Variation in PAH inputs and microbial community in surface sediments of Hamilton Harbour: implications to remediation and monitoring

Variations in concentrations of polycyclic aromatic hydrocarbons (PAHs) and microbial community indicators were investigated in representative highly contaminated and less contaminated surface sediment sites of Hamilton Harbour. Inputs of PAH to the upper 3cm of sediments up to four times the average upper sediment concentrations were observed. Associated PAH fingerprint profiles indicated that the source was consistent with the PAH source to the industrial region of the harbour. Increased PAH loadings were associated with decreased bacterial populations as indicated by phospholipid fatty acid (PLFA) concentrations. However, relatively minor impacts on overall community composition were indicated. Porewater methane concentrations and isotopic data indicated a difference in the occurrence of methane oxidation between the two sites. This study confirms temporally limited transport of contaminants from highly impacted regions as a vector for contaminants within the harbour and the impact on microbial carbon cycling and bed stability.     

Ambient noise, motor fatigue, and serial redundancy in chaffinch song

Many animal signals are performed in a highly redundant manner as in some bird species where males sing several renditions of one song type before switching to another. However, differences in signal redundancy between contexts and between individuals are only poorly understood. We found that chaffinches (Fringilla coelebs) in noisier areas (i.e., close to waterfalls and torrents) sang longer bouts of the same song type before switching to a new type, suggesting that they use increased serial redundancy to get the message across in noisy conditions. This is the first evidence of a noise-dependent adjustment of signal redundancy in a songbird. In addition, we found that song types with faster trills were sung in shorter bouts suggesting that the performance of highly redundant song series is probably limited by motor constraints. Thus, in noisy environments, serial redundancy in bird song may reflect a trade-off between successful signal transmission and preventing motor fatigue.     

Carbon isotope fractionation during reductive dechlorination of TCE in batch experiments with iron samples from reactive barriers

Reductive dechlorination of trichloroethene (TCE) by zero-valent iron produces a systematic enrichment of 13C in the remaining substrate that can be described using a Rayleigh model. In this study, fractionation factors for TCE dechlorination with iron samples from two permeable reactive barriers (PRBs) were established in batch experiments. Samples included original unused iron as well as material from a barrier in Belfast after almost 4 years of operation. Despite the variety of samples, carbon isotope fractionations of TCE were remarkably similar and seemed to be independent of iron origin, reaction rate, and formation of precipitates on the iron surfaces. The average enrichment factor for all experiments was -10.1 per thousand (+/- 0.4 per thousand). These results indicate that the enrichment factor provides a powerful tool to monitor the reaction progress, and thus the performance, of an iron-reactive barrier over time. The strong fractionation observed may also serve as a tool to distinguish between insufficient residence time in the wall and a possible bypassing of the wall by the plume, which should result in an unchanged isotopic signature of the TCE. Although further work is necessary to apply this stable isotope method in the field, it has potential to serve as a unique monitoring tool for PRBs based on zero-valent iron.     

Book reviews

Spatial Energy Analysis: Models for Strategic Decisions in an Urban and Regional Context

Lundqvist, L., Mattsson, L‐G., and Eriksson, E. A. (eds) 1989. Avebury. pp. 386.

Planning in the Face of Power

John Forester. 1989. University of California Press, London.

Planned to Death: The Annihilation of a place called Howdendyke

J. Douglas Porteous. Manchester University Press, 1989. ISBN: 0 7190 2831 0. Hardback, 254 pp. Illustrated. £35.

The Child in the City

Colin Ward. Bedford Square Press, 1990. Price £7.95. pp. 232.

Current Issues in Planning

Sylvia Trench and O. C. Tanner (eds). Gower, 1990. £29.50. Hardback.

Growth and Change in a Core Region

M. Breheny and P. Congdon (eds). London Papers in Regional Science 10. Pion, 1989.

The Greening of Aid: Sustainable: Livelihoods in Practice

C. Conroy and M. Litvinoff (eds). Earthscan Publications Ltd., London. 1989. pp. 293. £8.95 (paperback).

Mastering the Politics of Planning: Crafting Credible Plans and Policies that Make a Difference

Guy Benveniste. Jossey‐Bass, San Francisco and London. 1989. pp. 314. £24.95.     

Environmental justice: lessons on definition and delivery from Scotland

This paper considers the concept of environmental justice in Scotland. It reviews the research and developments in law and policy in this area, starting with the Dynamic Earth speech in Edinburgh in 2002. It analyses the findings by grouping causes and solutions to environmental justice and identifies a particularly wide definition of the concept in Scotland. It concludes that the inclusion of social justice is a defining feature of environmental justice in Scotland; however, measures to mitigate environmental injustice are being implemented in an incremental way, with the most significant achievements being through the implementation of international obligations.     

