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The pyrolysis and chlorination of petroleum coke in a NaCl‐KCl melt results in the production of CCl4 and C6Cl6. Polychlorinated dibenzo‐p‐dioxins (PCDDs) are produced from the air oxidation and chlorination of coal using HCl or Cl2. Smoking of tobacco containing 36Cle provides CH3 36Cl. At 350°C, the rateof aromatization of 1,3‐cyclohexadiene is negligible as compared to that of 1,4‐cyclohexadiene. The aromatization of the latter diene proceeds through the molecular elimination of hydrogen; while that of 1,3‐cyclohexadiene expecially at higher pressure (10–90 Torr) and at 362–421 °C involves free radical chain mechanism. 相似文献
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Heidelore Fiedler Gerd Rippen Susanne Sievers Peter Friesel Birgit Gras Christoph Lau Thomas Reich Uwe Schacht Roland Schwörer Hansjörg F. Wesp Otto Hutzinger Fritz Vahrenholt 《Environmental Sciences Europe》1997,9(3):131-135
The sources and reservoirs of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/PCDF) in the city of Hamburg, Germany, in the year 1992 were identified and quantified combining analytical data of PCDD/PCDF with statistical data on annual fluxes of materials and products. Fluxes and amounts of PCDD/PCDF were estimated for the environmental compartments water, air, and soil. Dioxin emissions originating from industrial, commercial or private activities were also calculated. Together with the analysis of the specific regional nutrition data, the human exposurevia the various pathways could be determined. It could be shown that the total PCDD/PCDF intake of individuals in Hamburg was about the same as the national average. High annual fluxes of PCDD/PCDF connected with the trade of industrial products and the waste management and disposal: system in Hamburg obviously had no influence on the human intake of PCDD/PCDF. 相似文献
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