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81.
某鞋业公司一起不明爆炸事故的分析、处置与预防对策 总被引:1,自引:1,他引:0
对某鞋业有限公司发生的一起爆炸事故进行了分析,找出了导致爆炸事故的根源是操作人员不了解氧化剂与易燃、可燃物的混触危险性,将丙酮等有机废料与少量双氧水混合后,形成了对热、撞击、摩擦敏感度非常高的熵炸药(TATP)。处理TATP的最大难点是其敏感性太高,少有不慎,即会发生爆炸,导致人员伤亡事故。特别是打开桶盖过程中,螺纹中可能存有干燥的TATP,桶盖旋转过程中可能发生爆炸。根据TATP和废料的特性,制定了现场存留危险性废料的处置方案并进行了处理,提出了防范该类事故的措施。 相似文献
82.
重大事故移动监测和指挥平台AKY-MCP的设计与实现 总被引:3,自引:2,他引:1
介绍了重大事故移动监测和指挥平台AKY-MCP的设计与实现。该平台能够快速、及时、准确地被部署,并收集应急指挥需要的各种现场信息,满足应急指挥人员进行沟通、指挥、调度对现场数据采集、处理和传输的需要,为应急指挥提供现场信息检测和辅助决策平台。该系统已经得到成功的应用,并取得了良好的效果。重大事故移动监测和指挥平台AKY-MCP,能更有效的监测事故现场情况,快速进行处置,降低生命财产的损失。重大事故移动监测和指挥平台AKY-MCP,能够在事故现场进行快速部署,对应急指挥进行辅助决策,并把现场视频图像信息、有毒有害气体浓度信息、GPS信息、现场地形位置信息和现场风速风向等信息实时发送到远端的指挥中心,为领导和专家提供现场资料,有利于及时决策、控制事故后果蔓延,维护社会稳定和人民财产安全。 相似文献
83.
Hexabromocyclododecanes in surface sediments and a sediment core from Rivers and Harbor in the northern Chinese city of Tianjin 总被引:1,自引:0,他引:1
In the present study, hexabromocyclododecanes (HBCDs) were investigated in the sediment from Haihe River (HR), Dagu Dainage Canal (DDC) and Tianjin Harbor (TH) at Bohai Bay using a total of 51 samples of surface sediments and a sediment core collected from May to September in 2010, and its diastereomer- and enantiomer-specific profiles were analyzed. The concentration of total HBCDs were generally high, with mean value and ranges of 31.0 and 1.35–634 ng g?1 dw, respectively. The contamination followed the order of TH > DDC > HR. Higher levels (up to 634 ng g?1 dw) occurred in the lower reach of HR and DDC located in an industrial area of Tianjin. This is the first time to report so high concentration of HBCDs in sediment in Southeast Asia. The γ-diastereomer dominated in most samples (44 out of 51), and this is in agreement with the diastereomer distribution pattern in industrial products, while α-HBCD was the dominant diastereomer in the other seven samples. However, only few samples exhibited γ-diastereomer ratio similar to that (75–89%) in technical products, indicating the inter-transformation and variable degradation of the different isomers. The high ratio of γ-diastereomer could be used as an indicator for fresh contamination input. Enantiomeric factors (EFs) of HBCD isomers in most of the samples were statistically different from technical products (p < 0.05), showing a trend of more easily enrichment of the (?)-HBCD-enantiomer compared to the (+)-HBCD-enantiomer. The δ- and ε-diastereomers were frequently detected but at low level. The HBCDs in the sediment core showed several peaks, and the greatest value occurred in 2005, when a plastic manufacture plant using HBCD was set up nearby. 相似文献
84.
85.
Yanwei Zhang Hongwen Sun Fang Liu Yuanyuan Dai Xuebo Qin Yuefei Ruan Lijie Zhao Zhiwei Gan 《Chemosphere》2013
To interpret the distribution of hexabromocyclododecanes (HBCDs) in various organisms, we measured the concentrations and diastereomer and enantiomer profiles of HBCDs in 21 different species of limnic and marine cohorts from Tianjin, China. The concentration ranges of HBCDs in limnic and marine organisms were 64.3–1111 ng g−1 lw and 85.5–989 ng g−1 lw, respectively. Living habitat and feeding habits had important impacts on HBCD diastereomer distribution. Most of the species appeared to preferentially select (+)-α-, (−)-β- and (−)-γ-HBCD. There is a tendency that the total and α-HBCDs were magnified as trophic level increased with trophic magnification factors (TMFs) around 2. The concentrations of HBCDs in the limnic and marine fishes were highest in the liver, followed by the gill, skin, and muscle. In terrestrial plants, the highest concentrations of HBCDs were observed in the leaf, followed by the root and the rhizosphere soil. Plants showed enantioselectivity for HBCD enantiomers, which varied with plant species and organs (leaf vs. root) of the same plant. Higher estimated daily intakes (EDIs) of HBCDs were observed from fish than from wheat. 相似文献
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87.
城市是区域经济发展的依托,区域旅游合作水平的高低同样与区域城市体系的发育程度紧密相关。以中部6省城市体系为构架,对中部6省省际间区域旅游合作进行了探讨,并从节点优化、线路组织、市场拓展等方面提出了6省间区域旅游合作的构想,以期为中部六省区域旅游合作程度的进一步加深提供一定的借鉴。 相似文献
88.
89.
通过微波消解法、标准测试方法(SMT)和碱熔法分别测定了水系沉积物成分分析标准物质GBW07307a(GSD-7a)中的总磷(TP)含量,并分别采用3种方法对采集于黄河流域甘宁蒙段表层沉积物样品进行TP含量和样品加标回收率的测定。结果表明:测定标准物质的相对误差绝对值:微波消解法碱熔法SMT法;变异系数:微波消解法碱熔法SMT法。同时,微波消解法提取的表层沉积物TP含量的范围为634.3~909.2μg/g;SMT法TP含量的范围为627.1~889.5μg/g;碱熔法TP含量的范围为559.1~784.8μg/g。微波消解法的测定结果相对偏高,SMT法的测定结果相对偏低。样品加标回收率平均值:微波消解法SMT法碱熔法;变异系数:微波消解法碱熔法SMT法。综合测定标准物质中TP含量以及样品加标回收率实验结果的准确度和精密度,对于黄河甘宁蒙段表层沉积物,使用SMT法提取TP较优于微波消解法和碱熔法。 相似文献
90.