效、节约经费的作用.     

干挂石材幕墙火蔓延数值模拟研究

采用数值模拟技术研究了干挂石材幕墙发生燃烧情况下的火蔓延及羽流特点。通过外部高温辐射源点燃了具有4 cm厚PMMA保温层但保温材料和外层钢板间存在2 cm缝隙下的干挂石材幕墙,对模拟结果的温度场、速度场和热释放速率的分析表明其火蔓延速度较泡沫壁面低,但碳化区形状规则,蔓延路径清晰;虽然热释放速率低,但相对而言火焰高度较高,火焰宽度较小,而且其火羽流呈现点火源的特点。     

基于OPC的煤矿安全监测系统的设计

针对控制网接入上层管理网难和各个安全监控系统互不兼容的问题,设计了一种基于OPC技术的煤矿安全监测系统。通过各种工控设备配有的OPC服务器,与矿井下各安全监控分站建立通讯关系,并遵循统一的OPC协议,将采集的井下实时状况数据整合到SQL Server2005关系数据库中,借助工业以太网上传给企业的安全管理平台,经过数据分析和图表显示,可以快捷直观地了解井下具体情况,同时也可以通过网页W eb在整个煤矿企业内部办公网络中进行发布,让安全信息得到全矿的分享。这里以煤矿注浆监测系统为例,重点介绍了利用OPC技术实现上层网与终端注浆监控网通讯的方案。     

大型超市安全管理的定量评价研究

为了有效地评估大型超市的安全管理情况,提高其安全管理水平,根据大型超市的主要危险因素、事故特点等,从安全管理组织和制度、员工的安全管理、设备设施的安全管理、商品安全管理、环境安全管理和事故应急管理六个方面建立了大型超市安全管理定量评估指标体系。该指标体系共分为两级指标,采用层次分析法确定一级指标权重,采用德尔菲专家咨询法确定二级指标权重,建立了大型超市安全管理定量评估模型。为方便对大型超市的安全管理情况进行准确、快速地评估,利用于EXCEL软件建立了大型超市安全管理定量评估系统。     

变权综合法在航空公司风险评价中的应用研究

针对民航风险评价中大多数综合评价方法采取常权综合法,当评价指标体系中某些指标出现严重缺陷时,导致最终综合评价值与实际情况不符的现象,将变权综合法应用到民航风险评价中。给出变权综合法风险评价的基本步骤,以航空公司风险评价为例,建立评价指标体系,运用模糊数学知识对底层指标进行赋值,并对其进行标准量化,其次根据变权综合评价法的基本原理及民航行业高风险的特点,选择适合的状态变权公式,计算评价指标体系的状态变权及变权,最后由变权综合法的综合评价公式,计算出系统的风险评价值。通过与常权综合法的计算结果相比较,变权综合法能较好解决民航风险评价中常权综合法存在的问题,同时计算结果也验证了变权综合法的优越性、有效性和实用性。     

资源环境承载力研究的缘起与发展

随着我国学习实践科学发展观的不断深入,理论和实践界越来越重视在资源环境承载力的允许范围内推进经济的可持续发展.回顾资源环境承载力相关研究的缘起与理论演变,从理论层面上对资源环境承载力相关问题进行系统梳理,理清脉络,这是正确制定和实施可持续发展战略的理论前提.     

变化环境下北江下游年径流量的加权马尔可夫链预测

在气候变化和人类活动的影响下,西北江的水文环境发生了重大变化,导致北江下游的来水条件发生变化。采用斯波曼检验（Spearman’s rho test）和Mann-kendall法系统地分析了北江下游的年径流量的变化趋势和变异情况,在此基础上建立了北江下游变化环境下年径流量的加权马尔可夫链预测模型。结果表明：西北江近50年来的大规模联围筑闸、大规模无序采掘河床泥沙等剧烈的人类活动,导致北江下游三水水文站年径流量在1990年左右发生了变异;所建立的加权马尔可夫链预测结果表明,从变异后的序列中统计出来的状态＂转移概率＂矩阵,能准确地反映出环境变化后年径流量之间的关系,所建立的加权马尔可夫链法预测变化环境下的年径流量是可行的,预测效果也比较好;按文章确定的分级标准,依现有的资料信息推断,环境发生变化后,在未来长期过程中,北江下游出现平水年的机会最大,但年际间的丰枯波动概率也不小。这一结果值得水资源管理部门注意。     

施用碱渣对茶园土壤酸度和茶叶品质的影响

开展田间小区试验研究了不同施用量条件下碱渣对酸化茶园土壤的酸度和茶叶品质的影响.结果表明,施用碱渣可以显著提高土壤pH、土壤交换性盐基和盐基饱和度,降低土壤交换性酸和交换性铝含量,并使土壤中钙、镁养分保持合理比例.施用碱渣提高了茶叶中茶多酚、儿茶素、咖啡碱、氨基酸和叶绿素含量,降低了茶叶中铅含量,使茶叶品质得到改善.碱渣施用量为4 500 kg·hm-2时,可将土壤pH值调节至5.51,达到最适合茶树生长的酸度条件,该条件下生产的茶叶品质也最佳,茶叶茶多酚、儿茶素、咖啡碱、氨基酸和叶绿素含量分别比对照提高22.5%、27.8%、34.9%、69.0%和52.1%,而Pb含量下降51.2%.     

Occurrence, distribution, and source of polybrominated diphenyl ethers in soil and leaves from Shenzhen Special Economic Zone, China

Polybrominated diphenyl ethers (PBDEs) were measured in soil and three plant species samples taken at different land use areas in Shenzhen China. The concentrations of ??₇BDEs (BDE-28, BDE-47, BDE-99, BDE-100, BDE-153, BDE-154, and BDE-183) and BDE-209 in the surface soils ranged from 0.23 to 271 and 8.9 to 5,956 ng/g dry weight (dw), respectively. These figures are comparable to that in the soils of electronic waste dismantling sites. BDE-209 was the predominant congener (contributes 85?C99% of ??₈PBDEs (??₇PBDEs plus BDE-209)) in soils. The regression slopes of total organic carbon and individual BDE congeners were rather gentle, indicating that factors other than soil organic matter regulated the soil concentrations. Proximity to sources of deposition processes might be the major factors. In the plant leaves, ??₇BDEs and BDE-209 concentrations ranged from 1.29 to 5.91 and 5.49 to 28.2 ng/g dw, respectively. BDE-209 is also the dominant component, but the contribution was much lower compared with that in soils. Bauhinia purpurea Linn. and Michelia alba DC. show some similarities on the uptake of PBDEs, while Ficus microcarpa var. pusillifolia is different from them. The correlations between plant leaf concentrations and predicted gaseous concentrations were moderate, indicating that gaseous concentration did not influence the leaf concentration significantly.