Sea Cucumber Aquaculture in the Western Indian Ocean: Challenges for Sustainable Livelihood and Stock Improvement

The decline in sea cucumber fisheries that serve the Asian dried seafood market has prompted an increase in global sea cucumber aquaculture. The tropical sandfish (Holothuria scabra) has, in this context, been reared and produced with mixed success. In the Western Indian Ocean, villagers often participate in the export fishery for sea cucumbers as a source of income. However, with a growing concern of depleted stocks introduction of hatcheries to farm sandfish as a community livelihood and to replenish wild stocks is being promoted. This review identifies and discusses a number of aspects that constitute constraints or implications with regard to development of sandfish farming in the region. The conclusion is that for sandfish farming to live up to its expectations the possible impacts need to be further studied, and that improved evaluation of ongoing projects is required. In the interim, a precautionary approach toward new enterprise activities is suggested.     

Soil mobility of surface applied polyaromatic hydrocarbons in response to simulated rainfall

Polyaromatic hydrocarbons (PAHs) are emitted from a variety of sources and can accumulate on and within surface soil layers. To investigate the level of potential risk posed by surface contaminated soils, vertical soil column experiments were conducted to assess the mobility, when leached with simulated rainwater, of six selected PAHs (naphthalene, phenanthrene, fluoranthene, pyrene, benzo(e)pyrene and benzo(ghi)perylene) with contrasting hydrophobic characteristics and molecular weights/sizes. The only PAH found in the leachate within the experimental period of 26 days was naphthalene. The lack of migration of the other applied PAHs was consistent with their low mobilities within the soil columns which generally paralleled their log K _oc values. Thus, only 2.3 % of fluoranthene, 1.8 % of pyrene, 0.2 % of benzo(e)pyrene and 0.4 % of benzo(ghi)perylene were translocated below the surface layer. The PAH distributions in the soil columns followed decreasing power relationships with 90 % reductions in the starting levels being shown to occur within a maximum average depth of 0.94 cm compared to an average starting depth of 0.5 cm. A simple predictive model identifies the extensive time periods, in excess of 10 years, required to mobilise 50 % of the benzo(e)pyrene and benzo(ghi)perylene from the surface soil layer. Although this reduces to between 2 and 7 years for fluoranthene and pyrene, it is concluded that the possibility of surface-applied PAHs reaching and contaminating a groundwater aquifer is unlikely.     

High technology firms and planning policy: a case study of research machines limited,Oxford

This article reviews planning issues relating to “high‐tech” industry in Britain, and uses a case study of a manufacturer of micro‐computers in Oxford, England as a focus for a discussion. It concludes that town planning categories are not, in themselves, a constraint on high technology firms, and suggests that the provision of sites and premises by local authorities is a useful and undervalued task.     

Relationships among plant available phosphorus, fertilizer sales, and water quality in northwestern Ohio

Soluble reactive phosphorus (SRP) in northwestern Ohio river water has declined over the past 20 yr in response to decreased applications of fertilizer P. Our objective was to evaluate changes in soluble P (Bray-1 P) levels in the soil over time as influenced by fertilizer P management, cultivation practice, soil properties, and landscape factors. Because soil is the intermediary between added P and SRP measured in river water, we examined the relationship between fertilizer P, soluble soil P, and SRP. Using historical soil survey sample sites as a baseline for original soluble P concentrations (Por), we resampled Ap horizons to establish current levels of soluble P (Pcu). The Por baseline extended from 1953-1982 and Pcu from 1996-1998. Thirty percent of the Pcu values and 17% of the Por values were > or = 40 mg kg(-1). Log-transformed means for Pcu were significantly higher than for Por. The principal determining factors for Por were physiography, soil texture, and soil series. Current P is affected by present tillage practice and drainage class. Change in soluble P in the soil is not as responsive to fertilizer P sales as is SRP in river water. This suggests that as fertilizer P sales decline, a declining percentage of P added as fertilizer is annually dissolved and transported into the drainage system. Soluble P in soil is governed by a combination of fertilizer and tillage management, soil properties, and landscape factors interacting over time.     

The investment climate for gold mining

This analysis compares the gold mining industry investment climate in the USA to the investment climate in Australia. These two major gold producing nation's industries share many similarities; in both the USA and Australia, there is evidence of a maturing gold mining industry. Each country has experienced a dramatic increase in gold production and, more recently, greater mining of refractory ore and development of more underground operations. In the 1980s both nations experienced a pronounced rationalization trend that consolidated some gold producing operations and eliminated others. Each country commands a disproportionately large share of exploration expenditures. Land access, a major concern in the USA, has also become a critical issue in Australia as well. For all their similarities, however, the two countries have differences that are significant enough to influence mining company investment decisions. This paper explores those differences and how they may affect the future course of these nations' gold mining industries. Both effective government policy making and corporate strategic planning will occupy a major role in the future course of the two nations' gold mining industries .