Effect of CeO2 and Al2O3 on the activity of Pd/Co_3O_4/cordierite catalyst in the three-way catalysis reactions (CO/NO/CnHm)

The present article studies the effect of CeO₂ and Al₂O₃ on the activity of Pd/Co₃O₄/cordierite catalyst in conversion of NO, CO, C_nH_m. The catalysts were characterized by temperature programmed reduction with hydrogen, X-ray diffraction, X-ray photoelectron spectroscopy and transmission electron microscopy. It is shown that the effect of CeO₂ on the properties of Pd/Co₃O₄/cordierite catalyst depends on preparation method. The catalyst obtained by co-deposition of cerium and cobalt oxides has higher activity in CO oxidation (CO + O₂ and CO + NO) and total hexane oxidation (C₆H₁₄ + O₂). Such phenomenon is probably caused by more than stoichiometric amount of formed oxygen vacancies, an increase in both mobility of surface oxygen and dispersity of components in the catalytic composition. It is demonstrated that CeO₂ addition promotes the SO₂ resistance of Pd/Co₃O₄/cordierite. The second support decreases the activity of Pd/Co₃O₄/cordierite catalyst in the reactions of CO and C₆H₁₄ with oxygen because of CoAl₂O₄ formation.     

Acute and chronic toxicity of nickel to nitrifiers at different temperatures

This study investigated the acute nickel toxicity on nitrification of low ammonia synthetic wastewater at 10, 23, and 35°C. The nickel inhibition half-velocity constants(K_(I,Ni)) for ammonia oxidizing bacteria(AOB) and nitrite oxidizing bacteria(NOB) based on Ni/MLSS ratio at 10, 23, and 35°C were 5.4 and 5.6 mg Ni/g MLSS, 4.6 and 3.5 mg Ni/g MLSS, and 9.1 and 2.7 mg Ni/g MLSS, respectively. In addition, chronic toxicity of nickel to nitrification of low ammonia synthetic wastewater was investigated at 10°C in two sequencing batch reactors(SBRs). Long-term SBRs operation and short-term batch tests were comparable with respect to the extent of inhibition and corresponding Ni/MLSS ratio. The μ_(max), b, and K_o of AOB were 0.16 day~(-1), 0.098 day~(-1) and 2.08 mg O_2/L after long-term acclimatization to nickel of 1 mg/L at 10°C, high dissolved oxygen(DO)(7 mg/L) and long solids retention time(SRT) of 63–70 days. Acute nickel toxicity of nitrifying bacteria was completely reversible.     

Chemical looping with oxygen uncoupling: an advanced biomass combustion technology to avoid CO2 emissions

Mitigation and Adaptation Strategies for Global Change - Bioenergy with carbon dioxide (CO2) capture and storage (BECCS) technologies represent an interesting option to reach negative carbon...     

Culturally correct song dialects are correlated with male age and female song preferences in wild populations of brown-headed cowbirds

Variation in vocal behavior among local populations of songbirds may be significant to females in mate choice. In a study of dialect populations of brown-headed cowbirds, estradiol-implanted females from two dialects held the pre-copulatory lordosis posture longer in response to playback of the local flight whistle song than to foreign whistle types from adjacent and more distant dialects. Females were held in captivity for a relatively brief period prior to testing and received no tutoring so discrimination was based solely on experience in the wild. This is the first study to show evidence of discrimination by female cowbirds based on flight whistle type. Evidence is presented from one of the study dialects that the majority of yearling male cowbirds are vocally distinct from resident adults in having either foreign or incomplete local whistles. Although these yearlings are fully mature sexually, they have little or no mating success. The correlation between female whistle preference and male mating success suggests that the ability to give the correct local whistle type may be a characteristic used by females to assess age and quality of a potential mate. A learned female preference for the predominant local song type may be a factor in the stability of these dialects by making it adaptive for males to conform to the local dialect.     

Mechanisms of the Formation of Extrazonal Biocenoses on the Solovetskiye Islands

On the Solovetskiye Islands, subtundra forests and forest-tundra crooked forests are considered to be zonal biocenoses, as this region is intersected by the 12°C isotherm for July, which marks the boundary between the northern taiga and forest-tundra zones in northern Europe. The formation of extrazonal tundras on the islands is attributed to the cooling effect of the sea and the prevalence of cold northeasterly winds in the growing period. Herbaceous and herb-bilberry forests similar to their middle-taiga counterparts develop in this region due to a convective heat flow anomaly of high intensity (up to 40–50 W/m²). The phenomenon provides evidence for the existence of an active heat source in the crust under the archipelago. This source is probably a diapir fold involving the upward movement of the mantle.     

Geographic Variation in the Seasonal Reproductive Strategy of the Mite Varroa jacobsoni in the Honeybee Nest

Variation in the reproduction of Varroa jacobsoni mite was studied in relation to the expansion of the range of its parasitism on the honeybee. Geographic differences in the seasonal dynamics of mite reproduction in the nests of bee families were revealed. Variation in the sex ratio of mites and the factors inhibiting their reproduction at the northern boundary of the honeybee range are considered. The forms of parthenogenetic reproduction in V. jacobsoni are discussed.